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Look away now Amal! George Clooney kisses stunning Sandra Bullock after she wows the crowd in little black dress at Our Brand Is Crisis premiere

Published: 21:59 EST, 11 September 2015 | Updated: 08:42 EST, 12 September 2015

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He has only been married for less than a year after studiously cultivating a reputation as a dashing ladies man.

So no doubt the heart of George Clooney's wife Amal will miss a beat when she sees the warm chemistry he shared with old friend Sandra Bullock at the premiere of her movie Our Brand Is Crisis at the Toronto International Film Festival on Friday.

The fading heartthrob gave the silver screen beauty a kiss on the cheek as they hammed it up for photographers at the thrilling event.

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Irresistible: George Clooney gave stunning Sandra Bullock a red carpet kiss at the premier of Our Brand Is Crisis in Canada on Friday

Star attractions: The A-listers were surely the biggest names appearing at the Toronto International Film Festival

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George, who produced the political drama, looked like he was having a great time getting to grips with the saucy starlet on the red carpet.

And no wonder, for his 51-year-old Gravity co-star looked great for her age in a figure-hugging black dress that showcased her remarkably taut physique to the maximum.

It even boasted a thrilling see-through check-patterned chest and skirt, with the latter feature giving just the teasingly merest glimpse of her toned thighs.

Second helpings: He could not resist giving the stunning actress' other cheek some attention

Can I kiss you again? George would be forgiven for trying his luck given how amazing his old friend looked

Hamming it up: George showed all the talent that helped win him an Oscar as he played up to the cameras

Ageing like a fine wine: It could be argued George is looking almost as good as he did during his ER glory days

Little black beauty: Sandra looked simply sensational in her pleasingly figure-hugging gown

George made headlines earlier this week when he openly admitted he is a mere trophy husband when he appeared on Stephen Colbert's first ever Late Show.

The funnyman verbally ran rings round the Hollywood heartthrob as he extracted his stunning confession about his relationship with his high-flying human rights barrister wife Amal.

Witty raconteur Stephen said: 'What is it like to be the arm candy in a relationship, because she’s the very serious person?'

What's her secret? The 51-year-old actress must have access to the fountain of life, or at the very least a very good plastic surgeon

Defying Gravity: Sandra credits a low-carb sugar-free diet and working out for her fabulous appearance

What's over there: Despite a beautiful starlet flaunting her figure just yards away the bystanders looked elsewhere

Crowd-pleaser: Sandra was only too happy to saunter around for a while in front of an excited crowd

Occupational hazard: While stars previously only had to worry about straining their wrists signing autographs, they now risk straining their neck taking innumerable selfies

'She must say like, "We’re going to meet extremely intelligent people tonight – these are not show folk. Just be shiny and pretty."'

George conceded: 'That’s mostly what I do.'

However he is clearly not as stupid as he seems, as he succeeded in bringing the thrilling tale of 2002 Bolivian presidential election to the silver screen.

Sandra stars opposite the charmingly bald Billy Bob Thornton as they attempt to determine the outcome of the controversial race.

Hogging the star: Producer George pulled rank so he could pose for numerous pictures with Sandra

Spreading the love: George looked a little put-out when his chum wrapped her arms around producer Grant Heslov and director David Gordon Green

Hope she remembered her deodorant: A pro like Sandra would surely never make such an elementary red carpet mistake

Sounds exciting: In the film Sandra plays a political and advertising consultant working during the 2002 Bolivian presidential election

Nice to see you: There were shades of a young Bruce Forsyth as the handsome star posed for some solo shots

Partners: The ER hunk seemed excited to wrap his arm round co-producer Grant Heslov

Oh dear: Cast member Zoe Kazan made a major stylistic blunder with this black leather gown

For the actress' character, that outcome seems to hinge on publicity, the tears of a politician, and a llama with stage fright, if the trailer is any guide.

Sandra plays 'Calamity' Jane Bodine, a political and advertising consultant hired to run the campaign of Pedro Gallo, one of two main candidates for the Bolivian presidency who ultimately ends up winning the election.

It is a result which still is fresh in many minds after it led to the Bolivian gas conflict, which reached its deadly crescendo the following year.

Comedy and drama both follow in a campaign that almost immediately becomes cutthroat and could eventually turn deadly.

Hurry up George: The cheeky star wore a grin when he finally sauntered along to the event

Time for a detour: The actor looked excited to go mingle with the adoring proles who came to snatch a glimpse of their hero

Didn't he do well: The Oscar-winner was more than happy to press flesh with his excited supporters

Selfie obsessed: George wore his trademark smouldering look as he posed up with a thrilled fan

Tough talk: George's legal eagle bride Amal Clooney has been overseas working on a big case for client, Mohamed Nasheed, the jailed former president of the Maldives