This video was incredibly helpful. I am a professional web designer who regularly reads blogs, pokes around sites, and reviews CSS books, so I didn't expect to learn much. And, when it came to the box model or specifying colors, I didn't.
But seeing the working methods and process, and hearing about the thought process behind the design steps, was incredibly helpful. You walk through making a linear outline of the page content (which makes it accessible and well-structured) in a word processor and then HTML, then styling the typography, roughly laying out the page, and then lots of finishing touches like beautiful buttons, image replacement, etc.
I ordered this DVD as inspiration before starting a new client project, and I already feel like they're getting more than they originally paid for!