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Rita Ora looks elegant and angelic in ethereal white gown (at first glance!) as she takes to the stage on Alan Carr's Chatty Man

Published: 10:39 EST, 24 April 2015 | Updated: 12:27 EST, 24 April 2015

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She’s known her risqué ensembles and wild flair for fashion, and it appeared as if things had changed for Rita Ora as she took to the stage on Alan Carr's Chatty Man.

At first glance the British star looked elegant and angelic-like in an ethereal white gown until she revealed a saucy pair of racy suspenders on Friday’s upcoming episode.

The beautiful Vionnet number featured a sleeveless bodice and a small train, while it was clinched at the waistline by a bold leather belt.

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Misguiding! At first glance Rita Ora looked elegant and angelic-like in an ethereal white gown until she revealed a saucy pair of racy suspenders on Friday’s upcoming episode of Chatty Man

Dazzling the crowds with her vocal talents, the 24-year-old singer looked nothing short of gorgeous in her style choice which she teamed with patent nude heels.

Rita, who performs her latest single New York Raining with Charles Hamilton, pulled her peroxide blonde locks back from her face in an elegant updo and chose dramatic diamond ear cuffs to complete her look.

She took to her social media sites on Thursday to share a backstage snap with the chat show host and American music artist.

Bold: The beautiful Vionnet number featured a sleeveless bodice and a small train, which offered a peek at her hosiery

'Don't miss us and my suspenders and @chattygram singing New York Raining live,' she captioned it. 'Vionnet you give me life with this outfit thank you!’

Other guests on the show include British actor Stephen Mangan and property guru's Kirstie Allsopp and Phil Spencer.

Avengers: Age Of Ultron stars Paul Bettany and Aaron Taylor Johnson also made a special appearance.

Meanwhile, Rita has just been recognised for a very special accolade, after she was named one of only three O2 Silver Clef Awards winners on Thursday.

On Twitter, the starlet gushed: 'Thrilled & honoured to be named Best Female at this year's #O2SilverClefs40 in aid of @NordoffRobbins1 #musicmatters'

The R.I.P hitmaker will receive the award on 3 July at a ceremony held at the Grosvenor House Hotel, Park Lane.

Style star: Dazzling the crowds with her vocal talents, the 24-year-old singer looked nothing short of gorgeous in her style choice

'Don't miss us and my suspenders': Rita took to her social media sites on Thursday to share a backstage snap with chat show host Alan Carr and American music artist Charles Hamilton

Rita Ora & Charles Hamilton sing New York Raining on GMA

Speaking about the news with music charity Nordoff Robbins, Rita said: 'I feel honoured to be receiving the Best Female Award at the O2 Silver Clef Lunch.

'It's great to be recognised by Nordoff Robbins, a charity which uses music to transform the lives of so many people.'

The Voice UK judge also confirmed that a new single was imminent when she appeared on radio show The Breakfast Club in US last week.

Her second album was originally slated for release last summer and while the title of the first single has not yet been revealed, Rita let slip last November that she was preparing a track called Testosterone.

Alan Carr Chatty Man will be shown on Channel 4 at 10pm on Friday

Strike a pose! Charles Hamilton, Rita Ora and Alan Carr cosy-up for a backstage picture

Nice to see (through) you! The blonde star managed to walk the line between classy and sexy

Star-studded: Other guests on the show include British actor Stephen Mangan, Kirstie Allsopp and Phil Spencer as well as Avengers: Age Of Ultron stars Paul Bettany and Aaron Taylor Johnson