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Rihanna slips into an elegant rose gown as she towers over tiny Kim Kardashian at her First Annual Diamond Ball

By Louise Saunders and Jennifer Pearson for MailOnline

Published: 03:12 EST, 12 December 2014 | Updated: 09:39 EST, 12 December 2014

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They're two of the world's most photographed women, and never fail to raise an eyebrow or two when it comes to their penchant for racy attire.

And Rihanna and Kim Kardashian came together for a good cause as they attended the singer's first-ever Annual Diamond Ball at The Vineyard in Beverly Hills on Thursday night.

The 26-year-old pop princess positively towered over the diminutive reality star as they enjoyed a good chat as the charity event, held in honour of the Clara Lionel Foundation, before working their magic in front of the camera.

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The perfect pair: Rihanna towered over tiny Kim Kardashian as they posed up a storm at the Inaugural Diamond Ball at The Vineyard in Los Angeles on Thursday night

Terrific twosome: The 34-year-old reality star and the 26-year-old singer seemed to be having an absolute ball as they worked their magic in front of the camera at the charity event

Never far away: Kim's 'momager', Kris Jenner, also got in on the act, treating hostess with the mostess Rihanna to a huge hug inside the venue

The girls opted for rather different outfits for the occasion, with the Rude Boy hitmaker ditching her usual racy and revealing attire in favour of something a little more elegant.

Displaying her toned curves in all their glory, the Bajan beauty positively smouldered as she hit the red carpet in a breathtaking Zac Posen Fall 2014 Rose Stretch Duchesse Off-The-Shoulder Gown.

Although this was a pleasingly graceful and new look for her, Rihanna still managed to show off some cleavage highlighted by a glittering red stone and diamond pendant necklace.

Her tattooed wrist was adorned with a purple bracelet while dark red lipstick lent a dramatic effect to her features.

Rihanna raised the bar by wearing her hair slicked back into a long ponytail.

Firm friends: The girls seemed to be complimenting each other on their equally stunning outfits as they enjoyed their glamorous night out

Glam squad: Kris, Rihanna and Kim posed with musician Big Sean as they partied the night away

Night to remember: Rihanna donned an elegantly trailing rose satin gown to attend her first ever Diamond Ball at The Vineyard in Beverly Hills on Thursday

Professional pout: Kim struck a sultry pose before the event, flashing plenty of flesh in a plunging sheer sequin gown, which she wore over a revealing bodice

Salma Hayek and Rihanna stun in evening gowns at Diamond Ball

Graceful for a change: The 26-year-old singer was unusually understated and played up her classy side at this event to benefit her very own The Clare Lionel Foundation

She's got sparkle: Rihanna dressed up her ensemble with a dazzling diamond and red stone pendant necklace

Standing room only: With a tight fit like that one wonders if Rihanna was able to sit down at all

Aside from mingling with Kim, Rihanna was also spotted chatting to the star's momager Kris Jenner, who treated the hostess with the mostess to a huge hug to congratulate her on her efforts.

As the trio posed alongside musician Big Sean, Rihanna positively towered over tiny Kim as as the photographers snapped away.

Of course, Kim didn't give up her penchant for racy attire for the evening, showcasing her world-famous figure in a very revealing ensemble.

The mother-of-one a plunging sheer sequin gown, which she wore over a revealing bodice.

Never under-dressed: Kim looked utterly incredible as she worked her magic on the red carpet, ensuring her world-famous figure was on full display for the occasion

Dare to bare: The mother-of-one made for a rather arresting sight thanks to her dramatically plunging neckline

Kris Jenner tries to steal Kim's thunder in lace top with no bra

When one outfit simply isn't enough: Rihanna later changed into an incredible Zac Posen Resort 2015 Midnight Blue Duchesse and Taffeta Strapless Ball Gown

The ultimate pop princess: Rihanna's turn on the stage would have no doubt delighted the star-studded room of attendees at the inaugural event

Gothic glamour: Rihanna's second outfit of the evening proved equally dramatic as the first

Bling ring: The hostess of the evening was wearing a dazzling collection of diamonds and rubies at the glamorous event

What's the matter, Ri? The starlet looked hilarious as she gawped in awe at one of her friends in the middle of the bash

Perhaps feeling the winter chill a tad, Kim - the wife of rapper Kanye West - slung a demure overcoat over her dress to preserve a little modesty.

The event served to benefit the star's own The Clara Lionel Foundation that 'works to improve the quality of life for communities globally in the areas of health, education, arts, and culture,' it's website states.

Rihanna may have been one of the last to arrive, but this bash couldn't start without her.

The Barbadian beauty was also the star performer and she took to the stage in the same dress with a regal quality.

Sealed with a kiss: The star planted an affectionate kiss on her beloved grandfather as they posed for a family photo to commemorate the occasion

We are family: The entertainer was joined at the charity bash by her grandfather Lionel Brathwaite and her mom Monica Brathwaite

You are my inspiration: Rihanna named her foundation after her grandparents Lionel, pictured with her here, and her late grandmother Clare

She's surrounded: The star got a boost having so many loved ones there with her

Pink ladies! Rihanna was joined by a stunning Salma Hayek at the bash

Simply stunning: Salma, 48, looked beautiful on the carpet in her glamorous gown

Seeing double: Guests were handed lifesized masks of the pop princess

'Feel so lucky to have an evening like this, to spend with people with hearts like mine, who want to change and save lives at any cost,' tweeted Rihanna, who jumpstarted the organisation two years ago.

'There’s so much to do, and I can’t do it all by myself, so I have to thank all of the supporters of and people who donated to #TheClaraLionelFoundation Looking forward to seeing you later this evening.'

Jimmy Kimmel reportedly served as host while Brad Pitt introduced her before she hit the stage to perform.

Hot mesh! Kim Kardashian cut a striking sight in a black leotard with netted dress

Curvaceous: Kim showed exactly where she got her famous figure from

Host with the most: Kimmel was the man in charge at the Diamond Ball

Star presence: Rihanna was also the star performer at the star-studded bash

Now there's an introduction: Brad Pitt introduced Rihanna to the stage ahead of her performance

Plenty to talk about: The addressed the audience gathered at Beverly Hills venue The Vineyard ahead of Rihanna's onstage appearance

In good company: Brad was joined onstage by US talk show host Jimmy Kimmel on Thursday evening

'It is such an honor to have Jimmy Kimmel host this event. There is no one more hilarious to make the first annual Diamond Ball an incredible night. I'm blessed by his support,' Rihanna said last month in a statement.

She added: 'Brad Pitt is not only a phenomenal talent, but I admire him and am inspired by his philanthropic work.'

It was also a family affair and Rihanna's beloved grandfather Lionel Brathwaite was also in attendance.

Rihanna seemed to be having a grand time too mingling with such superstar pals as actor Tyrese Gibson, actresses Ellen Pompeo and Salma Hayek and others.

And the star made sure to treat her fellow attendees to a striking rendition of some of her most famous tunes as she took to the stage.

Proving one outfit is simply never enough, Rihanna looked showstopping as she slipped into a dramatic black strapless gown with a jaw-dropping full skirt.