From Mistress to temptress! Alyssa Milano shows off cleavage in daring LBD at New York Fashion Week show

PUBLISHED: 17:01 EST, 5 September 2013 | UPDATED: 17:01 EST, 5 September 2013

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She came back to the small screen with a sexy new role on television show Mistresses.

And it seems that even in her spare time, Alyssa Milano can't quite resist looking every inch the seductive temptress.

Arriving at the Tadashi Shoji show for New York Fashion Week, the former Charmed actress looked incredible in a daring black dress, with a plunging neckline on Thursday.

Best dressed: Alyssa Milano attends the Tadashi Shoji Spring 2014 fashion show during Mercedes-Benz Fashion Week at The Stage at Lincoln Center on Thursday

The 40-yeard-old star showed her cleavage in the ensemble, which almost threatened to steal the show from the other models.

Alyssa also easily stood out from the other VIPs that were in attendance, including Bella Thorne, 15, and model Jessica White, 29.

Designer Tadashi Shoji had titled his spring collection 'Sweet Liberation'.

Front row: Milano is joined by Bella Thorne at the Tadashi Shoji Spring 2014 fashion show and both seemed very impressed with the designs

Fashion friends: Alyssa and Bella happily posed together ahead of the show in New York on Thursday

He said in a pre-show interview: 'I think we need more sweetness and fun in this world. Femininity and sweetness? I am not afraid to be sweet, and women are confident enough now and know they can be taken seriously even if they wear pretty clothes,'

However, Alyssa looked far from sweet in her daring LBD.

The racy star had fun with fans earlier this month when it emerged that someone had 'leaked' a 'sex tape' of the star.

'My sex tape was leaked. Not sure what to say. Going to post the link myself to try to control the situation,' she tweeted to her more than 2.5 million fans on Wednesday.

Long and short of it: Bella and Alyssa seemed to be impressed with the latest collection from designer Tadashi Shoji

VIP: Model Jessica White also attended the Tadashi Shoji Spring 2014 fashion show at The Stage Lincoln Center on September 5, 2013 in New York City

Not taking it seriously? Sister Act: The Musical star Patina Miller looked half-asleep, while Glee's Amber Riley and J. Alexande appeared to be sharing a joke at the event

In a skit recorded for website Funny Or Die, the Mistresses star found a very clever way of drawing attention to the escalating violence in the Middle East.

Capitalizing on her curves, the 40-year-old drew viewers in with plenty of cleavage in a pink push-up bra and purple lace camisole, which she pairs with green silk pajama shorts.

Supposedly cavorting with a good-looking robe-wearing man in a hotel room while 'vacationing' in Cabo, Mexico, the mom-of-one sets up the video camera to capture some sordid action.

But a stiletto-clad foot derails the plan to film the intimate encounter, with the camera spinning round to focus on the news being broadcast on the wall-mounted television.

Grand designs: Designer Tadashi Shoji had titled his spring collection 'Sweet Liberation'

Haute couture: The pretty dresses at the Tadashi Shoji show were in stark contrast to the sexy outfit worn by former Charmed actress Alyssa Milano

The Row: Bella Thorne, Alyssa Milano, Rochelle Aytes and June Ambrose appear to keep a watchful eye on the model during the show at New York Fashion Week