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Gwen Stefani debuts single about break-up from Gavin Rossdale on Ellen after claims couple have settled divorce and agreed to joint custody

Published: 13:17 EST, 26 October 2015 | Updated: 15:15 EST, 26 October 2015

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There's little doubt who or what Gwen Stefani is singing about on her latest single Used To Love You.

The 46-year-old singer appears on Ellen on Monday to debut the song on TV, which details her heartbreak at splitting with husband Gavin Rossdale.

Her TV turn comes after reports this weekend that the the couple have settled their divorce and agreed to share custody of their three sons.

But amid a hectic personal life, Gwen proved the show must go on as she took some time to film a rendition of her new track.

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Star: Gwen Stefani debuted her latest single Used To Love You on Ellen on Monday

The singer showed off her slim figure in a classic white sleeveless tank that showcased her toned arms, teamed with blue denim cropped jeans.

The Hollerback Girl hit-maker rocked a pair of sky-scraper high heeled red boots, as she strutted her stuff on stage.

Her peroxide locks were pulled into a sleek ponytail, with the front section left loose and colour-dipped indigo and black.

The track includes the poignant lyrics: 'You go, I'll stay, you can keep all the memories. I thought I was the best thing that ever happened to you, I thought you loved me the most,' which Gwen sang with passion.

Poignant: The 46-year-old singer belted out the track which details her heartbreak at splitting with husband Gavin Rossdale

Her expression remained remarkably neutral, despite the heartfelt words, as she showed off her youthful and line-free radiant skin.

Always one to add a touch of glamour, the star didn't disappoint with her perfectly applied make-up smoking out her eyes framed by a substantial amount of thick black lashes.

She tends to opt for a strong red lip by way of habit, but had toned it down to a nude shade for the daytime television appearance.

Striking: Her peroxide locks were pulled into a sleek ponytail, with the front section left loose and colour-dipped indigo and black

She added some simple gold accessories, as she embraced the TV funnywoman - flashing her yellow neon bra straps.

Meanwhile, her The Voice co-star Adam Levine shared a cute instagram snap with Gwen and Blake Shelton on Sunday.

He added the affectionate caption: '#family #blakeisthestepbrother.'

Solo star: The Hollerback Girl hit-maker rocked a pair of sky-scraper high heeled red boots, as she strutted her stuff on stage

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Gwen Stefani not only wears her favorite pair of distressed jeans by DSquared2 to take her kids around but also performs in them at the Ellen show.

Wearing a white tank top with her signature exposed colorful bra, spiked Louboutin boots and her trustee jeans by the luxe Italian label, Gwen oozed effortless cool without looking as if she’d put much thought into the look.

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The Bush singer and No Doubt front-woman settled details of their high profile divorce at the weekend, according to TMZ.

It's believed the former flames will share joint custody of their three children, Kingston, nine, Zuma, seven, and Apollo, one.

While the agreement provides equal guardianship, it's thought Gavin will have the kids more often than the No Doubt singer because of her hectic touring schedule.

No doubts: Always one to add a touch of glamour, the star didn't disappoint with her perfectly applied make-up smoking out her eyes framed by a substantial amount of thick black lashes as she greeted Ellen

Affectionate: She added some simple gold accessories, as she embraced the TV funnywoman - flashing her yellow neon bra straps

Relaxed: Her expression remained remarkably neutral, despite the heartfelt words, as she showed off her youthful and line-free radiant skin

It's reported the couple did not sign a prenup before tying the knot, though Gavin has agreed to take less than his 50% share of the community property.

Despite California law entitling each of the spouses to half of their fortune, it's thought the Bush rocker's decision to take a smaller fraction could help them reach a quicker settlement.

If everything runs smoothly, the judge will sign the final divorce documents by the end of the year.

Judges family: Meanwhile, her The Voice co-star Adam Levine shared a cute instagram snap with Gwen and Blake Shelton on Sunday

MailOnline have contacted both Gwen and Gavin's reps for comment.

Announcing their divorce in a joint statement in early August, the couple said: 'While the two of us have come to the mutual decision that we will no longer be partners in marriage, we remain partners in parenthood and are committed to jointly raising our three sons in a happy and healthy environment.'

The musicians, who for the most part kept their relationship out of the public eye, started dating after meeting in 1995, when No Doubt opened for Bush on tour.