Near-IR spectral evidence for the presence of iron-poor orthopyroxenes on the surfaces of six M-type asteroids

Abstract

The first verifiable near-infrared absorption features in the ∼0.9-μm spectral region are reported for Asteroids 16 Psyche, 69 Hesperia, 110 Lydia, 125 Liberatrix, 201 Penelope, and 216 Kleopatra. These weak features (∼1–3%$\sim 1\text{–}3\text{\%}$) are attributed to orthopyroxenes present on the surfaces of these asteroids. 16 Psyche and 125 Liberatrix have full rotational coverage while 69 Hesperia, 110 Lydia, 201 Penelope, and 216 Kleopatra have ∼75%$\sim 75\text{\%}$ rotational coverage. Qualitative ∼2-μm absorption features are present, but are very weak (<1%$<1\text{\%}$). Absorption band positions suggest relatively low abundances of calcium and iron in the pyroxenes. This indicates relatively reducing redox conditions for these asteroids, their parent bodies, and the nebular regions in which they formed. Four potential interpretations for these asteroids include: (1) they are exposed metallic cores or core fragments of differentiated parent bodies with residual orthopyroxene mantle material, (2) they are the result of a smelting-like reaction that converts olivine to pyroxene and metallic iron in the presence of carbon at high temperatures, (3) they are analogs to the primitive metal-rich Bencubbinite meteorites, or (4) they represent metallic surfaces which have accumulated silicate debris from external sources. Of the two original interpretations for the M-asteroids, the enstatite chondrite interpretation (Chapman and Salisbury, 1973, Icarus 19, 507–522; Gaffey and McCord, 1979, Mineralogical and petrological characterizations of asteroids. In: Gehrels T. (Ed.), Asteroids. Univ. of Arizona Press, Tucson, pp. 688–723) can be eliminated for these asteroids because the pyroxene in enstatite chondrites is iron-free and does not exhibit such absorption features. The iron meteorite interpretation remains valid, but with modification. For M-Asteroids 16 Psyche and 216 Kleopatra, these spectral results combined with previous determinations of high radar albedos indicate that these bodies are most probably exposed core fragments of differentiated bodies. M-Asteroids 69 Hesperia, 110 Lydia, 125 Liberatrix, and 201 Penelope exhibit similar spectral features consistent with exposed core fragments, but radar observations would be needed to confirm a high metal abundance. Observations of M-Asteroids 136 Austria and 325 Heidelberga suggest the absence of absorption features in the ∼0.4- to ∼2.5-μm region within the scatter of the data. Verification of the presence or absence of features across the surfaces of these two asteroids requires full rotational coverage. The interpretations for these “featureless” M-asteroids are not well-constrained, but remain consistent with the iron meteorite and enstatite chondrite interpretations.