Not such an angel! Adriana Lima reveals her devilish side in red velvet pantsuit and black fur

As a veteran Victoria's Secret Angel, she is set to appear in the brand's annual fashion show on Monday.

But Adriana Lima showed she's also not always so angelic as she made an appearance on The Wendy Williams Show in New York earlier in the day to promote the big event.

The stunner was a vision in devilish crimson, dressed in a velvet pantsuit. 

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Not such an angel: Adriana Lima, 35, made an appearance at The Wendy Williams Show in New York to promote the Victoria's Secret Fashion Show

 Adriana, 35, kept warm in a fur-like black coat, layered over her stylish ensemble.

The blue-eyed Brazilian wore her raven locks in soft, bombshell curls, which she parted to one side. 

The supermodel's look was complete with a set of black pumps, rings and delicate earrings.  

Lady in red! The stunner was a vision in crimson, dressed in a velvet pantsuit

What a stunner! The blue-eyed Brazilian wore her raven locks in soft, bombshell curls, which she parted to one side

'How you doin'?': The mum of Valentina, seven, and Sienna Jarić, four, took to Instagram ahead of her talk show appearance

'You're my daytime angel!': In another picture, Adriana posed with the talk show host herself

The mum of Valentina, seven, and Sienna Jarić, four, took to Instagram ahead of her talk show appearance. 

In one snap, the richest Victoria's Secret Model, with an estimated worth of $75 million, held up a sign bearing the show's trademark phrase.

'How you doin'? @WendyShow Watch now! #vsfashionshow,' read the photo's caption. 

In another picture, Adriana posed with the popular talk show host herself.

'Thank you for having me @WendyShow... you're my daytime angel!'

Making the rounds! The stunner also stopped by AOL's Build Series

Girl chat: Adriana was joined by fellow VS model Sara Sampaio, 25

Make it metallic in a silver mini dress like Sara's

Sara Sampaio joined fellow model Adriana Lima on AOL's Build Series and while Adriana chose a berry colored sheath dress as her #ootd, Sara donned a cute little mini and thigh high boots for her appearance.

The flirty frock is by Haney and the silver number featured a mock neckline, drop waist and fitted skirt. We've spotted this same exact style on Ciara just a few months back so we know it's in high demand.

Sara's dress is so popular in fact that it's now sold out. But there's plenty of new season looks up for grabs on the brand's website so follow the link at right to check them out.

Then browse the carousel below for our selection of metallic frocks from the Web that are perfect for party season!

* PRICES MAY NOT BE AS ADVERTISED

Shinng star: Sarah dazzled in a sleeveless, turtleneck frock and thigh-high boots

In their zone: The models gave off one of their signature poses

Although she is practically the face of the Victoria's Secret brand, having walked in the Fashion Show since 1999, the supermodel has not let it get to her head. 

The Vogue Eyewear spokeswoman is known for her kind spirit and bubbly personality among her peers and the press.

While on the Today Show on Monday, Adriana praised fellow model Elsa Hosk, 28, who opened this year's show. 

'She did awesome! Mow she know how it [opening the show] feels,' she said, as she sweetly hugged the fellow beauty. 

Signing off! Both girls left a sweet message on an office wall

'Show your own personality!': The ladies chatted away on the show. Adriana gave advice for walking down the runway

Genuine gal: The Vogue Eyewear spokeswoman is known for her kind spirit and bubbly personality among her peers and the press

Last week, the beauty also had kind words to say about Kendall Jenner, 21. 

'I have worked with Kendall on runways before when we were in Europe, like Versace and also with Victoria's Secret. Kendall is very sweet and very nice, and it's always pleasant to work with someone like that,' she told E!

'You know, she works as hard as we [VS vets] do, so I give her credit for all the effort. And I think she is going to do great because Victoria's Secret is all about personality, and she has her own personality.'

'She did awesome!': While on the Today Show on Monday, Adriana praised fellow model Elsa Hosk, 28, who opened this year's show

'She works as hard as we do': Last week, the beauty also had kind words to say about Kendall Jenner, 21. She is pictured in Paris on November 30

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