Lac

Laccaic acid A

Laccaic acid B

Laccaic acid C

Laccaic acid D

Note that laccaic acids A, B and C differ at a single point only.

Property Data
Common name
Suggested name
Other names
 
 
C.I. number
C.I. name
Class
Ionisation
Solubility aqueous
Solubility ethanol
Absorption maximum
Colour
Empirical formula
 
 
 
Formula weight
Lac
Lac
Shellac
Laccaic acid
Xanthokermesic acid
75450
Natural red 25
Natural
Acid


A: 302, 361, 518, 558
Yellow, Red
A: C26H19NO12
B: C24H16O12
C: C25H17NO13
D: C16H10O7

Lac is a dye, and shellac is a common wood finish. Both are obtained from the secretions of an insect found in India, Laccifer lacca (formerly Coccus lacca). The insects are embedded in the resinous secretion, forming a mass. The dye compounds are water soluble and this is used to extract them from the mass. The resinous residue is further purified to produce shellac, the wood finish.

The dyes produce red colours when used with mordants and were used for cloth, leather and cosmetics. Lac is chemically very similar to carmine and, as the older name indicates, the insects are related to those from which carmine is obtained.

Although not used in histotechnology, lac is relevant as, over a period of time, lac has been changed to lake and is now used as a general term for metal-dye complexes.


There are four compounds found in lac, designated laccaic acids A, B, C and D. Laccaic acid A is the most abundant. Laccaic acids A, B and C are very similar, differing at a single point, and this is illustrated in the formulas above. Laccaic acid D is also called xanthokermesic acid, and closely resembles kermesic acid in structure.

Compare this dye with other dyes obtained from the bodies of insects, Kermes and Carmine.

There is an article on lac in the United Nations Food and Agricultural Organisation web site.

 

Reference
Susan Budavari, Editor, (1996)
The Merck Index, Ed. 12
Merck & Co., Inc., Whitehouse Station, NJ, USA