BERGMANN
& COMPANY
SOCKET
RESEARCH SUB-SECTION
|
THIS PAGE WAS CREATED
AS A SUBSECTION FROM THE PAGE BELOW
http://www.antiquesockets.com/bergmann6.html
EARLY KNOWN INSULATING MATERIALS
|
ABOUT
THIS SECTION
This page was created for a dual purpose:
First, simply for the need of documenting different insulating materials
and compositions.
Secondly, to have a place to file and link the overflow from the Bergmann
socket sections.
It
is because of the Edison and Bergmann socket research, that
I was forced down the road of learning about different insulating
materials.
I soon learned that there was so much confusion on this topic,
stretching back as far as the mid 1800's forward to our times
today.
While we do have accurate testing methods and understand
more today, most of the current confusion that I refer to is
historical and stems from written and documented statements
that were made in the early days. This section will be used
to link to and from the Bergmann socket sections, while documenting
and attempting to clear up some of this confusion.
It will also serve those looking for general information relating
to insulating materials during the 1800's until about 1930.
|
BEFORE
CONTINUING ON WITH THIS SECTION:
This small
introduction explains the reason that this page exists, and will
provide a bit of basic knowledge that will be the key to understanding
this section much easier.
THIS SECTION IS UNDER CONSTRUCTION
IT WILL BE COMPLETED SYSTEM TENACIOUSLY ALONG
SIDE OF THE NEW EDISON BERGMANN PAGES
ONLY THE LINKED ITEMS IN THE TABLE ARE CURRENTLY
WORKING
You will notice the work getting done as you see the items below linked
and working.
Check back from time to time to see the new information being linked.
Also many linked items (with only
a small blurb for now) will be expanded, while some others will soon
turn into their own sections.
INSULATING MATERIAL TABLE
|
|
|
|
|
|
|
|
|
|
Solids |
|
Natural |
Asbestos |
|
|
|
|
|
|
Bone |
|
|
|
|
|
|
Chalk |
|
|
|
Natural
Solids
These insulation materials are all natural and are not
man made in any way. The hard materials can be carved,
clays can be hardened and natural gums used as coatings.
In the early days, it was common to use carved wood for
sockets, switches and other electrical items. Slate and
marble were commonly used for switch bases.
It was quickly realized that new more convenient insulations
were needed, and many of these materials began to be ground
up and used as inert ingredients in newly invented and
different types of molded compositions. |
|
Fire
Clay |
|
|
|
Gums
& Resins |
|
|
|
Ivory |
|
|
|
Kaolin |
|
|
|
Marble |
|
|
|
Mica |
|
|
|
Quartz |
|
|
|
Slate |
|
|
|
Soapstone |
Steatite |
|
|
|
|
|
Talc |
|
|
|
|
|
|
|
|
Artificial
Lava
/ Lavite |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Wood |
|
|
|
|
|
|
|
|
|
|
Fabricated
Solids |
|
Vitrified
Materials |
Glass |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Porcelain |
Dry
Process Porcelain |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Wet
Process Porcelain |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Silica |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Tile |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Vitreous
Enamel |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Fibrous
Materials |
Cellulose |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Fabrics |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Fiber
|
Impregnated
Fiber |
|
|
Fabricated
Solids
Vitrified & Fibrous Materials
In the early 1880's wood was the common insulator for
electrical supplies. Other
natural (and vitrified) materials were also used,
but these were more costly and new and improved inventions
were sought after.
Vulcanized fiber was one of the more common insulators
for electrical supplies until the early 1890's, at which
time porcelain became the more popular and insulator of
choice. |
|
|
|
|
Vulcanized
Fiber |
|
|
|
|
|
Gelatinized
Fiber |
|
|
|
|
|
Treated
Fiber |
|
|
|
|
|
Bitumenized
Fiber |
|
|
|
|
|
|
|
|
Impregnated
Asbestos |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Paper |
Asbestos
Paper |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Fish
Paper |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Bakelized
Paper |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Treated
Paper |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Pressboard |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Molded
Compositions |
Asbestos
Compositions |
|
|
|
Fabricated
Solids
Molded Composition Materials
By the mid 1880's many new compositions were being tested
and used (of which vulcanized and hard rubber became the
most popular). These molded compositions would commonly
use a hard natural solid material, mixed with a heated
plastic, resinous or solidified
liquid.
Cold molded compositions were also invented which used
a chemical binder, or sometimes a chemical, oil or other
ingredient to break down a natural plastic (asphalt, rubber,
etc.), or
resinous material. |
Fabricated
Solids
Hard Rubber Substitutes
The vulcanization of hard rubber was a great breakthrough
in rubber made products and was widely used. However,
hard rubber (vulcanized rubber) was a costly product,
so It was not long before many new black (rubber looking)
compositions were invented (some good and some bad) as
hard rubber substitutes.
Note that even though other products such as vulcanized
and gelatinized fiber were marketed as a substitute for
hard rubber, this was more in the sense of a direct "replacement"
for hard rubber. For this reason they do not belong in
the list of substitutes. I have only added the products
that tried to mimic or duplicate the product. |
|
Asphalt
/ Bitumen Compositions |
|
|
|
|
|
|
|
|
Celluloid |
|
|
|
Condensite |
|
|
|
Hard
Rubber |
Ebonite |
|
|
|
|
|
Kerite |
|
|
|
|
|
Vulcanite |
|
|
|
|
|
|
|
|
Hard
Rubber Substitute |
Dielectrite |
|
|
|
|
|
Electrose |
|
|
|
|
|
Gohmak |
|
|
|
|
|
Insulite |
|
|
|
|
|
Roxite |
|
|
|
|
|
Sternoid |
|
|
|
|
|
Vulcabeston |
|
|
|
|
|
Vulcalose |
|
|
|
|
|
|
|
|
Molded
Mica |
|
|
|
Pitch
Composition |
|
|
|
|
Synthetic
Resins |
Bakelite |
|
|
|
|
|
|
|
|
|
Plastics |
|
As
Used |
Asphalt |
Bitumen |
|
|
Plastics
-
Natural / Modified
Viscous / Liquid
(Bitumen & some pitches)
Many plastics were used as binders to make up compositions.
The rubber products could be mixed with sulfur and vulcanized.
Depending on the process both hard and soft insulating
materials could be made. |
|
Caoutchouc
(Rubber) |
|
|
|
Gutta
Percha |
|
|
|
Pitches |
|
|
|
Waxes |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Liquids |
|
As
Used |
Animal
Oil |
|
|
|
|
|
|
|
|
|
|
|
|
|
Mineral
Oil |
|
|
|
|
|
|
|
|
|
|
|
|
|
Vegetable
Oil |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Solidified |
Enamel |
|
|
|
|
|
|
|
|
|
|
|
|
|
Japan |
|
|
|
Liquids
-
Natural / Modified
While liquids are normally not thought of as an insulator,
they play a large part in the mixture of compositions
and the breaking down of different compounds. Solidified
liquids are those that are applied in a liquid state and
dry as a solid. Insulators such as varnish and shellac
are often times used to impregnate materials, or simply
fill voids and provide a seal. |
|
Paint |
|
|
|
Shellac |
|
|
|
Varnish |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Asbestos
(hydrous silicate of magnesia)
Natural Solid - Melting
Point 2,200 - 2,300°
F
Asbestos is a natural formation of a fibrous rock mineral, that takes
up as much as two-thirds of the earth’s crust.
It can be found as a component in many metamorphic and igneous rocks.
While the fibrous content is clearly evident, most of its makeup of
long thin fiber minerals are microscopic.
Asbestos is a mineral consisting chiefly of silica, magnesia, lime,
alumina water and oxide of iron.
Asbestos gets it name from the Greek meaning unquenchable or inextinguishable,
because of it's natural heat resisting properties.
While
proven to be quite dangerous and is seldom used today, it was a major
component in many early compositions and insulation materials (because
of its fibrous nature and heat resisting qualities). It
is unaffected by oils, acids and alkali and can withstand high temperatures.
There are six different types of asbestos and two categories of rock
types that they fit into. Five of these (the more dangerous) are categorized
as amphibole and the remaining (chrysotile) is categorized into a
group of rocks known as serpentine.
The serpentine is not as dangerous as the five amphibole varieties,
because its fibers are softer and less likely to cause as much damage.
Amphibole asbestos becomes a danger when the long thin brittle microscopic
fibers break and become air borne. The fibers do not easily dissolve
or breakdown and they can remain airborne for quite some time.
The fibers will eventually settle into soil, dust, or other materials
such as carpet and can become air borne again. When breathed into
the lungs, the stiff hard fibers embed themselves into lung tissue.
It is because of their durability and stiffness that they will remain
in the lungs for long periods of time causing serious damage.
NATURAL
RAW ASBESTOS
|
What
does asbestos look like?
Here is a short movie about asbestos that I found on Google
movies.
It was published in 1959 by the US Department of the interior
- Bureau of Mines.
The film was made as an Introduction to Asbestos
It describes how asbestos is mined and processed. Using diagrams
and on location shooting, both open pit and block carving
methods of mining asbestos are described, followed by a detailed
examination of how the fiber is milled and undergoes its change
from crude ore to refined fiber. The remainder of the film
deals with the numerous ways this versatile mineral enhances
our daily lives, from roofing materials to automobile brake
linings. Note several mentions of dust control, but no specific
mention of the occupational asbestosis, lung cancer or mesothelioma,
diseases caused by inhaling asbestos dust. Asbestos manufacturers
knew of these diseases by the 1930s.
Here
are the six different types of asbestos:
|
Chrysotile
(serpentine rock)
|
Amosite
(amphibole rock)
|
Crocidolite
(amphibole rock)
|
|
|
|
Tremolite
(amphibole rock)
|
Actinolite
(amphibole rock)
|
Anthophyllite
(amphibole rock)
|
|
|
|
ASBESTOS
COMPOSITIONS
Asbestos
itself can maintain its mechanical
strength up to about 1,830°
F
and can recover itself after being cooled. It will melt and loose
its structure from 2,200 - 2,300°
F
When
asbestos
is used as the main inert ingredient in a composition, it can add
to the compositions hardness and sometimes help absorb some heat.
However, the melting point of the composition will greatly depend
on the binder being used to hold the composition together.
EARLY
KNOWN COMPOSITIONS & RECIPES
Below
is a short incomplete list of known compositions that used asbestos
and its derivatives
To view other
known compositions, patents, ingredients, etc., you
can view my known compositions lists on this page by clicking on
the link here.
Asbestos
Paper
Most of the manufacturers of all of the different types of insulating
products, branched into different uses. Paper that was covered, coated
or impregnated
with
asbestos. Vulcanized fiber and other insulating materials had their
paper products, which were used for many different purposes. These
different types of paper came in many different thickness and forms.
Thin sheets of this paper could be made bendable or brittle depending
on the use. Some products were made for lamp plugs to insulate and
cover the bottom between the prongs. Inside of sockets as liners,
wrapped around furnace duct work, etc.. Asbestos was used in thicker
fiber board as well as roofing which was simply a thick asbestos paper
product. Later asbestos paper and fiber papers (fishpaper) was replaced
by cardboard in socket liners as well as other insulations. Note worthy
is the fact that other papers such as vulcanized fiber is still in
use and being sold today.
Asbestos paper is manufactured using an asbestos base and is soft
and flexible with not much strength. It is hygroscopic meaning that
it will attract water molecules from it's surrounding environment
through either absorption or adsorption.
Asbestos paper can withstand a constant temperature of 500°
F
before breaking down.
Impregnated
Asbestos
While normally asbestos is used to either harden or give heat absorbing
properties to other ingredients in a composition, asbestos itself
is also commonly impregnated with different binders and/or chemicals
to add to its properties as in the treated paper below.
Treated
asbestos paper
A variety of treated asbestos paper that was known as Delta sheeting
was impregnated with a black insulating compound which softens at
about 240°
F
and melts at about 400°
F.
It is claimed that from 2,500 to 5,000 volts is required to puncture
it, in thickness of 10 to 25 mils
Some
patents for asbestos paper
234,417
- COVERING FOR STEAM-PIPES
Filed Sep 17, 1880 - Jane Meiiriam, of Milwaukee Wisconsin
Asbestos paper
310,205
Fabric for covering heated surfaces. — H. W. Johns.
Consists of ropes or rolls of fibrous materials, woven with sheets
of paper, sheathing
310,334
Asbestos paper.—S. Tingley.
A
sheet of asbestos paper is covered on one or both sides with
thin paper, coated with a salt, which will form a glaze when heated
to high temperatures.
Elastoid Fibre Was Asbestos Paper
While
on the topic...
Noteworthy is this quote for quality vs. money...
Did General Electric change from the good old vulcanized fiber
linings to cheap asbestos paper,
because they tested them and found them to be better? OR - Did
they at least check which one had better electrical properties?
Did they test them at all ??? OR was the move to paper ONLY
based on money?
Here (shown below) is a quote from G.E. in a court
hearing under oath...
That the "Only" reason for change to these new liners
was for the money |
...
EARLY ASBESTOS COMPANIES & ADVERTISEMENTS
|
Asphalt
- Bitumen (carbon,
hydrogen, and oxygen)
Also Known As:
Asphaltum, Asphalt, Asphalte,
Glance Pitch, Gum Asphaltum, Trinidad,
Elaterite, Gilsonite, Byerlyte, Emtage and Manjak
Natural
Viscous Liquid -
Bitumen 90 to 100% Pure (except bitumen with a low petrolene
content)
Natural
Plastics
- (Bitumen 30 - 90% Pure
Just
as a starting point: Bitumen or
the use of it is
nothing new, as we read in a real old book (the bible) "Make
thee an ark of gopher wood; rooms shalt thou make in the ark, and
shalt pitch it within and without with pitch.". (Genesis 6:14
KJV)
The
English word "pitch" is from the Hebrew word "kopher"
which is bitumen.
Also, sometime before 562 B.C. Nebuchadnezzar, a Babylonian king,
used it to pave a short ceremonial roadway.
The
most popular source of bitumen closer to our days and times (19th-21st
century), would be the Trinidad pitch lake which is shown in the
first photo on your right.
The Trinidad lake actually sits over the throat of a (so called)
extinct volcano.
This 114 acre lake of asphalt (bitumen combined with clay), has
been producing an endless supply of bitumen now for hundreds of
years.
It produces both hard and soft bitumen of which is strong enough
to walk on.
Even though you can safely walk on the soft areas, if you parked
a car on it, you would not be able to find it within 48 hours.
Also,
workers can remove a large section of a foot or two deep and within
no time at all, more bitumen bubbles up to take it's place.
This lake was known by Christopher Columbus in the 1490's, but did
not pay it too much commercial attention since his main interest
was in finding gold.
About another 100 years later, Sir Walter Raleigh was given a tour
of the lake and he immediately recognized the value of the discovery
for caulking his ships. He noticed that it didn't melt in the sunlight
like the traditional Norway pine pitch they were currently using.
Even though he noticed it's value, it did not develop into any significant
world wide interest for the product.
About
150 years later (In 1849), the potential of Trinidad asphalt was
seen by Admiral Thomas Cochrane, the Earl of Dundonald, who commanded
the Royal Navy’s West Indian squadron. He was a man with endless
imagination and energy, which is seen from the large number number
of inventions credited to his name. One of his early inventions
was a new kind of street light. He tried to use the bitumen to pave
streets, but he never figured out how to process it properly and
his efforts came to a sad failure. However his testing sparked interest
and others began to test it and work on these processing issues.
A little over a decade later in France a way to process it successfully
was invented. It was in the 1880's that its real industrial use
began along with using it for electrical insulation and making up
different compositions both insulating and for paving.
By
1900, Trinidad was exporting thousands of tons of raw asphalt to
the United States and was fast becoming a favored material. In
the early days (1880's and early 1900's) there was much about bitumen
that
was still unknown, which caused confusion about it and products
that were being developed. It was because of the fact of
people (including chemists of the time) not fully understanding
exactly what it was that the term "asphalt",
had been so misused during these early days. At the time any black
sticky pitch material that could be melted down and used as a binder,
was being
called "asphalt".
Bitumen can
be found in geological formations all over the world, and
will always differ one from the other in their chemical composition
and properties. They all however share the luster and shinny appearance
of a pitch.
Petrolene
Content
Pure
bitumen
is considered a viscous liquid. However, as it becomes less pure
(or has a low petrolene content) it is categorized a harder solid
with much higher melting points. A sample being termed "less
pure" is not a bad thing, as it still has a content of "pure"
bitumen with the remainder being all organic substances. This means
that a sample can be processed or refined to a much better quality,
all depending on the need and what product is being made. Bitumen
with a low petrolene
content would not only be much harder and brittle, but also melt
at much higher tempters. For this product to be of much use, it
would need to be refined by having petroleum "residuum"
and or heavy oils added to it.
Bitumen
refers to the natural mineral without the addition of foreign substances
or pitches.
Asphaltum
refers to the mineral pitch that is of a higher grade then asphalt,
but still not as soft as pure bitumen.
Asphalt
refers to the natural but less pure (harder) samples of bitumen
of which the most popular would be Trinidad.
Note that asphalt (as well as the others shown above) also includes
the refined product. Refining is simply where different processes
are used to separate some of the natural impurities, to produce
a more pure bitumen.
Asphalte
refers to natural limestone that mixed with natural bitumen
Asphalt Products
& Trade Names are materials in which real
Asphalte (those shown above) are purchased and then mixed with other
ingredients making up different compositions.
Asphalt was used in the manufacture of insulating varnishes, japans,
impregnation of non-waterproof insulating materials, insulated covering
for cables and as a binder for different molded compositions.
Pure bitumen consists of carbon, hydrogen, and oxygen with the properties
close to carbon 85, hydrogen 12, and oxygen 3.
Bitumen's share a color of deep black, with a slight touch of red.
When at boiling temperature it has a strong aromatic odor.
Pure Bitumen
- Melting Point 120°
F
Under
50°
F it is solid and brittle
From 50 to 70°
F
it
is soft and plastic
From 70 degrees to 90°
F it
has a pasty consistence
From 90 degrees to 120°
F it is glutinous
Over 120°
F
it
is liquid
The gravity is about 1.03
Depending on the purity level and what the exact composition of
the actual natural bitumen is, there will be different melting points.
Also, taking into account of trade products and recipes of different
compositions, some inert ingredients can either excelerate or slow
down melting points. From testing that has been done in the past
we can at least derive at some basic ranges, even though some may
be spread far apart because of such quality differences.
Pure
Asphalt
(meaning bitumen that is in solid form) softens
at from 195 to 210°
F
Byerlyte (certain grades) melt
at temperatures ranging from 200 to
350° F
Gilsonite has a melting point
that varies varies from 230 to
400° F
Here
are some tests that I have compiled together, to give the reader
a basic concept of the purity or hardness of different sources and
locations. You can use the above melting and softening points of
pure bitumen as a reference, as well as the following:
Bitumen that is from 90 to 100% pure normally ranges from a paste
type consistency to a very thick liquid. Also, bitumen that is from
90 to 30% pure, ranges from pasty to hard and brittle.
Note that there are samples of almost pure bitumen with a low petrolene
content,
which makes the more pure sample harder, as well as raising the
melting point.
Source
/ Sample / Type |
Bitumen Present
|
Melting
Point
|
Properties |
Trinidad
Manjack |
95.25
|
428°
|
not
available |
Barbadoes
Manjack (Merivale) |
97.0
|
420°
|
0.68
organic dust, 2.32 ash |
Trinidad
Glance Pitch |
88.0
|
360°
|
4.56
organic dust, 7.44 ash |
Mexican
Asphaltum |
99.5
|
140°
|
mineral
matter (ash) 0.3, carbon 0.2 |
Utah
Gum Gilsonite |
99.4
|
300°
|
mineral
matter (ash) 0.5, carbon 0.1 |
Bermudez
Asphalt |
94.0
|
180°
|
mineral
matter (ash) 2.0, carbon 4.0 |
Bermudez
Asphaltum, Refined |
91.22
|
150°
|
mineral
matter (ash) 4.50, non-bituminous organic 4.28 |
Standard
Asphalt, California |
99.5
|
180°
|
mineral
matter (ash) 0.3, carbon 0.2 |
Trinidad
Natural |
56.0
|
190°
|
mineral
matter (ash) 36.8, sulphur 6.5, carbon 0.7 |
Refined
Trinidad Pitch |
51.81
|
192°
|
carbon
9.72, ash/earth 28.30, sulphur 10.00, water 0.17 |
Refined
Cuban (soft) |
64.03
|
115°
|
carbon
7.98, ash/earth 19.51, sulphur 8.35, water 0.13 |
Refined
Cuban (hard) |
8.34
|
160°
|
carbon
66.03, ash/earth 16.60, sulphur 8.92, water 0.11 |
Cuban
(crude pure) |
75.1
|
240°
|
mineral
matter (ash) 21.4, carbon 3.5 |
Grahamite |
94.1
|
cokes
|
mineral
matter (ash) 5.7, carbon 0.2 |
EARLY
KNOWN ASPHALT COMPOSITIONS & RECIPES
There were many different compositions that used an asphalt
binder.
The most popular would be common roofing materials, however molded
electrical items and supplies were also used widely at a really
early date.
Stephen
Allen
My first example would be it being used with a type of vulcanized
fiber invented by Stephen Allen of Woburn (and later Duxbury) Massachusetts.
Allan was a long time paper manufacturer (see patent no. 38,020
March 1863), started improving his products and inventions in patents
1880 and 1881 where he started making his 'leather' product by mixing
fiber rags, paper, bark and other ingredients with asphalt which
was his process. His basic bitumen / asphalt base composition invented
and patented Jan. 1883 (patent no. 278,481)
material for roofing purposes, was now being molded and used for
electrical conduits (patent no. 284,794
July 1883) calling it "a composition". The product was
much like rubber and hard rubber and could also be vulcanized. By
1885 as seen in patent no. 337,472
he is now far underway molding and casting many different shapes
for a variety of different electrical uses.
(also see a note about this composition here)
Edison
Asphalt
based compositions were not new to Edison,
as his use of these materials predate his electrical inventions.
In the early years Edison experimented and used different compositions
for his other inventions, such as his phonograph in the late 1870's.
I
can document several uses and testing of different asphalt
binding compositions through the electrical years, but the best
example is a laboratory notebook that I found belonging to Charles
Batchelor (shown right).
The entire notebook contains his experiments and notes which were
written in his own hand, with exception to the first page.
The first entry was by Edison in which he wrote some instruction
about a molded composition.
Edison told Batchelor that he could get a sample of the molded material
from Bergmann (he gives his address).
Edison then describes the molded material as made from hard asphalt
(Cuban or Syrian) mixed with a large percentage of kaolin
(a natural clay material). It is then pressed in a hot polished
brass mold from about 350 to 450°
F.
NEW added
In the section for the Bergmann moving tongue socket no. 2, I took
some more time to cover the topic of 'Lava' and bring up some additional
points, as well as a few more documented references of in use asphalt.
You can go directly to this section and part using this
link.
Below is a short incomplete list of known compositions that used
asphalt, bitumen and its derivatives
To view other known
compositions, patents, ingredients, etc., You
can view my known compositions lists on this page by clicking on the
link here.
EARLY ASPHALT COMPANIES & ADVERTISEMENTS
|
LAVA - Artificial
Lava
/ Lavite / Soapstone / Steatite
/ Talc / Etc...
|
You will also want
to cover the topic of soapstone, since there
is so much confusion on this topic.
Even when it comes to actual "Soap Stone" and it being used
as an insulator can be confusing, since it was most always used in
a composition form after being ground up into a fine powder.
Volcanic
Lava
It was this first topic that got me started researching different
stone and rock, in hopes to identify an early insulating material
in an Edison / Bergmann patent (311,100)
that was being called "Lava" (talked
about on the site here). Then again describing yet another material
as "Soap Stone" in another Bergmann patent (341,723)
for a switch, .
A serious problem in my mind came up, when the fragment test samples
from both materials melted during low temperature testing. Of course
the raw materials withstood the testing, which sent me down the
long road of learning about different compositions. In some cases
(such as soap stone) there were compositions being called by raw
materials name. Then in other cases (like lava) the composition
was just named lava for it's properties or appearance, without having
any actual "lava" content at all.
I
am not a geologist or an expert on different types of rock, but
I have now done lots of research and have put in many hours of reading
and study on the topic. I learned that different types of Lava rock,
are grouped together into one category called "Igneous"
(Latin for fire) rocks. While these are all 'lava' - each varies
a bit in texture and color.
When I first started my study, I read the comforting quote:
"At the most general level, rocks fall into three great categories,
and they're pretty simple to tell apart. You won't even need a rock
hammer or hand lens, though those are fun to have."
The three basic categories of rocks which are: Igneous Rocks, Sedimentary
Rocks and Metamorphic Rocks.
Once you identify what category your rock is, the rest is a cake
walk.
In this case "Igneous Rocks". These Igneous rocks now
break down into three more categories which are easy to tell apart
by the coloring, grain size, texture and hardness.
Artificial Lava
After spending so much time and learning all about real 'Lava' stone,
you can imagine how disappointed I was to learn that Bergmann did
not use "lava stone" at all as we know it today.
During this time (early 1880's) some electrical supplies were being
made of a newly invented composition and manufacturing process,
named in it's patent as "ARTIFICIAL LAVA". However, an
important fact is that it was made from soft metamorphic rocks and
not the igneous rocks that someone would envision.
This substance can, and has, caused confusion for those of us reading
patents by different electrical manufacturers.
Namely those that specify in their patents that they are using an
insulating material such as: soap stone, lava, steatite, talc, etc..
The reason being is that ALL of these terms can also be referring
to the "Artificial Lava" invention. Even though soap stone,
steatite or talc is really soft and can be easily tooled, it is
almost always referring to it as ground up and mixed into a composition,
and almost never the real raw materials that we all think of. In
the case of "lava", I have never read once so far of it
actually being used in any composition. It is a stone that would
be extremely hard to work with.
After talking to other researchers on this topic, it is also even
more clear that the term "Lava" was used extremely loosely
in the day. This looseness of terms could have made it possible
for Bergmann and others to identify or call different insulation
materials by the wrong substance names.
WHY ALL OF THE CONFUSION?
- More about Artificial Lava...
When you think of LAVA, you would automatically think of an igneous
rock that is already known to absorb heat.
You would envision a rock that is hard but porous (with a texture
like that of a piece of hard bread), that easily chips and breaks.
You would NOT be thinking of metamorphic rock or mineral such as
soap stone or steatite (the softest stone known) which is so soft
that talcum and baby powder is made from it.
The fact is however, that soap stone, steatite, talc and artificial
lava are all basically the same thing.
Even though these are the same mineral, the differences in the names
simply identify how they vary in quality or softness (talc content)
and to identify different grades (which are then used for different
products). For example a real soft stone could be used for powder
or carving art pieces or statues, while a harder less pure sample
would be used for a table or laboratory counter top.
I have now collected and tested different samples of this stone
from all over the U.S.A and the world to examine and identify different
qualities, colors and properties.
I will provide my soap stone research in a few minutes and then
show how it all compares and points to artificial lava.
As
already stated above, there was some confusion being brewed as seen
in some patents and publications of the time.
While researching, you will read where some inventors or manufacturers
of different electrical supplies prefer to use "soapstone",
while in another you might read "talc", "steatite"
or "lava".
Note of course that there are also other insulating materials mentioned
such as ebonite, hard rubber, wood, glass, porcelain, different
types of fibers, (and the list goes on and on), but for now we are
only interested in this lava term.
After some time had passed (about a decade), it is evident that
at least one person (Burton E. Baker of New Britain Connecticut)
thought it important enough to point out what exactly he meant by
the term "lava" in his 1894 patent no.
526,605. This is shown in a partial capture from the patent
shown on your right and linked above for anyone wanting to read
more of it.
So, here (as shown above on your right) we read that it was a "well
known" product in the day, and that it was being sold "under
the name of lava".
Evident is the fact that Mr. Baker knew that it was NOT "lava",
but only being called lava (obviously for marketing purposes).
Basically
there are two patents to read if you wish to learn more about this
"artificial lava".
It was an invention of Demetrius Steward who formed the D.M. Steward
M.F.G Co..
The first patent that Steward filed for this artificial lava was
August 22nd 1882 which was approved on February 6th, 1883. It was
assigned patent
number 271,994. On May 1st 1883,
Steward made some additions to his first patent and had it reissued
which was approved on June 19th 1883 and then assigned the new patent
number RE10,344.
It is important also to understand the scope of this
Notice that in the above announcement in The Electrical Engineer
that Steward is praised as the inventor of 'lava' insulators and
that at this time in 1895 "Millions" are in use.
Within a short time other "lava" companies and businesses
started, battled had legal issues, etc..
The two largest and most popular of these companies after a decade
were the DM Steward M.F.G Co. and the American Lava Company both
of Chattanooga Tennessee.
By this time we RARELY see the terms "ARTIFICIAL
LAVA", in fact, just the opposite as seen below
The
above is acceptable only if read in the context of ...the lava that
we have been using on electrical supplies for years, is not real
"lava" like everyone thinks. It is really a mineral called
talc and not "lava" at all!
Next we have a definition from the Standard handbook for electrical
engineers published in 1908 by McGraw N.Y.
"Lava"
is not a
mineral called TALC.
Talc is a completely different class of rock then lava.
If they were both at least in the same class of rocks, it would
be like calling a german shepherd dog a poodle.
They would both be dogs, but completely different breeds.
However, in this case it is like calling the German shepherd an
alley cat.
Just as all are animals consisting of dogs, cats and horses, are
these rocks that split into different groups.
Lava is one of a 'bread' of Igneous Rocks (dogs) and soap stone
is one of a 'bread' of Metamorphic Rocks (cats).
I apologize if you may feel that I have gone overboard on this topic,
as I rightly do feel some righteous anger on the topic.
Rightly, "Simulated" OR "Artificial" Lava (which
in my opinion does not even have the right to be named such)
is a mineral called TALC.
DM
STEWARD ADOPTS THE NEW TRADE NAME "LAVITE"
|
LAVITE
In May of 1902 Steward took on a trade name for his simulated lava
product, now officially calling it Lavite.
Around this time the D,M. Steward Manufacturing Company supplied the
following information: Lavite is a light buff or cream-colored insulating
material, Density, 2.5 to 2.7; electrical resistivity, 500 to 2.500
megohm-cm.; disruptive strength, 200 to 250 volts per mil; modulus
of rupture, 6.000 to 12,000 lb. per sq. in.; compressive strength,
20,000 to 30,000 lb. per sq. in.; compares with glass in hardness;
not affected by temperatures up to 1,000 deg. cent.; unaffected by
acids except aqua regia.
SOAPSTONE - Soapstone
/ Steatite
/ Talc / Etc...
|
SOAPSTONE
You will also want
to cover the topic of Lava, since there
is so much confusion on this topic.
Even when it comes to actual "Soap Stone" and it being used
as an insulator can be confusing, since it was most always used in
a composition form after being ground up into a fine powder.
Soapstone comes from the third category of rock called Metamorphic
Rocks.
There are two different minerals popularly called soapstone.
These are steatite and talc.
Soapstone basically gets its name from being a soft stone with a smooth
feeling texture.
You can run your fingers across a piece of raw soap stone and feel
how smooth it is (like a dry bar of soap).
STEATITE
Steatite soapstone is a harder stone because while it does contain
talc, it is also composed of several other minerals which makes it
a harder stone. Being the "harder" soapstone, it is mostly
used for sinks, flooring, countertops and other architectural applications.
Soapstone is impenetrable, it does not stain because liquid can not
permeate its surface. This is one reason why soapstone (steatite)
is commonly used in chemistry labs and acid rooms.
Also, noteworthy is that steatite in its initial raw form, only comes
in shades of gray.
Talc however can be found in a variety of different colors from light
or white, then moving through different shades of grays, greens, reds
and browns that are translucent to opaque (Talc also has a greasy,
soapy feel).
TALC
The more popular type of soapstone is talc (without many of the added
minerals that steatite has).
Talc is the softest mineral on earth when ground up into a fine powder.
It has been used in the manufacturing of tooth paste, baby powder,
chewing gum, lubricants, cosmetics and countless other applications.
This softer more high grade stone is most popular for carving sculptures
and has been used as such since ancient times.
A FEW EXAMPLES OF SOAPSTONE
TESTING FOR SOAPSTONE IN COMPOSITIONS
A good test that I have discovered that has proved to work for compositions
with a high soapstone/talc content, is LIGHT.
When comparing soapstone to lava, fiber, or other composition type
materials (which are not translucent at all), only soapstone will
allow the light to pass through it. However, please keep in mind
that all soap stone is not the same and all is not translucent.
For this reason, I can't guarantee that this light test will work
on all soapstone samples. Also it is possible that other compositions
could be transparent, such as Bakelite which came around years after
these Bergmann items.
It has however helped for these Bergmann examples, as well as an
1886 Westinghouse socket and a Schaefer socket dated 1885. Both
of these I had previously thought to be brown fiber or other type
of composition material. So, needless to say, I will be updating
the main web pages with this new find as well as starting a project
to identify different composition materials and how they were made.
I
had the idea for this light test when I noticed that a Bergmann
switch (the type that was first applied for patent on Jan. 8th
1883 and assigned patent no. 341,723) claimed to use "soapstone"
for the base (as shown below).
I had one of these that had a broken base, but never really
paid much attention to it before. I now had an intense interest,
because (unlike my sockets) I had something that I could carve
a small sample off from to experiment with.
|
|
|
The
first thing that I noticed from some small pieces that easily broke
loose (shown on your right), was how translucent they were. It was
also easy to notice on the switch base edges and a hole had been
previously drilled.
The second thing that I noticed, was how easy it was to cut or carve
from the edge of the base. You could not do this with the lava or
many other hard compositions. In fact when I was testing lava, I
stroked an edge part with a fine metal file. When I blew the dust
off the spot, it had not even left much of a scratch.
While carving or shaving the soapstone, I also noticed the obvious
talc flakes and soft powder residue. As shown below on the left,
small flakes that look and feel like soap. On the right seen on
the side of the base a fine talc powder type residue.
|
|
Shown
on your right is the switch after running the carving and chipping
tests.
I provide this picture so that you can see that it was a smooth
easy cut / carve, which ends up only being a new shape on the carved
item with no real distress.
I do not recommend this kind of testing on your sockets. I was happy
to have this broken switch of which I donated only one small corner
edge for experimenting. I have talked to some that have tested small
areas of their unknown materials with a small fine file or knife.
PLEASE, do not do any damage your sockets. Try using the light test
below, which works great for soapstone and matching the colors.
If light does not shine through, the rest of this page should help
with nailing down what materials you have in your socket.
If by chance you find a material not shown on this page, please
contact me with good pictures and descriptions. I will do my best
to help you identify any unknown materials that you may come across
on any Bergmann item.
HEAT TESTING
I should also mention that I will be adding my heat tests at a later
date for lava, soapstone and other compositions. My heat tests will
include both softening and melting points of different compositions,
as well as demonstrating how different properly vulcanized hard
rubbers can be heated to a few thousand degrees and then recover
and be used again (while other substitutes and less expensive imitations
just melt away). The point here though is that in my soapstone heat
and flame testing, my ground/powdered talc will glow red and not
combust or burn away into nothing. This soapstone composition does
the same after the binder melts away and consumes, the talc that
is left just sits there and glows red for ever.
MY SOAPSTONE LIGHT TEST
For this
test I use a powerful LED 115 lumens flashlight.
When testing actual sockets, you will need something strong enough
to focus a powerful beam of light directly into a small area. For
example: I tried some Bergmann sockets (with threads attached) in
all different directions; through different holes or spaces, and
got ZERO results.
It was not until I took the threaded sleeve off (the one held by
two screws) that I got any results at all.
So, I guess I am saying is that if you are testing, be sure to use
a strong enough light. Also, to be sure to get right up to the edge
of your item (touching your light to it and holding it at different
angles) to get proper results.
On the switch test example below, I actually set the switch on top
of the flashlight and shine it through an empty hole.
MICROSCOPE
PICTURES
Here are some captures of some shavings taken from the
switch base above, compared to shavings from a raw soapstone sample
under a microscope. You will mostly notice the talc right away,
which is the white soft flaky material. Next when different levels
of light are put to the samples you will notice that there is no
possibility of this being anything else but talc.
Other soapstone and talc samples match up to color as well, as you
will notice while comparing the raw
soapstone pictures shown above with the sample
sockets that I show below.
SOME SOCKET TEST EXAMPLES
MOVING TONGUE #5 USING SOAPSTONE
|
EXAMPLE
OF DARK SOAPSTONE PATINA
|
|
|
EXAMPLE
OF GRAIN WITH SOME DIRECTED LIGHT
|
LIGHT
TEST EXAMPLE SHOWING TRANSLUCENCE
|
|
|
|
|
EXAMPLE
OF A BERGMANN PUSH SWITCH USING SOAPSTONE
|
|
|
EXAMPLE
OF VARNISHED COATING AGED & BLISTERED
|
LIGHT TEST EXAMPLE SHOWING TRANSLUCENCE
|
|
|
SKINNY BERGMANN ROTARY USING SOAPSTONE
|
EXAMPLE
OF SOAPSTONE PATINA
|
|
|
EXAMPLE
OF SOAPSTONE TEXTURE BY CHIP
|
LIGHT
TEST EXAMPLE SHOWING TRANSLUCENCE
|
|
|
1885 SCHAEFER SOCKET USING SOAPSTONE
|
THE SOAPSTONE INSULATING PLATE
|
|
|
EXAMPLE
OF ITS TEXTURE COLOR & PATINA
|
LIGHT
TEST EXAMPLE SHOWING TRANSLUCENCE
|
|
|
1886
POPE, BYLLESBY & LANGE USING SOAPSTONE
|
EXAMPLE
OF ITS TEXTURE COLOR & PATINA
|
|
|
LIGHT
TEST EXAMPLE SHOWING TRANSLUCENCE
|
|
WHAT
IS VULCANIZED FIBER
The best place to start might be the correct spelling of "fiber"
or "fibre" of which both are correct. The spelling more
common in the early days was "fibre" which is of a French
origin and the way someone in the UK or Canada still spells it today.
Our way of spelling "fiber" here in the United States is
of a Germanic origin. It is also the way most European countries without
a Latin language origin such as Germany, Holland, Denmark, Sweden,
Norway, etc. will also spell it. The correct English (UK) spelling
is 'fibre' just as our early spelling was. I do not know when it changed,
but in this case it does not make a real difference on this page,
as along as you are aware that we are talking about the same thing.
There is no difference between the product fibre or fiber, other then
the spelling(.) Since we are dealing with history as well as company
names, products, advertisements and quotes which spell it both ways,
I bring this point up first so that the reader does not go crazy trying
to make sense out of it.
Vulcanized
Fiber was (and still is for the most part) very widely used. In the
early days It was made of cotton based paper pulp, which was chemically
dissolved (using zinc chloride) and solidified under enormous pressure.
It was not soluble or harmed by ordinary solvents such as alcohol,
turpentine, ammonia, etc.
It first came out in the early days as both hard and flexible or soft
fiber.
The hard fiber resembled horn and was exceedingly tough and strong,
while the flexible fiber had the appearance of a very close grained
leather. It worked great as an insulator in dry places, but because
it absorbed moisture it did not work as well in areas that were damp
or out in the weather. For this reason it is common to see vulcanized
fiber parts that are varnished or shellacked (shinny looking), as
shown the close up picture of the tack on your left. As you can well
see, this tack had been coated to protect it from moisture.
Vulcanized fiber was made in three basic colors
which were red (the most common and most loved), black and or gray
(which was made to look like hard rubber) and white, which was marketed
as an imitation horn product. Brownish gray was also common for the
imitation leather vulcanized fiber products which came in many other
colors. A sample of the soft red vulcanized fiber (fish paper) is
shown to your right, which was used to insulate tacks used to safely
nail down and hold wires in place. Those shown here are the same design
and patent as invented by Charles Chandler Blake as seen in patent
no. 662587.
Noteworthy is an early patent for this basic concept by Luther Stieringer
(patent no. 420635)
where he uses a coating of black japan insulation over the nail and
the insulating material (called a "saddle") which the patent
instructed could be made of "wood or vulcanized or gelatinized
fiber".
DIFFERENT
TYPES OF FIBER PRODUCTS
As stated above, vulcanized fiber was an invention made from paper
and or paper pulp, however later some fiber inventions also added
different vegetable fibers and vegetable based textile fabrics. The
list in one later patent included the following substances: "By
this process all forms of vegetable fiber or tissue may be treated,
such as sized or unsized paper, paper-pulp, whether from rags, wood,
or other material, cotton - wool, lint, and cotton - shoddy; also,
fabrics made from any of them".
In a nutshell for starters (I will go into more detail below later),
there was hard fiber which was most always marketed as a substitute
for hard rubber. In the early days (1870's and early 1880's) this
product was simply known as "vulcanized fiber".
As more manufacturers came onto the scene (mid 1880's), different
manufacturers had their own names or trade names for vulcanized fiber.
For example "vulcanized fibre", "hard fiber",
"horn fiber", etc. The many different types of fiber products,
company names and their advertising, can be seen in the trade
names below and at the bottom of this section
in the adverts.
In the early days there was a war on trade names where one would be
called 'vulcanized fiber' another 'horn fiber', 'kartavert', laminar,
etc.. It was not until a court case with 'indurated fiber' that they
woke up to the fact that these trade names were not really legal.
It was not until this landmark case that
insulating materials could safely start being called what they were
by any manufacturer, without the fear of infringement of a broad trade
name.
When hard vulcanized fiber first started being made, it was thought
of as a 'great product' and was widely received as the "latest
and greatest". Almost every person or company that used it, developed
a great love for it, its colors, texture and all of its uses in general.
As time went by and improvements were made, it is noteworthy that
some improvements were only called 'improvements' in order to get
around patents or current registered trade product names. I also personally
believe that some inventions were simply accidents that were understood
by others and then later improved on. The first real improvement was
the invention of gelatinized fiber.
Gelatinized fiber was a new type of 'higher quality' fiber. It started
to become more popular among those that already loved the regular
vulcanized fiber, as well as creating many more converts to fiber
in place of hard rubber. Gelatinized fiber was the first vulcanized
fiber that could be molded since it no longer used layers of paper.
This new fiber was also at first called by a trade name which was
"gelatinized fibre". As this new type of composition fiber
began to catch on, other manufacturers developed their own recipes
for similar gelatinized products. Later as knowledge increased, gelatinized
fiber (in general) progressed to an even harder and cleaner product
of which (for the most part) had an all cotton composition. This fiber
was again called by different trade names such as "vul-cot",
"egyptian fiber", etc.. Some of
the softer fiber products were called fish paper, trunk
fiber, letheroid and mostly marketed as imitation leathers or
insulated paper products. For example the insulating staples as shown
above. For more information, see the
item below under gelatinized fiber.
So the basics of product quality and product progression over time
went from:
(1). Paper sheets pressed together
(2). Scraps and paper, pulp, linen, etc. being ground up into a powder
for molding.
(3). To a cotton like paste that could harden more solid, and hold
together much better then those products before it.
There were still some applications and products that required different
types and manufacturing methods of vulcanized fiber, this quality
progression timeline is only meant for the gelatinized type of fiber
compositions. Each manufacturer had a full line of different fiber
products, which were used by different industries.
FIBER
USED FOR ELECTRICAL SUPPLIES
|
You
will find many different uses for all of the different kinds of fiber
products down through the years. In the early days (pre-1890) both
vulcanized and gelatinized fiber was used for socket innards until
porcelain became the favorite and standard insulating material for
that purpose.
It is important to know however that even though vulcanized fiber
products were at an end for socket insulators, it was just beginning
for many other uses.
A good example of this would be products of special uses such as nonmetallic
bulb guards.
Some industries require protection while at the same time need to
remain 'spark-proof'. Factories that were full of fumes needed to
be 'vapor proof' to prevent explosions. For this glass screw on and
air tight covers were made for fixtures in case bulbs were to break
or to explode. For portable work in places like these, metal guards
would have been to dangerous as they could short against terminals
and create a spark. Another example would be flammable places such
as auto garages or gas stations. Using metal guards in places like
these could also cause sparks and possible fires. For anyone that
was cautious in these areas Benjamin Electric Co. sold a nonmetallic
guard that was made of red gelatinized fibre. Benjamin started selling
this guard in 1907 and is still found decades later in their 1941
Benjamin Catalog.
While Benjamin used hard fiber for this product, other companies that
produced soft fiber products (such as letheroid or trunk fibre) found
no problems with producing the same type guard using their materials
as shown below. Benjamin used fiber in some of their plugs, it was
also used on many other items such as meters that had test leads or
parts that needed to be shaped, tooled, etc.. Gelatinized fiber was
mostly used for these tasks also because of it being able to be highly
polished. The red color is almost always a dead giveaway, but sometimes
when horn or ivory is to be imitated white would be used (also black
to imitate popular hard rubber products).
Below is only a small number of examples for different fibre uses.
VULCANIZED
FIBER TYPES AND COMPANY PRODUCT TRADE NAMES
|
VULCANIZED FIBER
Vulcanized
fiber was the first and original product of the first "Vulcanized
Fiber Co." And was used commonly for many different commercial
grade applications, such as washers, gaskets, gears, handles, etc..
After incandescent lighting was invented and began to become popular,
this first invented vulcanized fiber product was also considered to
be "electrical grade" fiber. However, a new gelatinized
fiber was invented which (in the electrical world) quickly became
the new "electrical grade" fiber. Later, when gelatinized
fiber products made from 100% cotton started to be advertised, it
became what was termed "electrical grade" fiber. This newest
cotton fiber could also be more flexible and suitable for layer and
ground insulation. Though other materials quickly replaced vulcanized
fiber for electrical switches, sockets and other uses, it is still
being made today and widely used for different electrical purposes.
As shown in the picture on your right, it has not changed too much
when compared with a sample from 1886 (bottom), and a thin sample
of fish paper that I obtained new in 2009 (shown on the top). Fish
paper came in many different thicknesses, and is simply thin layers
that was used for old style plugs to slip over the prongs and cover
the wire and screws, insulation inside of socket shells, etc.. Fish
paper was made from rag stock that was put through the chemical treating
process, which caused it to become a hard (but flexible) fiber-like
paper which was very strong.
GELATINIZED
FIBER
Gelatinized
fiber was an invention of William Courtenay and first sold by himself
and a partner (William Trull). They sold the new gelatinized fiber
in their business partnership which was called the Courtenay &
Trull Co.. It was gelatinized fiber that basically solved many of
the problems that vulcanized fiber had. While vulcanized fiber could
not be molded, it could be cut, filed, drilled, etc. However, it had
serious problems with chipping and cracking. Gelatinized fiber was
the first vulcanized fiber that could be molded into a composition.
The Courtenay & Trull company merged with the Vulcanized Fiber
Co. which gave them strength as a larger company to get through some
hard times (which you can read about here).
I believe that (as the patent says) that Courtenay did not want to
waste scrap pieces of vulcanized fiber. So, he found a way to put
them to use by grinding them up "into a fine powder" and
then using them in a vulcanized fiber composition. This also allowed
him to use other useful ingredients in his 'soup', namely: "graphite
or plumbago" (which added hardness), "ground resin 'or pitch,
any of the resinous gums" (which provided a high gloss and made
it impervious to moisture - it also acted as a binding agent being
mixed throughout and later hardened under heat and pressure), "sawdust,
hemp, jute, silk, linen threads" (added greatly to the toughness
and tensile strength), "talc, and a variety of other materials"
(varying according to the purposes for which the goods are intended).
I am sure that you can see now why this new gelatinized fiber made
such a big hit, when compared to normal vulcanized fiber. In fact
a large enough hit to cause a merger
and partnership with the vulcanized fiber company. While I am not
really sure if Courtenay really understood the importance of his invention
and the real reasons for it's successful composition makeup; It was
the grinding into a fine powder that really gave it the hardness as
well as the crushing and tensile strength above other products. The
more uniform or sorted the grains are, the closer the grain can bind
together producing a homogeneous hard and solid product.
The
old vulcanized fiber used layers of sheet paper which was homogeneous
itself as far as each sheet, but as you compressed several sheets
together and hoping for the best binding chemical reaction, it was
always lacking in the end result and never perfect. In time as many
other new compositions were invented, these basic principals of well
sorted materials were understood. Later hard gelatinized fiber was
improved and became the norm for all different fiber companies as
a high end product. The basic improvement was simple as it became
a cotton product that basically became one big joined mass of hardened
cellulose.
WHAT
IS GELATINIZED FIBER?
The first product being made by the vulcanized fibre company was quickly
and constantly being improved, but keeping the same basic structure
as the normal layered and compressed vulcanized fiber.
It
was William Courtenay of New York that took it on himself to greatly
improve the fiber product structure with his inventions.
Courtenay was the inventor of gelatinized fiber (a Bergmann product
sample shown on your right). Gelatinized fiber became Courtenay's
exclusive trade product until later merging with the vulcanized fiber
company.
As shown in patent no. 217,448
applied for August 24th 1878, Courtenay found that he could grind
down and "reduce to a fine powder" scraps of vulcanized
fiber, paper pulp and many other materials namely graphite, plubbago,
ground resin or pitch, sawdust, hemp, jute, silk, linen threads, resinous
gums, talc, "and a variety of other materials" and make
a hard vulcanized fiber composition material. This was a great breakthrough
seeing that the current invention of "vulcanized fiber"
could not be molded.
This new fiber invention was able to be molded into a really strong
composition, which he called gelatinized fiber.
BERGMANN'S USE OF GELATINIZED
FIBER
Bergmann started using this material on moving tongue sockets starting
with no. 6 in our moving tongue lineup (also shown in the picture
above). While Bergmann experimented with other composition materials
(some of which were used on other products), gelatinized fiber was
the preferred material for moving tongue sockets until porcelain started
being used in 1890.
Below is a write up that was in Mechanics magazine February 17, 1883
talking about vulcanized fiber and the new gelatinized fiber that
they just compleated testing.
.
EXPOUNDING THE MECHANICS MAGAZINE REVIEW SHOWN ABOVE
"We recently obtained samples of what the manufacturers
call a '' gelatinized " fiber, which, while resembling
in many particulars vulcanized fiber, has developed several
new characteristics." |
While
compared to vulcanized fiber, this new gelatinized fiber,
was said to have properties "resembling" in many particulars
vulcanized fiber. It was also said that it had "developed several
new characteristics".
Lets have a closer look at these "new" characteristics
ALMOST EVERY CHARACTERISTIC
OF HARD RUBBER
"Samples of this material, which we obtained from Messrs.
Courtenay & Trull, 17 Dey street, New York, have almost
every characteristic of hard rubber, combined with many of the
characteristics of horn." |
The known and widely
used vulcanized fiber product of the day, was also marketed as a replacement
for hard rubber. However, just as many other products with this early
claim failed, vulcanized fiber could not honestly live up to these
boasts. Gelatinized fiber was an entirely new concept, which
in time may had proven to be a better and less expensive product then
virtually all other hard rubber substitutes being sold in the early
1880's.
COMBINED
WITH MANY OF THE CHARACTERISTICS OF HORN
Horn was a frequently used material in the early days, along side
of (but preferred over) ivory and bone. Bone needed to be purified
before use, during which it lost much of its gelatine content (as
well as a portion of its strength and elasticity). Ivory had less
of a gelatine content and needed to be seasoned (just as wood did).
It was also susceptible to shrinkage to a small extent, as well as
being absorbent to water.
For the most part horn had already been replaced by hard rubber since
about 1875, but it was cheaper and at that time more easier to come
by. For these reasons horn was still in use as a material for less
expensive common uses, or for temporary purposes.
The 'characteristics of horn' spoken in the article, likely meant
that (because of the fact of it having a high gelatine content) it
was easy to work with. People already knew about horn and its ease
of use, but also knew that it was not a long lasting solution (as
this new gelatinized fiber was proving to be). When horn was heated,
it could be easily carved with a common knife. Even in its cold state
it could still be fashioned using a saw or other grinding tools (as
well as being drilled or threaded for binding screws to it). In my
personal testing between vulcanized and gelatinized fiber, I found
the vulcanized fiber to chip and break apart during cutting where
the gelatinized fiber sliced and carved nicely without any issues.
"Besides
the red, which resembles a very fine and beautiful form of the
ordinary vulcanized fiber, it is also made in black and in white.
It takes a fine polish, cuts in a very pleasing manner, apparently
without any grain, although thin layers seem to be visible in
the white under the microscope." |
THE
RED COLOR IS THAT OF "ORDINARY VULCANIZED FIBER"
Here we find that it is much like "ordinary vulcanized fiber"
when it comes to the popular red color, that everyone became familiar
with and loved so much.
The white and black gelatinized fiber is not as noticed today, where
as red examples stand out more and is noticed as being used in many
different product examples through the years. Black gets often confused
with hard rubber and hard rubber substitutes, and white with different
compositions or horn and ivory.
If you are looking for early examples of all three colors, a common
source would be antique or early poker chips that are found in sets
of the three colors (black, red and white). There are also poker
chips made from clays and rubbers, but many sets using only these
three combinations will be gelatinized fiber. Later chip sets (after
1910) would be using a much higher quality of gelatinized fibre
made mostly from cotton. The Vulcanized Fibre Company called their
product trade name Vul-Cot, where other companies had high end products
such as Egyptian Fibre, Conite, Condensite-Celeron, etc..
EASY TO CUT & "CUTS...WITHOUT
ANY GRAIN"
It was said "It takes a fine polish, cuts in a very pleasing
manner, apparently without any grain, although thin layers seem
to be visible in the white under the microscope."
I will make a few points using the picture shown on your right,
of this broken (gelatinized fiber) insulating plate of a (circa
mid 1880's) Bergmann moving tongue socket.
First, notice that it has a gelatinized fiber insulating-tip,
shown sticking up out of the tongue slot. This was added to this
picture to display it's gelatinous nature. The back end of this
tip had a chip above the threaded screw hole, in which I cut using
the same cutting tool that I used to cut this sample in half. Without
any doubt, this is the same exact material.
Next, notice that the sample itself was cut with a normal dremel
cutting tool, across where it was naturally broken and chipped on
the right side.
You can clearly see that where it was cut, it would not require
any polishing or sanding whatsoever. Also, where it has been cut
shows NO GRAIN at all, being perfectly smooth.
In contrast, vulcanized fiber when cut, will chip and show many
uneven layers as well as gaps, pockets crevices and small holes.
This is because vulcanized fiber is made from paper layers, being
compressed together.
Gelatinized fiber is made from finely ground up pieces of
vulcanized fiber and other gelatinous ingredients, which are molded
together. The texture of the molded product is more like what you
might think of today in a piece of particle board, and the older
vulcanized fiber being more like a piece of plywood. However, because
of its gelatinous nature and very fine gelatinous particles, it
seals and smoothens itself along with the friction created.
IT TAKES A FINE POLISH
Unlike
the normal old vulcanized fiber, it was said of gelatinized
fiber that "it takes a polish". The old vulcanized fiber
was normally varnished. The varnish gave it a protective seal as
well as a glossy wet looking shine.
Next to the picture above, I asked that you call your attention
to the broken or chipped part, shown on the bottom right. If you
notice the texture, you will see that it does not have the air pockets
and gaps of normal vulcanized fiber which would give it a gritty
texture, with chunks or pieces falling off of it.
This chip can provide a great example of the statement that it "takes
a fine polish".
Notice the picture to your right. This is the same exact area as
shown above, which has been only lightly and quickly gone over with
a polishing wheel on a dremel.
As you can see, this is looking more and more like a miracle material
when it comes to working with it.
So far, it is not hard to understand the quote in this article which
says "One of the electrical papers says that it is the best
insulating material now procurable".
"It is somewhat lighter than vulcanized fiber, and can
be sawed, riveted, drilled or embossed, and takes a good screw-thread.
It seems to be entirely free from grit, so far as we can judge.
It is made in sheets varying from 1/4 to 1-32 inch in thickness,
and is so tough that the thinnest sheets do not break until
folded to a radius of perhaps 1/8 inch. The fracture is then
more like a tough metal than a stiff, solid substance." |
LIGHTER
THAN VULCANIZED FIBER
I am not sure if this quote is to point to color or weight. If weight,
I would not understand the reasoning as to why gelatinized
fiber would be lighter in weight, unless it has something to do
with the leeching process in which vulcanized fiber is dried and
compressed. During this process vulcanized fiber has the chemicals
used to produce it, drained and removed. The brain would think of
it as a more heavy material seeing it has its content ground up
into a powder, which would be more like a concentrated version of
the same ingredients. If color, it is more of a pail red when comparing
1880's Bergmann samples with other sockets that used vulcanized
fiber around the same time frame (for example Thomson-Houston).
However, many gelatinized fiber product examples
later in history have a much deeper red color. So maybe it was found
that color had more to do with sucess and there were changes made
to the product years later that gave it a darker red color. Note
that I have since writing this section purchased a nice digital
gem scale and have tested the weight. After cutting two exact and
precise size pieces, in my opinion there were no differences in
weight that would have been noticed.
CAN BE SAWED, RIVETED, DRILLED. EMBOSSED,
THREADED, ETC...
While vulcanized fiber did not thread as well as the gelatinized
fiber, it could be sawed and shaped, riveted, etc..
However, as shown above gelatinized fiber cut much better
not leaving any gaps. Also while being cut, it did not chip, flake
or crack as gelatinized did.
ENTIRELY FREE FROM GRIT
As said above, when being cut, there was no chipping or issues of
this nature at all. With vulcanized fiber, you could sometimes just
rub it hard and get small grit pieces falling off. This new fiber
was smooth and solid.
FRACTURES EVENLY
In speaking of fish paper for example, this gelatinized fiber
could be bent and then cracked or broken into two pieces with a
straight edge as if it was evenly cut.
HARD
FIBER
Hard fiber was basically the same as vulcanized fiber, only under
a different registered trade name. As far as companies go, there
were two different "hard fiber" companies and both in
Delaware. The American Hard Fibre Co. (of Newark Delaware) merged
with the original Vulcanized Fibre Company in which merger created
a new business name, now called the "American Vulcanized Fibre
Company". The Delaware Hard Fibre Company of Wilmington which
was created by Charles G. Rupert in 1888, later merged with the
Continental Fibre Company (which became a consolidation of the Diamond
State Fibre Co. In 1919).
EGYPTIAN
FIBER
D H Egyptian fiber was also a product of the Delaware Hard Fiber
Company. Egyptian fiber was their high end cotton gelatinized fiber.
D.H. Egyptian fiber was molded into special custom shapes to order,
as well as the common sheets, rods and tubes.
LEATHEROID
FIBER
In
the 1860's to early 1870's Emery Andrews was an inventor of matches
and match tip improvements, with over ten different patents credited
to his name during those years. In the early 1870's his inventions
were based on imitation leather products. The first of his inventions
centered around imitation
leather shoe products, then trunks and finally simply Leatheroid.
His patents reflect the Leatheroid Manufacturing Company by September
8 1884. He also refers to "parchment paper" as "Leatheroid"
in the title of patent 312945 his improvement and recipe for his
trade name Leatheroid. By 1889 Andrews branched much more into electrical
insulation, as can be seen from the patents shown below for a hard
rubber product called Vulcaloid (which was rubber mixed with ground
up scraps of Leatheroid). He also started manufacturing electrical
fiber tape, insulators, etc.
In
1876 Emery Andrews, Stephen Moore, Homer Rogers and C.W. Goodnow
were the controlling group in the National Leather Board Company.
In 1886 they founded the Leatheroid Manufacturing Company with Emery
Andrews as the president. In 1918 the National Leather Board Company
and the Leatheroid Manufacturing Company (and others) merged into
a new name of the Rogers Fibre Company.
Some of Emery
Andrews patents: Counter top: US Pat. 140569
- Filed Feb 14, 1873 (no assignment), Machine for stripping leather-board:
US Pat. 166837
- Filed Jan 20, 1875 (no
assignment), Coloring Leather-board: US Pat. 203810
- Filed Jun 16, 1877 (no
assignment), Heel stiffener for boots and shoes: US Pat.
242737
- Filed Mar 31, 1881 (no
assignment), Heel stiffener for boots and shoes: US Pat.
276550
- Filed Jun 7, 1882 (no
assignment), Drier for paper-board: US Pat. 314640
- Filed Dec 15, 1883 (no
assignment), Bending machine: US Pat. 329613
- Filed Sep 8, 1884 (assigned
to the leatheroid manufacturing company), Manufacture of
parchment-paper or LEATHEROID: US Pat. 312945
- Filed Sep 24, 1884 (assigned
to the leatheroid manufacturing company), Trunk-hinge: US
Pat. 312947
- Filed Sep 24, 1884 (assigned
to the leatheroid manufacturing company), Trunk: US Pat.
332034
- Filed Apr 16, 1885 (assigned
to the leatheroid manufacturing company), Box: US Pat. 329875
- Filed APR 16, 1885, Box Fastener: US Pat. 329614
- Filed APR 27, 1885, Nut Locking Washer: US Pat. 329615
- Filed Aug 14, 1885, Parchmentized paperboard: US Pat. 352729
- Filed Feb 17, 1886, Waterproofed parchment-paper: US Pat. 458840
- Filed Mar 8, 1889, Textile fabric: US Pat. 433388
- Filed Mar 21, 1889, Compound for parchmentizing paper: US Pat.
420615
- Filed APR 26, 1889, Electric Insulator: US Pat. 428545
- Filed Nov 4, 1889, US Pat. 428544
- Filed Nov 4, 1889, Leatheroid tape (electrical tape) US Pat. 541032
- Filed May 8, 1894.
The ad shown on above on your right for the National Fibre &
Insulation Co. In Yorklyn is appropriate since it was that company
that ended up absorbing most all of these fiber companies shown
here in the end and is still alive and well today after a few different
name changes.
The Vulcanized Fiber Co. ends up merging with many companies first,
and during one large merger they changed their name to the American
Vulcanized Fibre Co. (talked about here).
When the National Fibre & Insulation Co. merges in which they
again make a new company in which they consolidate into the National
Vulcanized Fibre Co., Of which the factory was in Wilmington and
the offices now in Yorklyn. Later the name is changed again to the
NVF Company.
TRUNK FIBER
This
type of fiber was known by many different trade names, but the type
of fiber was most commonly known as "trunk fibre" and
much earlier was known by different names relating to imitation
leather or "soft fiber" products.
Noteworthy is that most all of the fiber companies had their own
imitation leather (or soft flexible) product, called by their own
trade name. This
type of soft fiber was manufactured in many different colors (and
shades of those colors), not being limited as vulcanized fiber was
by choice. This
was normally so as not to weaken it using different pigments or
additives.
The trunk fiber product was (by design) a tough leather type of
fiber material that was mostly used to cover the surface of old
steamer trunks and drum cases. It was also used for machine belting
and almost every other application that real leather or rawhide
could be used for.
HORN FIBRE - DIAMOND FIBRE
Just as many other fiber companies, Diamond State Fiber Company
had a line of different vulcanized fiber products and trade names.
They had DIAMOND FIBER, which
was their regular layered vulcanized fiber product. DISFICO
was their HORN product which
was basically their white colored high end gelatinized fiber (made
from high quality rope stock in place of cotton). They also made
trunk fiber and a new product called
CONDENSITE, which was first
marketed by the Condensite Company of America.
The product however turned out to be a form of Bakelite which was
protected by patent. The General Bakelite Company brought suits
for infringements against the Condensite Company of America and
several users of "Condensite". The Condensite Company
acknowledged the validity of the Bakelite
patents and paid a substantial royalty. The Condensite Company was
allowed to then manufacture Condensite under the Aylsworth patents
as well as the license just granted for such of the Baekeland patents
as were broad enough to cover Condensite. The General Bakelite Company
felt gratified over the confirmation of the breadth of scope and
pioneer character of its patents. It was the Condensite-Celoron
product that Diamond advertised in their ads for their "Silent-Gears"
product.
CELLUVERT
FIBER
The Celluvert Manufacturing Company was incorporated in 1887, but
the material was applied for patent and filed
on May, 25,1885. Celluvert was again another new trade name for
vulcanized fiber, this 'invention' by a chemist named Henry W. Morrow
of Wilmington, Delaware Morrow used this material himself for trunk
fiber as well as being documented for journal-bearings, belting,
trunks, washers, tubes, skaterollers, etc..
It is also quoted with the ability to also be made into knife handles,
and various forms and shapes of non-conductors of electricity. The
sheets or slabs may be made either hard and hornlike or pliable
and leather-like, according to the use to which the "celluvert"
is to be put. See these patent entries.
The Celluvert Manufacturing Company changed its name to the Kartavert
Manufacturing Company and the product Celluvert was now called "Kartavert
Fiber".
KARTAVERT
FIBER
Kartavert fiber (previously celluvert
fiber) now made by the Kartavert
Manufacturing Company (changed from the celluvert manufacturing
company). The Kartavert word in Latin means "changed paper".
The word being derived from the two Latin roots Charta (paper) and
Verto (to change). A special quality of cotton fibre paper was obtained
in large rolls, which were placed at the front of the machine, and
upon unwinding pass over a drying cylinder. This cylinder was heated
by steam and is kept at such a temperature that the paper was soon
dried. It was then put in a bath of chemicals immediately back of
the dryer. The action of the chemicals upon the paper caused a change
in its surface and general texture and the fibre became glutinous.
Later,the
Kartavert
Manufacturing Company
merges with the vulcanized fiber company.
LAMINAR
FIBRE
Laminar
fibre was again the same fibre with it's own trade names. The company
is said to have been organized in 1890, but I have found the company
existing in 1889 publications. In fact, I also find it as far back
as 1879 in the Cambridge Massachusetts City Directory. While it
was only listed for the one year, it started being listed again
in 1891 and then exists until it is merged with the vulcanized fibre
company in 1901. Along with the 1901 merger these companies were
also allowed to run independently simply becoming a sort of fibre
monopoly. So, it is noteworthy that about a year after the merger
(Feb. 1902) that Laminar Fibre Co. was absorbed by American Hard
Fibre Company which was another one of the companies that merged
in 1901. The early mention of the company in 1879 makes sense seeing
that the later company was organized by Thompson
Hanna who was one of the original vulcanized company founders.
Around the same time William Courtenay had some issues where there
was a new company formed and then merged in later. Hanna also had
some of his own ideas when it came to fibre and it's quality as
laminar fibre was almost always a gray color. They would make black
and red fibre for special ordering, but their company product 'belief'
was that the fibre could loose it's quality by adding different
color pigments.
VUL-COT
FIBER
This Vul-Cot trade name was used for the new cotton products of
the vulcanized fiber company in Wilmington Delaware. They used this
trade name for their regular products, as well as a new line of
waste baskets that was said to have saved their company. For more
information, see this page where I talk about fiberware
and vul-cot fiber.
INDURATED
FIBER
Indurated fiber was a type of fiber that was known for making wood
pulp fiber products such as waste pails, bowls, pots, etc..
In the beginning this fiber was not seen as anything good for electrical
insulation, because of the fact that while it was held together
by the pulp compression process, it was the varnish that kept it
weather proof. Once the protective coating wore down a bit, the
bowl, pail, etc., would absorb moisture and fall apart. Later, new
processes (actually old processes reinvented see below: "Another
Type Of Wood Based Fiber") were wood pulp based fiber started
becoming more popular for electrical insulation (having water resistant
binders mixed in with its mixture or sometimes in the manufacturing
process).
Update 12-14-2010 - I was recently
contacted by someone that was interested in the manufacturing process
and machines, etc., that were used in making indurated fibre. To
help, I put together a list of patents containing composition recipes,
methods, machines, known inventors other patents, etc.. In case
this patent research is of use to anyone else,
the list is presented here in this PDF file. Note that I
have listed these in order of oldest to newest. I have also
listed a few patents right at the start that will show the history
and progression from wooden pails (which were not seamless), to
the indurated items which were molded, reamed (or other methods
used) to make them all one seamless manufactured piece.
WOOD
PULP BASED FIBER
Asphalt / Bitumen Based And Wood Pulp Fibre Compositions
STEPHEN ALLEN
Stephen Allen of Massachusetts, another long time paper manufacturer
(see patent no. 38,020
March 1863), started improving his products and inventions in patents
1880 and 1881.
He started making his 'leather' product by mixing fibre rags, paper,
bark and other ingredients with asphalt (which was his main binder
and patent process).
This was his basic "material for roofing purposes" which
was a bitumen / asphalt base composition (invented and patented
Jan. 1883 patent no. 278,481),
and was now being molded and used for electrical conduits as seen
in patent no. 284,794
July 1883.
As seen in the patent, he is now calling it "a composition".
The product was much like rubber and hard rubber and could also
be vulcanized.
By 1885 as seen in patent no. 337,472
he was now far underway molding and casting many different shapes
for a variety of different electrical uses.
Asphalt composition was common, as there were many different recipes
and methods of using it for both cold and hot molded applications.
To examine other asphalt type compositions, see this Edison
/ Bergmann example as well as the known composition
and the composition patent list looking for
green highlighted items.
RE-INVENTIONS
OF ALLEN'S IDEAS BY:
This
type of fibre was also re-invented a couple different times.
INDURATED COMPANIES
The indurated fibre companies had
a wood based fibre product that was in the early days used for waste
& ice buckets, pails, bowls, etc..
About the same time that the vulcanized fibre company moved into
marketing their vul-cot waste paper basket product, the indurated
fibre companies also started inventing and marketing their electrical
insulation products. (as shown in the quote on your right in the
street railway journal in 1906 and 1907).
MARK DEERING
As early as 1886 Mark L. Deering of the United Indurated Fibre Company
of Portland and member of the civil engineers club of Cleveland),
had the idea of using it for electrical insulation and started doing
experiments of ways to make wood pulp (indurated fiber) waterproof.
From what I can tell, his basic thoughts and processes were a bit
different from others. His papers (linked here
and here)
talk about an idea that he had when he noticed that water leaked
through indurated fiber when put under pressure (before the varnish
or sealing process). He invented a method of making barrels waterproof
by using a mixture of different sealers (varnishes, tar and pitch
too), heated and under pressure which caused the mixture to seep
into and between the molded material. When dried, it made for a
product which he became most popular for (seamless barrels) and
won a contract with Standard Oil. The most unconventional patent
may be his patent for "COMPOSITION
OF MATTER" in which the composition recipe calls for "one
pound of fiber to one quart of blood". Some of his
other patents can be seen in this google
patent search.
INDESTRUCTIBLE FIBER
- Also DURITE, FIBRITE &
KANTLITE FIBER
This was basically another trade name and products marketed by the
Indestructible Fibre Company of New York.
This company had claimed to have invented three different types
of indestructible fiber board. One which they called Durite with
claimed to be fireproof. The other two named Fibrite and Kantlite.
All three were fibre-board products mostly used for railway car
headlinings and steamboat panels or partitions. Kantlite was marketed
as non-combustible, and Durite as slow-burning. These two were also
marketed as their waterproof fiber products.
FIBER BOARD Also SERVICE
BOARD FIBER
Fiber Board was an invention of Wendell & Macduffie, New York
and sold under the trade name of "Service Board".
Service board was what basically took the place of Durite and Kantlite.
Fibrite was still used by many where a less expensive material than
service board could be used. Service board was a more compact material
with layers more closely united, under a new process of felting
and cementing the plies together.
VULCANIZED
FIBER HISTORY AND INVENTORS
|
HISTORY
OF VULCANIZED FIBER
Vulcanized fiber is composed of cellulose which was discovered in
1838 by a French chemist named Anselme Payen. It was Payen who first
determined its chemical formula and isolated it from different plant
materials.
The discovery of cellulose paved the way for the invention of nitrocellulose
based "collodion" Invented in 1848, which was later used
in a process for photographic plates. In 1851 an Englishman Frederick
Scott Archer discovered that collodion (a chemical process that
forms a flexible cellulose film) could be used in place of egg whites
(albumen) on photographic glass plates which also reduced the exposure
time.
This paved the way for Alexander Parkes who in 1855 directed special
attention to the fact that after the evaporating of solvents on
photographic glass plates, a solid residue remained. (The birth
of the plastics industry) Parkes invented a process to manufacture
the material and named it parkesine. He tried starting a company
to manufacture parkesine but failed and went bankrupt. (Later, John
Wesley Hyatt acquired Parkes patent and changed the name of parkesine
to celluloid and started the Celluloid Manufacturing Company of
Albany, NY).
VULCANIZED
FIBER INVENTORS
Three
early inventors are mostly credited with the invention of vulcanized
fiber, as well as improvements to the product for a little over
a generation. These inventors were: Stephen M. Allen of Massachusetts,
Thompson Hanna (and other family members) of Pennsylvania and William
Courtenay of New York.
INVENTION OF VULCANIZED FIBER
Vulcanized fiber was first invented by Thomas Taylor, an English
inventor who secured the British patent for it in 1859.
Over a decade later (March 16, 1871), Taylor applied for the United
States Patent for vulcanized fibre which was approved and assigned
patent no. 114,880
Taylor assigned his U.S. Patent to Thompson Hanna and Waldmer Schmidt
who also improved the invention, now owning three patents (61,267),
113,454),
(114,880).
Waldimer Schmidt was partnered with August Hartje (a well known
paper manufacturer and millionaire) now owned 50/50 of the Schmidt
share in the patents as well as the Pittsburgh Manufacturing Company.
A contract was written June
30th 1873 and later updated in November of 1873 to include all
future inventions of Thompson Hanna to also be split equally between
all parties including Hartje. A company was formed at the same time
which they named "Vulcanized Fibre Company". Though the
actual incorporation was not entered into the titles of acts of
incorporation law book until Feb.
8, 1875 (chapter 268), a special
charter was formed in the state of Delaware when the first contracts
were completed back in 1873.
Other
patents, improvements and products continued on through the years,
but the first actual industrial manufacturer of vulcanized fiber
here in the U.S. Was the "Vulcanized Fibre Company". In
these early days (before 1880) there was not many choices for fiber
companies. There was the original Vulcanized Fiber Company and a
couple of other early inventors.
VULCANIZED
FIBER COMPANY MERGERS
|
FIBER
USE INCREASES
It was not until the early 1880's (with the invention of incandescent
lighting) that the fiber business really started taking off and
becoming a real success. It was also about the same time that all
of the fathers of the fiber inventions patents started to expire
(1888). Within no time at all, fiber businesses started popping
up all over the country. In the Wilmington Delaware area alone there
was: The Vulcanized Fibre Company, American Hard Fiber Company,
Delaware Hard Fiber Company, Diamond State Fibre Co., Continental
Fibre Co., And the list goes on. The many fiber businesses in one
small area, was mainly attributed to the water power of Piedmont
streams in Northern Delaware.
In the early days (even before patents expired) the same basic materials
were sold under different registered trade names.
New manufacturers were inventing slightly different products in
order to come up with their own name and product. After naming their
product, they started to drum up business advertising their 'special'
fiber product as something better then the others out there.
For example, to get around current trade names, each manufacturer
had their own trade name for their product such as: Horn Fiber,
Hard Fiber, Laminar, Leatheroid, Kartavert, Fiberoid, Vulcanized
Fiber, Gelatinized Fiber, etc..
This is why for example that the Vulcanized Fibre Company (at the
time) could claim in their advertisements to be SOLE MANUFACTURERS
OF "VULCANIZED FIBRE". In the same way, Courtenay &
Trull was exclusive with their invention and trade mark for "Gelatinized
Fibre".
As the fiber products (in general) started to peak, each company
had followers and the word spread on their different products, some
with more success then others.
LANDMARK
CASE - TRADE MARKS AND NAMES - NOT VALID
Even though these companies chose these different 'broad' trade
names; and they were accepted by the U.S. Patent and Trademark Office;
they still were not legal trade names until infringement is proven
in a court. The vulcanized fiber company had a trademark for "Vulcanized
Fiber" and pressed it's weight in these early days not letting
others use the term to describe another fiber product. In truth
though and according to trademark law, anyone could had used this
term at any time since it was a description of fiber. In fact most
of these trade names were not really legal, they just had not been
tested in a court of law yet. It was a fiber company (with the trademark
for "indurated" fibre) that thought that their trade name
would hold up and is now a case quoted by lawyers and judges to
explain why you can not enforce this type of trade name. This was
the case of the United Indurated Fibre Co. In Lockport N.Y. trying
to get an injunction put on the Amoskeag Indurated Fibre Ware Co.
In New Hampshire. The Indurated Fiber Co. owned a trademark for
"Indurated Fibre" and fought for it and lost under the
grounds:
Trade-marks—"Indurated
Fibre."
"It seems to me that they do not sufficiently point either
by themselves or by association, to the origin, manufacture
or ownership of the article produced, but that they rather indicate
the quality, class, grade, or style of such article; or, to
express the distinction in another form, that they are not arbitrary
or fanciful words, but are descriptive rather of the quality,
ingredients, or characteristics of the manufactured article.
A name alone is not a trade-mark when It is understood to signify,
not the particular manufacture of a certain proprietor, but
the kind or description of thing which is manufactured. Anything
descriptive of the properties, style, or quality of an article
merely, is open to all.
"The cases cited are good law, but they do not apply to
this case, because it seems to me that the words now sought
to be appropriated as a trademark are indicative of quality
rather than of origin or ownership. For these reasons I must
deny the present motion."
|
It
is clear from the above that most of the trade names for vulcanized
fiber were not valid trademarks.
As time passed the term "vulcanized" fiber became a more
common word, without the fear of infringing on trademarks or trade
names. The Indurated Fiber case turned out to be a landmark case
as seen here cited in many
different legal publications.
COMPANY
MERGERS
In the beginning the vulcanized fibre company was the most successful,
being the first and already having the reputation for "vulcanized
fiber". The next most successful product trade names was the
"hard fiber" trade product and the gelatinized fibre which
was gaining lots of ground fast. However, along with the rash of
new businesses, there was no longer enough profit to go around for
the rate of public demand for fiber.
In a letter to a sundries committee (after a merger with the vulcanized
fibre company
William Courtenay wrote:
"The competition
among the various manufacturers has become so keen that there
is no longer a fair profit in the business, and this company
is the only one that is able to pay any regular dividends to
stockholders, and those only very moderately."
_____________________________________William
Courtenay |
Courtenay & Trull consolidated
with the Vulcanized Fibre Company in June of 1884 .
WILLIAM COURTENAY - A MAN WITH A PLAN?
Noteworthy is the fact that William Courtenay was one of the original
vulcanized fibre co. board members from the early 1870's.
In fact, he was it's first president as a New
York Corporation formed June 19 1873 listed with William Courtenay
President : Charles F. Cobby Secretary. (Also see the 1883
N.Y. City Directory) I do not know any of the details at all,
but the facts show that a special
charter in the state of Delaware was also created in 1873. The
New York corporation did not last for a listing the next year, but
the Delaware corporation was approved on February
8 1875 (see chapter 268) listing William Courtenay President
: Clement B. Smyth Secretary. As shown in the ads
below, up until 1877 there was a New York office with the factory
in Delaware (after the merger in June of 1884 with Courtenay &
Trull the New York office shows up again in ads).
There was a change February 4 1878 where William Courtenay is no
longer listed:
We have: Caesar A. Rodney President : Frank Taylor Secretary. This
same president and secretary in a listing I find in 1880 "THE
VULCANIZED FIBRE COMPANY—Tenth and Walnut Sts., Wilmington, Del.
The company was incorporated in 1873, under a special charter from
the State of Delaware, with an authorized capital of $300,000. The
President of the Vulcanized Fibre Company is Caesar A. Rodney, and
the Secretary and Treasurer is Mr. Frank Taylor" Industries
of Delaware: historical and descriptive review : cities, towns ...
By Richard Edwards page 109. Also in an ad shown below, April 1883
we have D. Fleming President.
More facts after this point are that in 1882, we have Courtenay
in his own business partnership "Courtenay & Trull".
Next, we have Courtenay patents which show his own inventions starting
around the same time that he is no longer listed as the president
of the vulcanized fibre company. These inventions filed in 1877,
1878 and 1880 are in his own name, and we see these inventions being
marketed by Courtenay & Trull as sole agents for these products
(in another ad shown below).
Again, we find a new invention in 1882, but assigned to a new company
"The Gelatinized Fibre Company" (Patent 256642
- Filed Jan 26, 1882). We soon see adverts by Courtenay & Trull
as sole agents for the Gelatinized Fibre Company and a remark of
how much better it is then "Vulcanized Fibre".
The next clear point of documentation we find is the fact that 'Courtenay
& Trull' merges with the vulcanized fibre company as shown below.
Messrs.
Courtenay & Trull, manufacturers of the "gelatinized
fibre," have consolidated with the Vulcanized fibre Company,
of Wilmington, Del. There is great similarity in the goods manufactured
by these two concerns, and the consolidation seems to be a wise
move. Their product has developed a great variety of uses, and
the demand for it is becoming very large.
------------------------The Electrician
and electrical engineer: Volume 3 - Page 135 June 1884 |
Another
point is that some time in 1884, W.W. Snow is elected the new president
of the vulcanized fibre company. He lasted almost a year, before
William Courtenay
was once again elected it's president, and was so until 1898 when
he is succeeded by J. Fred Pierson.
So, from this evidence, it appears that for some unknown reason
William Courtenay had left the vulcanized fibre company, and became
their direct competition. As seen from the marketing through the
years and large acceptance of Courtenay's gelatinized fibre invention,
it is clear that Courtenay could have caused serious damage to the
vulcanized fibre company if the merger did not take place.
The
ad shown on the right is from 1877 when William Courtenay was
first president and the Vulcanized Fibre Company was first incorporated
in New York.
WILLIAM
COURTENAY PATENTS
US Pat. 198,534
- Filed May 18 1877 Approved Dec. 25 1877 MARTINGALE RINGS
US Pat. 193,322
- Filed May 18 1877 Approved Jul. 24 1877 MAKING HOLLOW ARTICLES
OF VULCANIZED FIBER
US Pat. 193,323
- Filed May 18 1877 Approved Jul. 24 1877 CANS OR VESSELS FROM
VULCANIZED FIBER
US Pat. 197,252
- Filed May 18 1877 Approved Nov. 20 1877 SOUND-BOARDS FOR MUSICAL
INSTRUMENTS
US Pat. 195,885
- Filed May 18 1877 Approved Oct. 09 1877 HARNESS-LOOPS
US Pat. 217,448
- Filed Aug 24 1878 Approved Jul. 15 1879 PATENT FOR GELATINIZED
FIBRE
US Pat. 234,967
- Filed June 8, 1880 Approved Nov. 30 1880 SCREW-NUT
US Pat. 256,642
- Filed Jan 26, 1882 Approved Apr. 18 1882 NUT-LOCK (ASSIGNED
TO THE GELATINIZED FIBRE COMPANY OF NEW YORK)
US Pat. 240,892
- Filed Dec. 9, 1880 Approved May. 03 1881 SCREW-NUT
US Pat. 267,329
- Filed Oct. 5, 1882 Approved Nov. 14 1882 NUT-LOCK |
From
looking at the ads closely, you can see the progression of trade
names being merged as you notice the new offerings.
As
I look at and compare this information and the ads both above
and below, I can't help but to see Courtenay as a man on a mission.
If you look at the ad above that was made when Courtenay was
still president (1877 ad above - including the fancy font) and
then compare with the last ad (after the merger) shown below
at the end of this section, you will see the similarities. It
is almost like Courtenay took a walk around the block that took
him almost a decade.
What else could all of this history be showing us other then
a man out to prove a point, or a gambler that played his hand
well.
As seen on the right, the Vulcanized Fibre Company was advertising
in April of 1883 that they were sole manufacturers of "Vulcanized"
fiber and their only address in Wilmington Delaware.
Below, we see Courtenay & Trull advertising their gelatinized
fiber trade mark from their Dey St,. New York address in February
of 1883 and January of 1884.
|
|
|
|
As
seen in the ad on your right, Courtenay & Trull are shown
as the "sole agents" selling Courtenay's inventions.
As shown in the ads by the patent dates, these were the newest
gelatinized fibre products, as well as the nut-lock patent numbers
256,642
and 267,329.
Shown in the ad below.
You will also notice the note in the ad that they are superior
to leather and "Vulcanized Fibre" of which the Vulcanized
Fibre Company in Wilmington Delaware were "Sole Manufacturers"
of.
As shown in the bullion ad below, we see that in April of 1883,
Courtenay & Trull are now sole agents for the "Gelatinized
Fibre Company" (which I did find in a N.Y. city directory).
Notice also that the ad shows a new address for Courtenay &
Trull of 15 Dey St.
Again later after the merger the address is shown as 14 Dey
St. |
|
|
You
will notice on your right that after the merger in June of 1884
took place, the vulcanized fiber company now has two addresses
once again.
They are also now the "sole manufacturers of vulcanized
AND gelatinized fiber".
This was a great move on their part, now cornering the market
for both of the most popular trade names when it came to fibre.
Later they became an unstoppable force as they merged with other
fibre companies. |
|
VULCANIZED
FIBER COMPANY - MERGES INTO A NEW NAME
AMERICAN VULCANIZED FIBRE CO.
|
As time progressed
into the 1900's; and as Germany and other countries started importing
poor quality fiber products (at half the cost); many of the fiber
companies that were left were either forced out of business, or ended
up merging into one large fiber ball. This December 4, 1901 merger
created a new company called the "American Vulcanized Fiber Co."
Which was formed for the purpose of consolidating: Kartavert Mfg.
Co., Wilmington, Del. American Hard Fibre Co., Newark, Del. Vulcanized
Fibre Co., Wilmington, Del. and the Laminar Fibre Co. Of North Cambridge,
Mass.
Here is a tree that I made from my research of the vulcanized
fibre co., it's history and mergers mostly from city directories.
I have also included some fibre companies that went out of business
before 1904 that I found in Obsolete American Securities and Corporations
by R.M. Smythe.
OTHER COMPANY
MERGERS AND NEW
"AMERICAN VULCANIZED FIBRE COMPANY"
PRODUCTS
Note:
A special thank you goes to Cornelius Peterson (the great, great,
great grandson of Jesse Peterson the first president of the United
Indurated Fibre Company), who provided some documentation material
for this part of my research.
At
the same time the vulcanized fibre company was becoming a strong fiber
force (mid to late 1880's), another smart business man began building
his fiber empire. His name was Jesse
Peterson of Belfast New York, who was the president of the Indurated
Fiber Company of Lockport New York. Just as the other Delaware group
of fiber companies was attributed to the water power of Piedmont streams
in northern Delaware, Peterson was part of a small group of fiber
businesses and paper mills that grew around the Lockport New York
area, thriving on the water ways there (Erie Canal). Some of these
companies were: (Lockport Pulp Co., Traders' Paper Co., Lockport Paper
Co., Niagara Paper Mills, Cascade Wood Pulp Co., Indurated Fibre Co.
And Lockport Felt Co.. The Indurated Fibre Company should not be confused
with the Amoskeag Indurated Fibre Ware Company (Peterborough New Hampshire)
which was based on a fiber invention by Frank Eugene. However both
of these "Indurated Fibre" companies, were making wood pulp
fiber products such as waste pails, bowls, pots, etc. (note also that
there were other "indurated" companies).
The first indurated company was (as far as I am aware) the Portland
Indurated Fibre Company (Portland Maine) which was operating in 1884.
Jesse Peterson who owned and
operated a wood pulp mill in Lockport NY, became the first president
of the "Indurated
Fibre Corporation" in 1885 (which was a three story building
directly across the street from his mill).
Just
as with the vulcanized fiber businesses, as the indurated
fiber companies became a success, other indurated fiber companies
also started popping up.
By 1888 there were plants producing this type of product operating
in Oswego, New York, Mechanicsville, New York, Medina, New
York, Watertown Massachusetts and Peterboro New Hampshire.
Just for example and to show the growth, when Peterson's Indurated
Fibre Corporation plant first began operations it was producing
about 350 pails a day.
|
|
However,
by 1888 the output was 3000 pieces a day which included 1600 pails,
100 tubs, and an assortment of spittoons, slop jars, wash basins,
and butter bowls.
The largest part of the business at the time was the pails, since
they were marketed as one piece pails without bottoms (seamless).
In those early days the main problem with current pails was the
bottoms falling out with age.
As shown above, just as the vulcanized fiber companies merged to
become stronger, so did these indurated companies.
However,
in the long run the mergers did not prepare the indurated companies
for the new inventions and new products (namely galvanized iron
pails and items made from tin and aluminum) that soon put them out
of business.
United Indurated Fibre was purchased on July 13 1914 lock stock
and barrel by Phillip W. Russell (who was an attorney working for
the H.W. Johns fibre company) - Wall Street Journal, July 13,
1914
The company name was changed to "Fibre Corporation" on
July 20th 1914.
The directors of the new company were W.R. Siegle of Connecticut
and Richard Bennett, Jr., Roger Sherman, Wm.K. Dupree, Jr., and
Fred E. Sturgess, all of New York.
Wall Street Journal, July 20, 1914
Here is a link to a full size high res scan of a post card picturing
the United Indurated Fibre Co. In 1895 (click
here to view it in a popup window or tab).
Here are some examples of some indurated pails and items. Many of
the items made by the united indurated fibre company can be seen
on display at the Niagara
County Historical Society in Lockport NY.
Kandt
House at 229 Niagara Street. Newly opened in 1999 this Victorian
Home now houses several new Exhibits with more to come in the
future.
The Fitz-Gerald's
Medical Arts Room, features an old fashioned doctors office
honoring all three Fitz-Gerald doctors who practiced in this
county. Medical artifacts from the 1920's onward are featured.
The business
and Industry Exhibit documents some of the innovative and
important industries that developed here in Niagara County.
Artifacts from the Simonds Saw & Steel, the Carborundum
Company and Lockport Glass are main subjects. Birdsall Holly's
invention of the first pressurized fire hydrant started the
Holly Manufacturing Company a major employer in its day. Items
from that company, along with Merchant's Gargling Oil, the
Seven Sutherland Sisters and other local notables are included.
Local
flavor is featured in the Ford Gum Company that started in
Niagara County and supplied the colorful gumballs you remember
from childhood. Examples of Indurated
Fiberware made from the by-products of the lumber industry
will be on display.
|
Some images
below copied with permission from www.lockportcave.com
UNITED INDURATED FIBRE COMPANY
- LOCKPORT NEW YORK
INDURATED FIBRE COMPANY - WATERTOWN MASSACHUSETTS
NEW PRODUCTS MADE BY THE AMERICAN VULCANIZED FIBRE
COMPANY
From
the beginning there were basically two different types of fiber
companies that provided entirely different types of products.
The indurated wood fibre products shown above which did not survive;
and the vulcanized paper types of products which because of its
many different uses did survive the test of time.
This fiber is what was marketed as horn, trunk, gelatinized, vulcanized,
etc. This fiber was used for washers and all kinds of different
electrical insulation. It was used as imitation leather for belting,
trunks, shoes, etc.. When gelatinized fiber was perfected, it was
used for so many different things including poker chips, tokens,
pendant cord adjusters and the list just goes on and on. C.W. Sutton
the last president of the American Vulcanized Co. (right before
it's last large merger and name change into the national vulcanized
fibre co.) is quoted in an article (linked
here) in factory magazine February 1922 (from losses to profits)
that they "made up fibre into special articles on order-electrical
goods, and the thousand and one specialties for which fibre gradually
came to be used".
As
the article above also points out, during their battle for 'fiber
company survival', they needed a type of flagship product to carry
them through. The american vulcanized fiber company found this in
a new product marketed under their new trade name VUL-COT. Together
with the running of large ad campaigns (some shown below) and by
offering a five year guarantee - their new 'Fiber Ware' waste basket
became this flagship product. The picture below shows a dollar-sized
(36.7mm) red gelatinized fibre advertising token, from the American
Vulcanized Fibre Co.. It also shows a depiction of their VUL-COT
waste basket and advertises their 5 year guarantee.
EARLY KNOWN COMPOSITIONS PRODUCTS & RECIPES
|
When
I first started this section and my lists of early materials and recipes,
the main part of the list was for the most part directly copied from
a book published in 1899, 1909 and 1918 called Crude
rubber and compounding ingredients by Henry Clemens Pearson. However,
even with the large base or bulk of information found in this volume,
I have found myself adding much more information and research then
I ever anticipated. Information that has been added
from personal research would
include (but is not limited to) all of the
illustrations, ads, photos, patent information, known compositions
or ingredients that were missing, known compositions that were invented
after publication, corrected information or more expounded info on
some items that were originally quoted, color coding, links, etc..
COLOR KEY TO MY LISTS
|
GREEN |
Asphalt,
Asphaltum, Bitumen, Pitch and its derivatives |
RED |
Asbestos
and its derivatives
|
PURPLE |
Caoutchouc,
Rubber, Gutta-Percha, Etc. |
GOLDENROD |
Fibers
made from any paper, wood, rag, or vegetable pulp and then solidified
using zinc chloride.
Vulcanized / Gelatinized / Horn / Leatheroid / Etc. |
Please
check back from time to time, as this will always be a continuing
work.
If you have any corrections, ads, info or additions, please feel free
to contact me.
Here
are my composition research lists
Click here to view my Known
Composition Product List
The known composition part of my lists covers compositions that
were sold at one time under a trade name, or patented as a known invention.
I have tried to the best of my ability and scope of knowledge, to
only have known compositions in this list while listing the ingredients
in another list. This can be difficult when either a known composition
or trade product is 99 percent of an ingredient and 1 percent filler
or some other item. In most of these cases, I will try my best to
cross link or weblink them together.
Click here to view my
Inactive Ingredients Used In Compositions
Sand,
clay and other inert ingredients were used as fillers (most times
termed as inactive ingredients) in different compositions.
Most inactive ingredients
or fillers were chosen for their properties
and how they would mix into or help the composition.
For example, sand for the silica or quartz which would provide hardness
and take heat well, and clay for the high resistance to heat as well
as the additional binding properties (and because of its small granular
size). You will often times find talc or ground up soap stone used
along side of these ingredients to help provide additional resistance
to heat (and hardness if the composition was to be fired with clay
or mixed with plaster). Since sands, clays and some other inert ingredients
can play a big part in compositions, using the particle
size chart might be of use to you when trying to id some materials.
Click here to view my Composition
Materials Patent List
This list might take some time to complete, but as I come across composition
(and composition ingredient) patents in research they will be here.
If you come across a patent not in the list, please do feel free to
email me or contact me with the information so that it can be added
to the list.
Click
here to view my Active Ingredients
Used In Compositions
Molded insulation's are either cold molded or hot molded depending
on which active ingredients or binding agents and methods are
chosen. If it is a chemical reaction that takes place with a mixture
(without heat), this would be called a cold molded composition. It
can still have hard, stony, vitreous materials, fibers, etc. added
to the mixture, but the binding agent would be one of two classes.
It would be either a pitch, or resin that is dissolved using chemicals,
or a direct chemical reaction such as lime, silica and water mixed
with magnesia. An example of other chemical mixtures would be oxide
of magnesia mixed with chloride of magnesia or zinc oxide with zinc
chloride. Hot molded compositions are normally molded using pressure
and heat at the same time. Normally the binding materials used for
hot molded compositions, are those that are hard when cold and soft
when heated. Most any of the raw insulating materials can be mixed
with the binder as an inert ingredient. Often times the materials
are mixed together by use of a grinder and then heated to fuse the
binders while being placed into a hot mold and compressed. The composition
is then allowed to cool and harden under pressure.
ABOUT
MOLDED COMPOSITIONS
Molded
insulation embraces a great number of different compositions and compounds,
which are difficult of classification. The chief ingredients of some
of these materials are well known, while others are made by secret
formulas and processes. Among the raw materials employed in the manufacture
of molded materials are mica, asbestos,
silica, clay, alkaline earths, wood pulp, cotton, hemp, flax, asphalt,
camphor, hydraulic cement, rubber, shellac,
copal, dammar gum, rosin, paraffin wax,
linseed oil, turpentine, benxine, alcohol, phenol and formaldehyde.
See: Asbestos Compositions, Asphalt
Bitumen Compositions
ASBESTOS
For Asbestos
see the asbestos section
on this page
AETNA
Aetna material is a hard composition employed chiefly for strain insulators.
Tests made by Symons (Jour. I. E. E., 1904) on a strain insulator
of this material gave the following results: Resistance, 20,000 megohms;
puncture, 11,000 volts; tensile strength, 5,-500 lb.; absorption of
water, 3.2 per cent of its own weight after 1.5 hr. immersion at 49
deg. Cent Other , tests made on this material gave a dielectric strength
of about 90 volts per mil;
tensile strength. 1,400 lb. per sq. in. It will withstand great heat,
but tends to become brittle at high temperatures.
ALLARD'S
FIREPROOF FELT
Allard's fireproof felt is made of 50 per cent, of asbestos
and 50 per cent, of animal hair, and for ordinary purposes is wholly
fireproof.
ARTIFICIAL ELATERITE
Made from liquid bitumen by
incorporating with it vegetable oils, such as cottonseed oil, palm
oil, rapeseed oil, etc. The product is treated with the aid of heat
and pressure, with chloride of sulphur, saltpeter, and sulphur, which
produces an oxidization of the fatty substances. The result is an
elastic rubber-like
or leathery mass, which is soft, spongy, and gluey. This gum
is said to be far more elastic than the
best samples of mineral rubber, and is
useful for waterproofing and insulation. Patented by W. Brierly, in
England.
ASBESTONIT
An asbestos product manufactured
by Messrs. Ladewig & Co., Of Rathenow in England under a secret
process, for use as steam or hot-water packing.
ASPHALT
Asphalt is undoubtedly an oxidized residue from evaporated petroleum.
Its specific gravity varies from 1.00 to 1.68. This name is applied
usually to the solid bitumen,
the liquid being called mineral tar,
and sometimes maltha. It is chiefly
made up of hydrocarbons, but contains a certain amount of sulphur
and nitrogenous bodies. It is known also as natural
pitch, Jews' pitch, asphaltum,
bitumen, etc. It is a black, hard substance which, when
freshly broken, shows shining surfaces that are always correspondingly
rounding and hollowing. It is insoluble in water and alcohol, but
dissolves in benzine, acetone, and carbon disulphide. Is used in rubber
compounding in place of coal tar,
and in insulating compositions, and in certain substitutes like kerite.
Commercially there are two grades, known as "lake
pitch" and "land pitch,"
of which the latter is the harder.
In solution it is used sometimes to protect rubber goods that are
exposed to the destructive influence of brine. A little asphalt
is also said to increase the elasticity of hard
rubber. Asphalt mixed with resin
and oil of tar forms a low-grade artificial
gutta-percha. It is added to "Cooley's
artificial leather" to harden it and enable it to resist
heat. It is also the basis of one type of marine glue. See the Asphalt
section on this page
ASPHALT,
ARTIFICIAL
This is made by heating sulphur and resin together to about 250 degrees
C, where the reaction takes place, attended by the evolution of sulphuret
of hydrogen, and leaving an almost black, pitchy substance resembling
asphalt. It is insoluble in alcohol, but dissolves readily
in benzine.
ASTRICTUM
A compound to be used in damp places, consisting of pulped cotton
15 pounds, pitch 25 pounds, asphalt
20 pounds, ground granite rock 20 pounds, bitumen
5 pounds, resin 10 pounds, coal tar 12 pounds, and mastic
5 pounds.
BETITE
An English insulating material which is said to be bitumen
refined to absolute purity and vulcanized. It is used on cables, in
underground work, for low pressure resistance, and in rare instances
for high pressure.
BITUMEN
The term applied to a body made up of several hydrocarbons. It resembles
Trinidad asphalt and is of the
same nature. Its specific gravity is from 1.073 to 1.160. Artificially
it is prepared from shales, mineral asphalt,
etc. It is used as a source of paraffin. The West Indian product is
known as chapapote. A solution is made
from it in which the tapes are soaked that are used for
covering wire that has been insulated with india rubber.
Bitumen has been utilized by what
is known as the calendar process, which is a partial vulcanization,
rendering it valuable as an insulator. See the Asphalt
section on this page
BITUMEN,
AUVERGNE
A species of natural asphalt
found in the province of Auvergne, France. It is similar to Trinidad
asphalt, but is impure, containing clay, silica, magnesia,
iron, and traces of arsenic.
BLACK PITCH
Black Pitch Is the residue left after the oils of tar have been distilled
from that body. Used in weather proofing work. British
Gum
BLANDITE
An artificial India rubber invented by
Dr. A. L. Blandy, of London. It is fairly elastic,
stretching to about twice its length, and returning readily. It is
very pliable and composed of hemp fibers, so treated as to be impervious
to both alcohol and water. Dieterich analyzed a sample of the product,
and said that the fibers were sulphite wood pulp, and that the coating
was made from chrome gelatin treated with glycerine, or the well-known
compound of glue, glycerine, and bichromate of potassium does not
show signs of cracking when bent. It is vulcanized
like ordinary rubber, and can be molded into any form desired.
Coated on cloth, it strongly resembles leather. It is waterproof,
and is used for gas tubing, mats, etc. In its crude form, it is a
liquid mass resembling molasses. Dr. Blandy's patent describes the
compound as made preferably of linseed oil which has been reduced
by oxidation; then 10 per cent, of bisulphide of carbon, to which
has been added 10 per cent, of chloride of sulphur, is mingled with
the oil, and the mixture brought by gentle heating to the desired
consistency. Trinidad asphalt,
cleansed and reduced to powder, is combined under the heat in the
proportion of 3 parts to 1 of oil. Care must be taken to avoid fire
in heating. These proportions are gradually brought, by heat and stirring,
to a liquid or thin state, and when in this condition it must be poured
upon a wet, cold surface, and thus cast into sheets, convenient for
subsequent mixings.
BOUGIVAL
WHITE
Bougival White was a fairly common white pigment, although it has
been replaced by barytes, terra alba, and whiting. Bougival white
is a white, marly, China clay found at Bougival, near Marly, in France.
The district surrounding Bougival and also Normandy and Auvergne contains
many beds of white clays, notable for their smooth qualities of good
color. Roughly Bougival white contains 33 per cent, chalk (carbonate
of lime) and 67 per cent, kaolin (hydrated silicate of aluminum).
Also see Kaolin
BROWN'S
SUBSTITUTE FOR HARD RUBBER
Substitute For Hard Rubber made of bitumen,
sulphur, lead peroxide, and gum camphor. Amalgamated by heat.
CAOUTCHOUC
ALUTA
A composition used as a substitute for hard
rubber, made of leather scraps boiled in water, with a sufficient
quantity of oxalic acid to dissolve them, and a portion of glue. To
this are added resin, pitch, beeswax,
and copal gum, dissolved in oil. India rubber
boiled in linseed oil is then added and a powder formed of plaster
of Paris, and a coloring matter is stirred into the composition to
thicken and stiffen it.
COALITE PITCH
A residue of coalite tar, much like
natural bitumen
and containing little free carbon. An English product.
COHURU'S WATERPROOFING
COMPOUND
This consists of crude petroleum, 3 quarts; liquid
asphalt, 1 pint; white drier, 1 pint; besswax, 4 ounces,
and gum-arabic.
COPAL
Hard
copal is a fossil resin obtained from the East Indies, South America,
and the Eastern and Western coasts of Africa. It occurs commercially
in roundish, irregular pieces, having a specific gravity of 1.045
to 1.139. It is insoluble in alcohol, partially soluble in ether,
and slightly so in oil of turpentine. Soft copal is obtained from
living trees in New Zealand, the Philippine Islands, Java, and Sumatra.
Used with shellac, asphaltum,
and arsenate of potash for waterproofing leather; also in cements,
in proofing compounds, and in varnishes in connection
with India rubber, lead, alum, and other ingredients dissolved
in spirits of turpentine.
DAMMAR
Dammar is derived from the Amboyna pine, growing in the Malay peninsula,
Sumatra, and Borneo. The resin exudes in tears and is collected after
it has dried. It makes a very transparent varnish, the gum being soluble
in benzine, essential oils, and to a certain extent in alcohol. Used
in artificial leather compounds, and with rubber, asphalt,
and fish oil for waterproofing leather. It is quite largely
used in rubber cements. Specific gravity 1.10-1.12.
DEPONT SUBSTITUTES
An English patented product made from asbestos
30 parts, plaster of Paris 5 parts, clay 8 parts, copal 15 parts,
tar 5 parts, bitumen 15 parts, aniline 2 parts, lampblack 15 parts,
mica 4 parts, wax 3 parts.
DERMATINE
A well-known substitute for India rubber
and leather, made of an artificial gutta-percha
called "gum percha,"
7 pounds; powdered waste rubber,
7 pounds; India rubber, 14 pounds;
sulphide of antimony, 6 pounds; peroxide of iron, 2 pounds; flour
of sulphur, 4 pounds 8 ounces; alum, 4 pounds 8 ounces; asbestos
powder, 2 pounds; sulphur of zinc, 3 pounds
EBONITE
(also
known as)
Vulcanite,
Hard Rubber
The first hard rubber was manufactured by the American Goodyear, and
he must be considered as the inventor. Solvents which dissolve the
natural raw caoutchouc, and partly dissolve vulcanized soft rubber,
have no influence at all on it, and the material offers the strongest
resistance to all kinds of acids. If it is exposed for a longer period
to a dry temperature of about 400° F., it does not become first
sticky and then melt, as happens under the circumstances to raw caoutchouc
and vulcanized rubber; it carbonizes at once, and goes through no
intermediate stage.
EKERT'S HIGH
PRESSURE COMPOSITION
Consists of rubber, asbestos
fiber, litharge and sulphur. To this base are added oxide of zinc,
iron oxide, graphite, magnesium silicate and resin. It is patented.
ELATERITE
Elaterite is, also known as elastic bitumen
or mineral caoutchouc.
It appears naturally in soft, flexible masses of a brownishblack color,
somewhat resembling India rubber. It
is composed of 85.5 per cent, of carbon, and 13.3 per cent, of hydrogen.
In its physical characteristics, elaterite is found in infinite variety.
It is sometimes elastic and so soft as
to adhere to the fingers, and sometimes brittle and hard. One kind
of it, when fresh cut, resembles fine cork, both in texture and color,
and will rub out pencil marks. Its elasticity
is due to its cellular texture, and to the moisture with which
it combines.
It is used to a certain extent in insulating compounds, but is intractable
and so far shows no special features of value above other minerals
of the same series. A few years ago a company was formed in Colorado
which claimed to be able to make many kinds
of rubber goods from this product alone, but little has been
heard of the plan of late.
See Gilsonite.
ELASTOID FIBRE
See Elastoid Fibre in the asbestos
section
FIBERITE
A product made from a fiber composition.
Possible a wood pulp base seeing that the inventor makes machines
and other inventions to make this type of fiber. You can see google
patents here
FRENCH ASPHALTE
See Auvergne Bitumen.
GENASCO HYDROCARBON
A product made from natural high-grade asphalt
so treated that it is valuable in rubber compounding.
GILSONITE
Lustrous black, hard bitumen.
Found in Utah.
GRAHAMITE
Dull black solid bitumen. Found
in West Va.
GUTTALINE
A substitute for India rubber and guttapercha,
manufactured as follows: To Manila gum
tempered with benzine is added 5 per cent, of Auvergne
bitumen, also mixed with benzine. Then add 5 per cent,
of resin oil, and allow 48 to 86 hours to pass between treatments.
The product obtained is similar to India rubber.
If it be too fluid, the addition of 4 per cent, of sulphur dissolved
in bisulphide of carbon will act as a remedy.
HARD
RUBBER
(also
known as) Vulcanite,
Ebonite
The first hard rubber was manufactured by the American Goodyear, and
he must be considered as the inventor. Solvents which dissolve the
natural raw caoutchouc, and partly dissolve vulcanized soft rubber,
have no influence at all on it, and the material offers the strongest
resistance to all kinds of acids. If it is exposed for a longer period
to a dry temperature of about 400° F., it does not become first
sticky and then melt, as happens under the circumstances to raw caoutchouc
and vulcanized rubber; it carbonizes at once, and goes through no
intermediate stage.
IMPREGNATED
FIBRE DUCT
Impregnated Fibre Duct is in extensive use for both inside and outside
construction. It is made in the form of a cylindrical tube by wrapping
many layers of paper or pulp on a mandrel and impregnating it during
the process with bitumen or a compound of liquid
asphalt and coal tar, It is sometimes known as bitumenised
fibre. Tests made on a certain grade of this material show
that it absorbed from 2 to 3 per cent, of water after 96 hr. immersion;
one manufacturer guarantees not more than 0.75 per cent, when the
ends are sealed. The compound softens slightly at 55 aeg. Cent, and
commences to break down at about 95 deg. Cent Manufacturer's guarantees
on minimum puncture voltage, dry, through a 0.375-ln. Will, range
from 25 to 50 kv ; after prolonged immersion the dielectric strength
will usually be lowered, depending naturally upon the amount of moisture
absorbed.
IMPREGNATED
CLOTH
Impregnated Cloth is similar to varnished or oiled cloth,
with the difference that the fabric is treated with an impregnating
compound. One manufacturer employs a mixture of oxidized oil and
asphalt; others use an asphaltum
or a paraffin base, dissolved in a thinning material. The Mica Insulator
Co. gives puncture voltages for " Kabak" cloth (impregnated
cambric) ranging from 1,0*15 to 1,650 volts per mil.
INSULITE
A
preparation made of wood or vegetable fiber, finely ground and desecrated,
and saturated with a mixture consisting of melted asphalt,
incorporated with substances of the resin type, with or without substances
of the paraffin or anthracene types. The products resulting are used
as substitutes for India rubber, particularly in insulation.
Patented by Alfred H. Huth, London.
Note: In my personal research, I find this patent to be John Ambrose
FlemIng of University College, Nottingham England. Patent dated the
23d April, 1881, No. 1,762 - U.S. Patent applied for Mar 14, 1882
and assigned patent no. 259271
Insulite was brought up in a letter from Insul (Edison's personal
secretary) to Edward Johnson on March 21st 1882 where he had thought
that Johnson was making fun of his name in previous correspondence,
but it was only Johnson talking about this insulation. Flemming gave
Johnson a sample to take back to New York in June, and within a short
time it was being used in the insulation of Edison lights that were
installed at the London post office. See patent
entry notes on this page
JUNGBLUTH'S
COMPOUND
Calcium carbonate 75 per cent., Trinidad
asphalt 20 per cent., selenite 5 per cent. In place of
Trinidad asphalt, neutralite, an asphaltic material made in Berlin,
is sometimes used.
JUST'S ACID-PROOF
COMPOSITION
Just's Acid-proof Composition is composed of linseed oil, gutta-percha,
sulphur, rosin, shellac, and asphaltum or
pitch.
KARAVODINE'S
PROCESS
Karavodine's process (French) consists of pulverizing the material,
adding asbestos fibers which have
been previously treated with a binding medium, and subjecting the
mass to a higher pressure at higher temperature.
KEMPEFF HARD
RUBBER SUBSTITUTE
A hard rubber substitute mixture
consisting of 20 per cent, resin and asphaltum,
15 per cent, china clay, 11 per cent, kieselguhr. Mixture is allowed
to cool; ground dry; with 4 per cent, of sulphur, and 50 per cent,
of ground asbestos
fiber. It is elastic and unaffected by
acids.
KERITE
A compound of vegetable oils, coal tar,
bitumen, and sulphur, to which are added sometimes a little
camphor and various waxes. Occasionally sulphide of antimony is used
in place of sulphur. Vegetable astringents, such as tannin, the extract
of oak bark, etc., are also used in small quantities to impart toughness.
Kerite is the invention of Austin G. Day, and has been used largely
for the manufacture of a covering for insulated wire. A later patent
taken out by W. R. Brixey, changes the original kerite compound somewhat.
Cottonseed oil is eliminated and talc added. The later compound is
as follows: Coal tar 25 pounds. Asphalt
I5 pounds. Heat together to 350° F. for 'A hour; then add— Linseed
oil 70 pounds. Heat again to 350° F. for 7 hours; let stand over
night; heat up to 240° F., and add— Sulphur 10 pounds. Heat up
to 320° F. in 1/2 hour and add— Sulphur 4 pounds. Heat again to
300° F. and add— Talc 56 pounds. Keep at same temperature 1/2
to 3/4 hour, when
vulcanization will have taken place, and the mixture can be poured
into molds or allowed to cool in mass.
(see patent no. 322,802)
Also see this entry on this page for Kerite
LAVITE
- See Artificial Lava
LICONITE
Liconite, produced in Holland, is described as a mixture of bitumen
and various oils, without India rubber or
gutta-percha, elastic and tough,
and is claimed to be unaffected by water, dilute acids, and alkalies,
and neither flows nor cracks in ordinary temperatures.
LITHRO-CARBON
A kind of asphalt, large deposits
of which are found in the state of Texas.
It was at one time thought that it would supersede
India rubber, and a company was formed with the idea of manufacturing
goods from it. This was in 1892, and India rubber is still used. The
chemical composition of lithro-carbon is 88.23 carbon, 11.59 hydrogen,
.06 oxygen, a trace of sulphur. Lithro-carbon is jet black in color,
is flexible at ordinary temperatures, and is quite tough. Its specific
gravity is about 1.028. It is said to be soluble in naphtha, benzol,
bisulphide of carbon, etc. It will stand a temperature
of 600 degrees F., without giving off its associate products.
It resists alkalies and acids, with the exception of concentrated
nitric and sulfuric acids. Its manufacture was patented. Used
with gutta-percha and shellac it makes an excellent insulator.
MANJAK
A kind of asphaltum of which there
are extensive deposits in Trinidad, West Indies.
Used chiefly in varnishes. See the Asphalt
section on this page
MASTIC
A resin from the shores of the Mediterranean. It occurs in tears of
a pale yellow, is brittle, and of a faint balsamic odor. Specific
gravity 1.07. It dissolves in acetone, turpentine oil, and alcohol,
and is largely used in varnish. The residue
obtained in the purifying of mineral asphalt is also called mastic.
It is used in general rubber cements
for joining stoneware, earthenware, leather, etc. One of special value
calls for 10 parts of mastic to 1 part of
India rubber, dissolved in chloroform, and makes an excellent
cement for fastening letters to glass. The gum
also appears in many old-fashioned compounds. Also
see Mastic Patent Info
MINERAL
INDIA RUBBER ASPHALT
Mineral
India Rubber
Asphalt is the name of a material
composed of refuse tar produced during
the refining process of tar by sulfuric acid. It is black, like ordinary
asphalt, and quite elastic.
It is an excellent non-conductor of electricity, and is not assailed
by acids or alkalies. In a naphtha solution, it yields a waterproof
varnish for metallic objects, and is used in
rubber compounding in place of asphalt.
NATURAL
PITCH
Natural Pitch is the name given to such kinds of pitch as are not
manufactured, such as asphalt, bitumen,
etc.—That is, pitch of a mineral origin, except that from coal or
shale. See Asphalt.
OZOCERITE
aka Ozokerite
A waxy hydrocarbon occurring in Austria, southern Russia, and the
United States. It is also known as earth wax. Its specific gravity
is 0.9 to 0.95, and it is about as hard as talc. Chemically, it consists
of hydrogen 13.75 and carbon 86.25, while its melting point extends
from 140 degrees to 170 degrees F. It is often found adulterated with
asphalt and sometimes with Burgundy
pitch. Purified ozocerite is known as cerasin (AKA ceresine).
To make this, the crude material is treated with fuming sulfuric acid,
and then filtered through charcoal. Thus prepared it is of a pale
yellow color, the melting point ranging from 61 degrees to 78 degrees
C. It has almost wholly driven out Stockholm tar as a protection for
wires insulated with gutta-percha, when
placed under ground. It improves the insulation, but in spite of common
belief to the contrary, does not preserve textile fabrics. The best
compound for the protection of the insulation on wire consists of
3 parts ozocerite to 1 part of Stockholm tar. It is an insulator of
high quality, and while it is in some ways intractable, its wax-like
nature allows it to combine with other insulators or with textiles.
It is also used as a water-repellent in fabrics, the gum being volatilized
by heat, and the fumes passed through the cloth. As a surface covering
for tapes or braid, it is often employed and is better than other
gums, as it takes a fine polish from the polishing machine. The basis
of Henley's system of curing India rubber core
is melted ozocerite, which is used under pressure to remove all the
moisture, being afterward heated in hot ozocerite, which stops up
the pores. Ozocerite, mixed with India rubber,
is also the basis of the India rubber compound
called nigrite. It mixes, however, with difficulty
with India rubber, which is an objection to many proposed uses
of it. It also has a mildly deleterious effect on it. The picture
above is linked from the mineral collection of the Bringham Young
University Department of Geology, Provo, Utah. Photograph by Andrew
Silver. BYU index 1-1019b. Image file:http://libraryphoto.cr.usgs.gov/htmllib/btch569/btch569j/btch569z/btch569/byu00818.jpg
PIONEER MINERAL
RUBBER
One of the first successful asphaltum
rubbers used in connection with rubber compounding.
It unites perfectly with any grade of crude
rubber or with reclaimed rubber. Is said to prevent blistering,
and to minimize the harsh action of free sulphur; is acid proof.
PLASTITE
A vulcanite which is made extra hard and is not possessed of any special
amount of elasticity. The stock recipe for this is: India
rubber 100 parts, sulphur 25 parts, magnesia 50 parts,
orpiment 50 parts, coal tar asphaltum
60 parts. It is very hard and solid, and takes a high degree of smoothness
and polish. (Hoffer.)
PORCELAIN
The three principal constituents of electrical porcelain are feldspar,
clay and silica. There are three feldspars: orthoclase, or pot ash
feldspar, which is the most important; albite or indianite, which
is soda feldspar; anorthite, or lime feldspar. The two clays used
are ball clay, and china clay or kaolin. A standard
mixture of these constituents for testing purposes is 20 parts feldspar,
50 parts kaolin and 30 parts quarts. The function
of the feldspar is to act as a flux to unite the other constituents
into a vitreous mass when fired. There are two processes of manufacture,
the dry process and the wet process.
Dry-process
porcelain is manufactured by molding the moist raw mixture under
high mechanical pressure and then vitrifying by the usual firing
process. This grade of porcelain is usually very porous and consequently
has a disruptive strength on the order of atmospheric air, or less.
At or near disruptive pressures, however, it heats rapidly and is
not suitable for high voltage insulation. The safe dielectric strength
is on the order of 1,000 volts.
Wet-process porcelain is made by mixing the raw ingredients with
water. The mixture la placed in a filter press and the surplus water
extracted, leaving a wet plastic cake. The cake is re-mixed in a
pug mill to make it more homogeneous, then molded or jiggered into
a blank of approximate filial shape, and allowed to dry. When fairly
dry it is turned in a lathe or tooled to final shape, dipped in
the glazing bath and placed in the kiln preparatory to firing. The
glazing mixture is the same as the porcelain except that it contains
more flux, and thus melts at a temperature barely sufficient to
vitrify the porcelain. The finished glaze is virtually a species
of glass. During manufacture porcelain shrinks from 10 to 20 per
cent, and much care is required to proportion the parts so that
cracking will not result. The thickness is limited both by the shrinkage
and the difficulty of obtaining satisfactory vitrification. High-voltage
porcelain is made in all cases by the wet process.
For the most part different electrical supplies started being replaced
with porcelain at different time intervals depending on the time
frame. This could be because time was needed to perfect the different
processes needed before being able to manufacture different items
more precisely. I will get into this topic in much more detail at
a later date, but for now this fact is shown clearly in a statement
made in 1905 by Norman Marshall. This is
shown in a clip from a 1905 Marshall Electric Manufacturing Company
catalog below, it is stated that about twenty years ago it was "impossible"
to get to any degree of accuracy when manufacturing porcelain for
electrical supplies. (more
on this here)
.
As a general rule seen by looking through different dated electrical
supply catalogs:
Fuse blocks started being changed from wood to porcelain about 1886
or 1887 and by 1888 wood was hard to find.
Rosettes changed from wood to porcelain about 1890 1891 and wood
was no longer found much by 1892.
Socket innards first used wood 1879 to 1883 or 1884 and then started
using different compositions and vulcanized fiber. Porcelain started
being used about 1889 or 1890 and other materials not seen much
by 1892 (though there are some exceptions). Porcelain remained the
common material for socket innards until about 1922 (and the following
years), when Bakelite began to commonly be used in it's place.
RETINITE
Also known as retin asphalt. It
is a fossil resin found in brown coal. It is found in roundish masses
of a yellow-brown or reddish color, is quite inflammable and readily
dissolves in alcohol. At present it is somewhat rare, but if it ever
should become common, it would undoubtedly find
a place in rubber compounding. Its specific gravity is 1.07
to 1.35.
RUBBER
ASPHALT
For road making, a late French patent covers a mixture
of rubber and asphalt,
that after intimate mixture takes the form of a powder. This is laid
hot and under test is very cheap and lasting. See
Asphalt
RUBBERBESTOS
A mixture consisting of rubber
and asbestos.
Patent no. 623,982
See Asbestos
RUBBERITE
An artificial rubber of the same specific
gravity as fine Para. In color, elasticity, capability for vulcanization,
and durability, it is said to resemble the higher
grades of rubber. It is the invention of H. C. B. Graves, London,
England, and is made up as follows: Trinidad
asphalt 47 to 80 per cent. Oxidized oil 20 to 30 per cent.
Vaseline 5 per cent. Sulphur 15 per cent. Chloride of sulphur 3 per
cent.
SOREL'S COMPOUND
A so-called substitute for guttapercha
consisting of 2 parts resin, 2 parts asphaltum,
8 parts resin oil, 6 parts slaked lime, 3 parts water, 10 parts potter's
clay, and 12 parts gutta-percha.
Five per cent, of stearic acid is sometimes added
SPANISH
WHITE often given to a good quality of whiting,
but originally given to a good kaolin clay prepared
for sale first by levigation, then by treatment with vinegar, which
separated out any calcium carbonate it contained, then washing well
and drying.
TABBYITE
A mineral product from Utah which seems to be a mixture of asphalt
and paraffin oils. It is easily manipulated and quite
elastic.
THESKELON
CEMENT
A metallic substance used for waterproofing and for certain kinds
of packings. It will neither expand, contract, nor rust. It is used
instead of wax for sealing purposes, and resists acids, alkalies,
and grease. It is often used in place of asphaltum.
It can be mixed with tar, pitch, asphaltum,
and other similar ingredients, the compound possessing extraordinary
adhesive power. Patented by Thomas Smith, London.
TREATED
PAPER
Treated Paper is a clear dry paper impregnated with oxidised linseed
rid, or a mixture such as oxidized oil and asphalt,
or a gum-base varnish. Well-treated papers in thicknesses ranging
from 6 to 12 mils break down at about 500 to 750 volts per mil. The
Mica Insulator Co. Gives disruptive voltages for Empire oiled papers,
in thicknesses of 1.5 to 18 mils, ranging from 1.740 to 800 volts
per mil; these values include condenser, rope, bond and cement paper
and fuller board. The same manufacturer gives for rope paper treated
with a compound of oxidised oil and asphalt,
disruptive voltages ranging from 1,600 to 600 volts per mil, corresponding
to thicknesses of 5 to 15 mils. According to Jona, the dielectric
strength of impregnated paper cable insulation is from 200 to 250
volts per mil, and the dielectric constant is about 2.5 to 4. The
value of the constant k for impregnated paper is usually between the
extremes of 1,000 and 3,000. Treated asbestos paper is impregnated
in this mannor and can be read about here.
TRINIDAD
ASPHALT
Trinidad Asphalt is obtained from the pitch
lakes of the island of Trinidad.
Its specific gravity is 1.2, and it is some what soluble in alcohol,
while Persian naphtha, oil of turpentine, benzol, and benzoline readily
dissolve it.
TURNBULLS
ANTI-FOULING RUBBER PAINT
Pitch and resin are melted together,
and then a mixture consisting of crude naphtha,
dissolved Para rubber, and sifted whiting is added thereto.
UNVULCANIZED
PACKING WASHERS
Goldstein claims in an English patent a washer material
for the sheet-metal lids of vessels is made, without containing sulphur,
of a mixture of crude rubber,
talc, asbestos, and gutta-percha.
VISCOID
A compound of viscose, formed by mixing with it hot bituminous matter
such as tar, pitch dissolved in coal tar,
or the like. The resultant mixture, when solidified, constitutes a
material of a high insulating character, and is produced at a low
cost. The bituminous and cellulose matter
may be mixed in equal proportions, although there is a wide range
of compounds that may be made through the use of various proportions
of the substances.
VITRITE
A jet black, perfectly hard material, having a smooth polished appearance
similar to ebonite. It is not affected by dampness or acids. It is
a good insulator, is of low cost, and easily worked.
VULCABESTON
A composition of asbestos and
india rubber, forming a product which is a nonconductor
of electricity and stands the severest tests, resisting heat wonderfully.
Invented by R. N. Pratt, United States.
VULCANINE
A mixture of india rubber, asbestos,
litharge, lime, and powdered zinc, to which is added a percentage
of sulphur. Mentioned in a patent granted to J. E. Hopkinson, West
Drayton, England.
VULCANITE
(also known as)
Ebonite, Hard Rubber
The first hard rubber was manufactured by the American Goodyear, and
he must be considered as the inventor. Solvents which dissolve the
natural raw caoutchouc, and partly dissolve vulcanized soft rubber,
have no influence at all on it, and the material offers the strongest
resistance to all kinds of acids. If it is exposed for a longer period
to a dry temperature of about 400° F., it does not become first
sticky and then melt, as happens under the circumstances to raw caoutchouc
and vulcanized rubber; it carbonizes at once, and goes through no
intermediate stage.
VULCANIZED FIBER - See
this page section for Vulcanized Fiber
This material, which is very largely used, is made of cotton paper
pulp, chemically dissolved, and solidified under enormous pressure.
It is unattacked by ordinary solvents such as alcohol, turpentine,
ammonia, etc. It appears on the market in two forms—hard and flexible.
The hard fiber resembles horn and is exceedingly tough and strong,
while the flexible fiber has the appearance of a very close-grained
leather. It is an insulator in dry places, but, as it will absorb
moisture, it is useless in places requiring waterproof qualities.
It is made in three colors—black, red, and gray. Vulcanized fiber
is unaffected by oils or fats, and will stand action of hot grease.
Low grades have been found adulterated with chloride of zinc and calcium,
to the extent of nearly 50 per cent, of its weight.
WOODITE
A name suggested by Sir E. J. Reed for an
india rubber compound invented by Mrs. A. M. Wood. It is
said to possess the elasticity of india rubber,
to be uninflammable, and not injured by salt water. It is used in
making valves, packings, etc. It is claimed that it will not become
sticky or soft under heat or steam pressure, and will stand hot grease
and other lubricants, and neither acids, alkalies, nor wastes from
oil refineries, distilleries, etc., affect it in the least. A compound
for woodite or whaleite packing is: asbestos
fiber 38 pounds, asbestos powder
38 pounds, earth wax 6 pounds, charcoal finely ground 9 pounds, ground
whalebone 20 pounds, Para rubber
80 pounds, and sulphur 5 pounds.
ZINSSER'S
BARREL LINING
A compound for lining casks, consisting of deodorized copal, rosin,
india rubber, and a nondrying
fat, with coloring matter, such as asphalt.
LIST
OF COMMON INACTIVE AND INERT INGREDIENTS USED
IN COMPOSITIONS
|
Sand,
clay and other inert ingredients were used as fillers (most times
termed as inactive ingredients) in different compositions.
Most inactive fillers were chosen for their properties and how they
would mix into or help the composition.
For example, sand for the silica or quartz which would provide hardness
and take heat well, and clay for the high resistance to heat as well
as the additional binding properties (and because of its small granular
size). You will often times find talc or ground up soap stone used
along side of these ingredients, to help provide additional resistance
to heat (and hardness if the composition was to be fired with clay
or mixed with plaster).
Since sands, clays and some other inert ingredients can play a big
part in compositions, using the particle
size chart might be of use to you when trying to id some materials.
EXAMPLE
OF THE PARTICLE GRAIN SIZE CHART IN USE
|
Update
and new info about this topic 11-23-2010 seen at
the bottom linked here |
This
is an example of a composition that was used to manufacture
an insulated tip, on some Bergmann
moving tongue sockets.
Using the enlarged picture below, and the chart above, it is
not hard to id mostly clay (but also likely some very fine sand)
as the particles here.
Sand will feel gritty when rubbed between your fingers, while
silt and clay will have more of a texture like flour. |
|
Grain
size is the scaled size ranges of diameter of the grains found
within a granular material (or in this case compositions). The
diameter of irregular sized particles, would be measured across
the longest distance between two points on its surface. Granular
material particles range in size through small colloidal particles
found in clay, silt, sand, gravel and boulders. The next smallest
type of measuring would be crystallite sizing. This would be
where you are measuring the size of a single crystal inside
the grain. A single grain can be composed of several crystals.
Powders are a special sub-class of granular materials, but we
will not be able to id them by grain size. A couple of the most
common in compositions would be plaster of paris and talc (or
ground soap stone) which is more like a fine dust when used.
The two most common granular substances in compositions, would
be fine to very find sand or silt, and different clays. |
|
HERE IS SOMETHING YOU CAN CARRY AROUND WITH YOU.
I found this credit card sized 'Comparitor' - (Cheat Sheet of Classic
Sedimentologists).
Untouched
version here.
Just to bring things up to date:11-23-2010
Sometimes things seem to move really fast for me. I was excited
and interested to learn about particle size measuring and felt that
it would be a great method for at least figuring out some basics
of different compositions. Don't get me wrong, it is a great thing,
but I found out much more and other methods of digging deeper too.
For starters in trying to find my own size compares, I had a hard
time trying to locate a place to purchase different small samples
of grain sizes. So, I purchased online a sieve
shaker kit (sand sifter) and a bag of sand from Home Depot.
Now at this point at least I could compare grain sizes next to the
different compositions I was testing. I still was not sure if this
sample was clay based or what it was really made from as I looked
through Edison history and documents. I had originally thought this
must be a composition based on testing done in 1882 and 1883 (Menlo
Park Notebook No. 143). Well, I purchased a large supply of magnesium
chloride and magnesium oxide and went
to work duplicating the Edison experiments and composition mixtures
and formulas. While I learned so many new things from this testing,
I also learned that this composition had nothing to do with these
composition recipes. I also learned that the naked eye and a good
camera with a macro lens mode, do not compare to a microscope or
400X magnification. I researched for days different types of digital
microscopes as to their compatibility, abilities, resolution, options,
etc., etc.. I came up with the VMS-004D
- 400x USB Microscope. I thought I was going to need to spend
a few hundred dollars (but I guess prices are coming down), this
cost me under $70.00 on Amazon.com. I should also say that I was
concerned that a digital camera type microscope would work just
like a digital camera in macro mode, and that it would be a waste
of money. I could not have been more wrong! With a camera you can
focus at the macro level and then that is it. However, while using
the microscope, you can find different zoom levels - and then focus
at that level. So, I was able to zoom in to this composition at
400x and focus in on the smallest area. WOW, what a surprise that
I was to find. Here is a pdf that I put together of this microscope
test, and then for anyone interested, here is a manual
for the microscope in case you are looking for one (as this
will provide lots more information about it and the software that
it comes with). Well as for the binder and this composition the
jury is still out as to what it actually is. All different kinds
of asbestos was being used at this time as well as new methods being
invented. As for cotton, I think that was more of a later thing
for these chemical compositions (i could be wrong), but yes as to
this being cotton from rag or pulp stock. I am also leaning towards
an Edison patent that I found as a real possible for this, but have
more testing to do. The time line is about right as the patent (no.
543986)
was applied for Oct 20, 1882 and with the title "PROCESS
OF TREATING AND PRODUCTS DERIVED FROM VEGETABLE FIBERS".
"I
have found that by treating fibrous vegetable materials of any
kind with strong hydrofluoric acid a remarkable chemical change
takes place in the structure of such material, the result being
a transparent or translucent, tough, pliable substance, which
is capable of being formed into any desired shape, and is adapted
for many different uses. This process is one quite distinct
from that of parchmentizing or vulcanizing vegetable fiber by
the use of sulphuric acid or chloride of zinc, the resulting
products being entirely different."
"The preferable process consists in soaking the fibrous
material, which may be a sheet or sheets of paper, a wooden
board, a strip or filament of bamboo or similar material, or
a thread of cotton or flax; in short, any fibrous vegetable
material in the acid, when a substance is produced of transparent
jelly-like appearance, but tough and flexible, impervious to
water, and a good electrical insulator, and also carbonizable."
"It is evident that this substance is suitable for a great
variety of uses, notably ' those for which hard rubber, vulcanized
fiber, and even leather have hitherto been employed." |
This
brings you up to date so far on this topic, I will post more after
further testing.
INACTIVE
MATERIALS USED AS FILLERS AND INERT INGREDIENTS
|
Sand, clay and other inert ingredients were used as fillers (most
times termed as inactive ingredients) in different compositions. Most
inactive fillers were chosen for their properties and how they would
mix into or help the composition.
For example, sand for the silica or quartz which would provide hardness
and take heat well, and clay for the high resistance to heat as well
as the additional binding properties (and because of its small granular
size). You will often times find talc or ground up soap stone used
along side of these ingredients, to help provide additional resistance
to heat (and hardness if the composition was to be fired with clay
or mixed with plaster). Since sands, clays and some other inert ingredients
can play a big part in compositions, using the
particle size chart might be of use to you when trying to id some
materials.
AGALMATOLITE
A silicate of aluminum resembling soapstone. It has no advantages
over talc, silicate of magnesia, or soapstone in rubber use. Its specific
gravity is about 2.25.
ALUMINA
(Aluminum Oxide)
The oxide of aluminum and a chief constituent of clay. Its specific
gravity is 4.15. Ordinarily speaking, it is a very inert substance,
insoluble, and not readily attacked by acids. It is best known in
the arts under the forms of corundum, emery, etc. As obtained chemically
it is a fine white glistening powder, harsh and dry to the touch.
Eaton's formula for the use of oxide of aluminum in making white rubber
was 'india rubber 40 per cent., oxide of aluminum 55 per cent, and
sulphur 5 per cent.
ALUMINITE
A white clay containing a large percentage of aluminum (about 30 per
cent.) And a certain amount of silica. Its specific gravity is low,
and its fusing point 2,400 degrees F.
ALUMINUM
FLAKE
A natural product in the form of a white powder, free from grit, with
a specific gravity of 2.58. It is a remarkable heat resistant, is
inert in compounds, and toughens them. It is a partial substitute
for zinc oxide, both for color and strength.
ALUMINUM
OXIDE
See Alumina.
ALUNDUM
A patented abrasive material made from oxide of aluminum or bauxite.
AMPHIBOLINE
A German earth. When wetted and dried, it will not absorb water again.
Specific gravity about 3.25. It is used in waterproofing, the product
being noninflammable. It is mixed with gelatine or size, no rubber
being used: 34 parts amphiboline, 9 parts gelatine, 2 parts chrome
alum, 2 parts ammonium sulphate, 53 parts water.
ANHYDRITE
The water-free form of sulphate of lime or gypsum, white in color
and crystalline in form. Its specific gravity is 2.9. It is formed
artificially by heating gypsum so as to drive off all its water. Gypsum
that has been overheated in the preparation of plaster of Paris and
that has lost its ability to "set" is pure anhydrite. It
is used as a filler in rubber compounding instead of whiting or Paris
white.
ANTIMONY
See Golden Sulphuret of Antimony, Black Antimony, and Kermes.
ANTIMONY
OXIDE
There are really three of these oxides. The trioxide, one most useful
in the arts, is a snow-white powder of the specific gravity of 5.2.
It may be obtained by treating stibnite or, better still, powdered
antimony metal with nitric acid, in a current of air sufficient to
carry off the copious fumes arising during the operation, or by treating
the chloride of antimony with cold water for several days. A mixture
of the trioxide with a small percentage of the insoluble peroxide
may be obtained by melting antimony in a cast iron retort fitted with
nozzles, through which air may be blown to agitate the melted metal.
Dense white fumes arise, which may be condensed in suitable chambers
into a snow-white powder. This is used in coloring dental vulcanite.
ARGILLACEOUS
RED SHALE
A shale that has a large amount of clay in it is termed argillaceous,
and the substance mentioned in the heading may be briefly termed clay
tinted red with oxide of iron. The analysis of argillaceous clay shows:
alumina 39, silica 46, water 13, iron, magnesia, and lime 2. It was
the basis of a well-known oil-resisting compound that for years baffled
imitation. Specific gravity 2.70.
ARSENIC
A white brittle metal, with a specific gravity of 4.7 or 3.7, according
to its form. Also a popular term for the oxide of arsenic, sometimes
called the white arsenic, which is a heavy white powder of the specific
gravity 3.7. It is slightly soluble in cold water and to the extent
of 10 per cent, in hot water. There are several coloring matters formed
from arsenic.
The most familiar are Paris green; realgar, which is red, and orpiment,
yellow. The white oxide is rarely used; the red sulphide is, however,
often used; the green has been used in mechanical rubber goods, but
the color was not a valuable one. Hancock vulcanized gutta-percha
with orpiment, and Forster used it in "mosaic work" for
floor coverings. An anti-fouling composition for ships' bottoms is
formed of gutta-percha, copper, bronze, and arsenic. Another is formed
of: india rubber 2 pounds, rosin 7 pounds and arsenic 2 ounces.
ASBESTIC
The part of the rock remaining after the richer veins of asbestos
have been extracted. This remainder is a purely fibrous material,
clearly showing its origin. For mechanical uses it is ground fine,
and for all sorts of fireproofing purposes is valuable and much cheaper
than long fiber asbestos. It makes an excellent compounding material
for asbestos packings, etc., In connection with rubber.
ASBESTINE
A pure fibrous silicate of magnesia, called also mineral pulp. It
is mined near Gouverneur, New York, where is the only deposit at present
known where magnesia shows so distinct a fiber. Apparently the pulverized
mineral is a very strong white powder, but in actual use it has not
much more covering quality than whiting. It was at one time used largely
in the manufacture of rubber shoes, but, aside from being inert and
a good filler, was probably no better than whiting, while it was more
costly. It is often used in white goods, in connection with oxide
of zinc, to make a light weight compound. It is also known as agalite
and asbestine pulp. Its composition is: silica 62, magnesia 33, water
4, iron oxide and alumina 1. Specific gravity 2.80.
ASBESTOS
(Amianthus)
A fibrous silicate of calcium and magnesia, also called stone flax,
salamander's wool (from an old belief that it was originally made
from the wool of the salamander), cotton stone, mountain flax, mountain
wood, and mountain cork. Its specific gravity is 3.02 to 3.1 An analysis
of the two best known varieties shows: Silica 40.92- 40.25 Magnesia
33.21- o n 40.18 Water of hydration 12.22 14.02 Alumina 6.69 2.82
Protoxide of iron 5.77 .75 Soda 68 1.37 Potash, etc 22 .15 Sulphuric
acid traces .31 The longest fiber is possessed by the Italian, which
is sometimes 3 feet in length. The Canadian ranges from 3 to 6 inches
in length, but it is finer, more flexible, and more easily separated
than the Italian. The mineral divides itself naturally into three
classes: the first, coarse, brittle, very plentiful, and cheap; the
second, possessing well-defined fibers of a brownish-yellow color,
fragile, and containing many foreign bodies; the third, with pure
white silky fibers which can be woven into textiles. A notable use
to which asbestos has been put is in the production of packing and
brake linings. Its low heat conductivity renders it particularly useful
in steam packings, both for cylinder work and for joints, while its
incombustibility has long caused it to be used for fireproofing purposes.
There are fibers formed of serpentine rock which are much used as
a substitute for genuine asbestos, and answer nearly as well, being,
however, shorter in fiber and somewhat less durable.
ATMIDO
A snow-white filler of low specific gravity, free from organic matter
and indifferent to acids. Used in small proportions, is said to increase
both strength and resiliency in soft rubber goods. Used in large proportions,
it makes a very hard compound, said to resist superheated steam. Of
German origin.
ATMOID
A very light white earthy matter of English origin. Analysis proves
it to be an almost pure silica—quite close, in fact, to infusorial
earth. Specific gravity 2.00.
BARIUM
CARBONATE
See Carbonate of Barium.
BARYTES
A heavy white mineral that in commerce takes the form of a fine white
or gray powder. It is obtained by grinding the mineral heavy spar,
or by chemical means from barium chloride. Its specific gravity is
4.5. It occurs in commerce under the names "permanent white"
and "blanc fixe." The
artificially prepared substance is to be preferred to the finely ground
mineral, on account of its less crystalline form. The commercial article
should always be examined to determine its freedom from acid impurities.
Barytes is chiefly used as an adulterant for white lead and paints.
Thus, Venice white contains equal parts of sulphate of barytes and
white lead; Hamburg white, 2 parts to 2 parts of white lead; and Dutch
white, 3 parts to 1 part of white lead. It is wholly inert when used
as an ingredient in rubber compounding, increases the resiliency of
rubber, and is a make-weight.
BASOFOR
A trade designation for a specially precipitated barium sulphate or
"blanc fixe." Used as an inert filler and pigment.
See Barytes.
BLACK
ANTIMONY
A black powder obtained by grinding stibnite or antimony ore. It is
a sulphide of the metal and is met with more or less pure, as it is
often prepared from a highgrade ore. The sulphur contained in it is
unavailable for vulcanizing purposes, and if used in compounding it
is necessary to add a sufficiency of sulphur to vulcanize. In the
purest form, black antimony contains about 28 per cent, of sulphur
and 72 per cent, of antimony. It is insoluble in water, but is dissolved
by muriatic acid or by caustic alkalies. From its solution in alkali
a fine brown-red powder may be obtained by treatment with a dilute
acid, and this powder, known as kermes, has the same chemical composition
as that mentioned above. Its specific gravity is 4.6. It was formerly
used sometimes as a filler, as it was believed to give a soft effect
in molded goods. It has been almost wholly displaced, however, by
cheaper and better ingredients.
BLACK
LEAD
See Plumbago.
BLANC
FIXE OR PERMANENT WHITE
Artificial barium sulphate, specially prepared by precipitation from
solutions of native barytes. There are several methods giving variations
in product adapting it to specific purposes. The specific gravity
is 4.10-4.20. The grain is extremely fine and amorphous. It is particularly
valuable as a filler and is said to enhance the tensile strength of
rubber. See Barytes.
BLUE
LEAD
Where zinc ores are found in combination with galena, or natural sulphide
of lead, the two are often smelted
together with raw coal and slaked lime, producing a fume called blue
powder, which is sold under the name of blue lead. It is an excellent
filler, but is not as good as sublimed lead, for example, as it does
not impart enough resiliency to rubber. Its chief merit is its cheapness.
A very fine quality of blue lead, containing considerable lead oxide,
is now on the market, but this must not be confused with either of
the two low-grade articles mentioned in these paragraphs. This blue
lead is of exceeding fineness, and gives a peculiarly soft finish
to the rubber. Used in the place of litharge, it materially assists
in the cure, and produces a fine black. As it has a high specific
gravity, it often displaces barytes. Blue lead is also a name given
to an artificial aluminous substance occurring either as a loose powder
or in a concrete form, colored blue by means of some kind of blue
dye—aniline or logwood—which does not contain lead.
BONE
ASH
See Calcium Phosphate.
BONEBLACK
See Charcoal (Animal).
BUCARAMANGUINA
A transparent amber-colored, incombustible material, found near
Bucaramanga, Colombia. It is somewhat similar to asbestos, for which
it has been mentioned as a substitute in the manufacture of packings.
BURNT
UMBER
An earth containing a large amount of iron oxide of a dark-brown
rust color. As mined, it is called raw umber, and the product obtained
by calcining it is known as burnt umber. It was formerly used in
brown packings, and to a certain extent, in maroon goods.
CALAMINE
An ore of the metal zinc, and a carbonate of zinc. Ordinary calamine,
which is a silicate of the metal, has a specific gravity of 3.6
to 4.4, and is little used in the arts. Noble calamine, or native
carbonate of zinc, is a gray or grayish yellow to brown powder,
according to its priority. Its specific gravity is 3.4 to 4.4. Its
nature is earthy, and heat has no action upon it. A little of it
is said to toughen soft compounds.
CALCIUM
CARBONATE
Very familiar under the native form of limestone, marble, or chalk.
See Whiting.
CALCIUM
PHOSPHATE OR PHOSPHATE OF LIME
The chief constituent of bones, forming the bulk of their ashes
when burnt. It is a white powder, and when in crystalline mineral
form, has a specific gravity of 3.18. It is insoluble in ether,
alcohol, or the benzine class of solvents. As it occurs naturally
it is known as flour of phosphate and is used in part as a substitute
for whiting. Bone ash made from animal charcoal is a common form
used in the same way.
CALCIUM
SULPHATE
Also called gypsum. A common mineral occurring under various forms
and names as alabaster, selenite, and gypsum earth. It is pure white
in color and has a specific gravity of 2.33. Plaster of Paris is
a calcined form of gypsum. In the ordinary recovery of rubber by
the acid process, whiting becomes changed from carbonate to sulphate
of calcium, otherwise sulphate of lime. See Plaster of Paris and
Anhydrite.
CALCIUM
WHITE
Another name for whiting.
CALOMEL
A white, inodorous powder of specific gravity about 7.2. It is permanent
in the air, but should be kept in the dark, as light blackens it.
When pure, it may be wholly volatilized by heat. Calomel blackens
under the action of alkalies. It is insoluble in water, alcohol,
ether, or benzine. It is the basis of a compound for rendering hose
waterproof, the other ingredients being magnesia, black antimony,
oxide of zinc, tar sulphur and india rubber. Its function in rubber
is to hasten the cure.
CARBONACEOUS
CLAY
Found near Lake Albert, South Australia. After being boiled at a
high temperature with caustic soda and washed with a weak solution
of sulphuric acid, it assumes a remarkably light, spongy, elastic
character. It is used as an absorbent, and as a substitute for cork
in linoleum. It has been suggested as an ingredient for use in connection
with rubber for playing-balls, etc.
CARBONATE
OF BARIUM
Known also as witherite; has a specific gravity of 4.3. It is a
white powder insoluble in water and alcohol. See Barytes.
CARBURET
OF IRON
A name given to a mixture of graphite and oxide of iron. A fine
black-brown powder, specific gravity 4.00, although variable. It
makes a fair filler in compounding, being inert and strongly coherent.
In packings it has been largely used, and also in compounds for
wagon covers and tarpaulins before reclaimed rubber came largely
into use. It has also been used in cements for card clothing.
CHALK
A white, soft, somewhat gritty substance, consisting chiefly of
carbonate of lime. It is made up of myriads of very small shells
of marine animals long extinct. Its nature is earthy; that is to
say, it is not easily affected by ordinary bodies. Acids disengage
carbonic acid gas from it. Its specific gravity is 2.9. If heated
to a red heat, carbonic acid gas escapes and quicklime is left behind.
See Whiting.
CHARCOAL
(animal)
Animal charcoal is made from bones distilled out of contact with
air and has the property, in a high degree, of absorbing odors and
soluble coloring matters. It is often used, therefore, in deodorizing
rubber goods, and experimentally by chemists for filtering gutta-percha
dissolved in bisulphide of carbon, where a perfectly clear product
is desired. Its use is advised by Forster in gutta-percha compounds,
and by Warne, Jaques, and others for packings to withstand heat.
Its specific gravity is about 2.85.
CHARCOAL
(vegetable)
This is a popular term for the coal produced by the charring of
wood. There are many materials which are really charcoals, such
as animal charcoal just quoted, carbon, coke, graphite, and wood
charcoal. All of these are practically the same in their pure states,
being almost wholly carbon. Wood charcoal—that which is meant in
rubber compounding by vegetable charcoal—consists of carbon, hydrogen
and oxygen, the last two being in the proportion to form water.
It is black and brittle, insoluble in water, infusible, and nonvolatile
in the most intense heat. It has the power of condensing gases and
destroying odors. Charcoal may or may not be a bad conductor of
heat and a good conductor of electricity, these properties depending
upon the wood from which it is made. Technically, it is divided
into hard wood charcoal and soft wood charcoal. Its composition
at ordinary temperatures is about as follows: carbon 85 per cent.,
water 12 per cent., ash 3 per cent. Specific gravity (powdered)
1.40 to 1.50. It is used in rubber compounding in certain vulcanite
varnishes and in certain insulated wire compounds. For the latter
use, willow charcoal is
preferable, as it is a decided non-conductor. It has also been used
in sponge rubber, with the idea that it acts as a preservative in
a compound which is very likely to be short-lived. Macintosh used
large quantities of ground charcoal in place of lampblack in some
of his compounds. A French substitute for vulcanite paints or lacquers
is made of 10 pounds of bitumen, 15 parts of charcoal, and a little
linseed oil, mixed by heating.
CHINA
CLAY
See Kaolin.
CLAY
- (see kaolin)
Clay is a naturally occurring material composed primarily of fine-grained
minerals.
Clay was often chosen for its small granular size. As shown in the
particle chart above, clay is the smallest particle in size before
needing to move to a new type of measurement.
The most popular clay used in early compositions was Kaolin
which is a natural 'plastic like' clay which will harden when fired
or dried.
COMPO
A name for a composition used in rubber manufacture in the United
States years ago, but not in use now. The name, however, clings
to two compounds sold by an English chemical house for use in rubber
work. They are of a secret nature. No. 1 is used in the manufacture
of oil-resisting valves and in tubing for chemical factories, in
the proportion of 30 pounds of compo to 10 pounds of rubber. No.
2 is used for soles for tennis shoes and in mechanical goods, in
the proportion of 25 pounds of compo to 10 pounds of rubber.
CORK
is the bark of the cork oak, native of Southern Europe and Northern
Africa. The chief supplies come from Spain and Portugal. Cork is
the basis of the fine black known as Spanish black, which is made
by burning the refuse in close vessels. In granulated or powdered
form, cork has long been a favorite ingredient in rubber compounding.
Not that it is used in any such measure as whiting or barytes, but
many mills have used it, and a few in large proportions. Used in
connection with india rubber and gutta-percha, it has been the subject
of about fifty patents. Its largest use, perhaps, was in the manufacture
of kamptulicon, where india rubber is used as a binding material,
and in linoleum, where oxidized oils are used in place of rubber.
It was also used in what was known as leather rubber, in which palm
oil distillate, a little india rubber, and a good deal of granulated
cork were used. At one time it was also compounded with rubber and
made up into a waterproof felt for hats. It also went into compounds
to resist heat, into cricket balls, and into golf balls, where it
was compounded with gutta-percha and enough metal filings were added
to give the necessary weight. A rubber blanket used in special manufacture
also had its surface covered with granulated cork as an absorbent
material. In some cases the cork was charred and roasted to remove
what resinous matter might be in it, while in others resinous matter
was removed by boiling in alcohol. In its usual form cork has a
specific gravity of 0.24. Fine grinding eliminates much of the contained
air with proportionate rise in specific gravity.
CORNWALL
CLAY
See Kaolin.
CORUNDUM
A mineral which is nearly pure alumina, yet of great specific gravity,
and of exceeding hardness, being inferior, in this respect, only
to the diamond. Emery (which see) is a variety of Corundum. Specific
gravity 3.90.
DIATOMACEOUS
EARTH
See Infusorial Earth.
ELECTRIC
FINISH
See Farina.
EMERY
The average composition of emery may be taken as alumina 82, oxide
of iron 10, silica 6, lime \y2. Its specific gravity is about 3.8
to 4. It is prepared by breaking the stone at first into lumps about
the size of a hen's egg, then running it through stamps, and crushing
it to powder. It is then sifted to various degrees of fineness,
and graded according to the meshes of the sieve. Emery is next in
hardness to diamond dust and crystalline corundum, and it is used
chiefly as an abrading agent. Prior to the invention of vulcanite,
emery wheels were made by heating clay and emery in suitable molds,
thus vitrifying them like common earthenware. In rubber mills it
is chiefly used in the manufacture of what are known as vulcanite
emery wheels. It is also used in grinding and sharpening compounds,
as hones and strops. (See also Alumina and Corundum.) A certain
amount of it also gives' the desired surface to rubber blackboards.
FARINA
This is sometimes used in small quantities in unusual mixtures as
a compound, but has little value, as there are many better substitutes
for it. A practical use for it, however, is the brushing of a rubber
surface with it before vulcanization, when it is necessary to have
printing or stamping done upon that surface afterwards. Farina is
made largely of potatoes, another name for it being potato starch.
The process consists simply of crushing, sifting, washing, bleaching,
and grinding, which is repeated three times, and each time the starch
granules separate and are collected. It has a specific gravity of
1.50. Potato starch will be remembered by rubber manufacturers as
the, material which the gossamer makers used successfully for a
number of years in the production of the "electric" or
"corruscus" finish. Bone ash is used sometimes in the
place of farina, where rubber surfaces are to be printed upon.
FELDSPAR
A name given to a group of silicates of which the principal ones
are orthoclase or potash feldspar, containing silica, alumina, and
potash, and having a specific gravity of 2.5; albite, containing
silica, alumina, and soda, specific gravity 2.61; oligoclase, containing
silica, alumina, soda, and lime, specific gravity 2.66; and anorthite,
containing silica, alumina, and lime, with a specific gravity of
2.75. The feldspars by the action of the weather break down into
china clay, kaolin, or pottery clays. Ground very fine, they have
been used in the production of rubber enamels and lacquers.
FIRE CLAY
A kind of clay which, better than any other, resists the action
of heat and direct flame. It is composed principally of silica and
alumina, with traces of the alkali earths. The best is found in
conjunction with coal, and is called Stourbridge clay. Its specific
gravity is about 2.5, and its color dirty white. Mixed with vulcanized
india rubber dissolved in tar oil and sulphur, it forms a compound
which, when applied to hot joints, cures at once.
FLINT
is practically pure silica and its specific gravity is 2.63. The
nature of the powder obtained by grinding is always sharp and gritty.
It is unacted upon by all ordinary means, and with difficulty even
in the laboratory of the chemist. Its principal use, perhaps, is
in the manufacture of glass. Flint varies in color from yellow and
brown to black. It has been used in erasive rubbers, although pumice
stone is better.
FLOUR
OF GLASS
Glass powdered and sifted through a fine sieve of 150 meshes to
the inch. Glass varies much in its composition, the more common
kinds containing lime, while the so-called flint glass contains
lead. Potash and soda also enter into the composition of glass;
hence all flour of glass will contain those ingredients which entered
into the composition of the glass it was obtained from. Its specific
gravity ranges from 2.40 to 3.00 for ordinary compositions. Generally
speaking, flour of glass may be considered an inert substance under
ordinary conditions, though the softer kinds are attacked even by
boiling water. It was used by Newton and Wray in insulated wire
compounds, and has also been used in certain packings.
FLOUR OF PHOSPHATE
See Calcium Phosphate.
FOSSIL
FARINA
Fossil Farina , also called mountain milk, is an earth physically
similar to infusorial earth. It is obtained from China and consists
of silica 50J4, alumina 26y2, magnesia 9, water and organic matter
13, with traces of lime and oxide of iron. It has been used in rubber
compounding for the production of packings and semi-hard valves.
FOSSIL
MEAL OR FOSSIL FLOUR
See Infusorial Earth.
FRENCH
CHALK
This is ground and sifted talc, forming a white, greasy-feeling
powder. I^s chemical composition is hydrated silicate of magnesia,
the water being chemically combined. Its specific gravity is 2.70.
See Talc.
FULLER'S
EARTH
A kind of clay. It is a greenish or brownish earthy, somewhat greasy-feeling
substance, having a shining streak when rubbed. Its composition
is: silica 70, oxide iron 2.5, alumina 3.5, lime 6, combined water
16, magnesia trace, phosphoric acid trace, salt 2, alkalies trace.
Fuller's earth is found in extensive deposits in England, where
its annual consumption at one time exceeded 2,000 tons, chiefly
in woolen manufacture for fulling cloth. Its specific gravity is
from 1.8 to 2.2. It is used in rubber compounding for about the
same purposes as infusorial earth, and is also used in the manufacture
of rubber type.
GOLD
OXIDE
As a matter of curiosity it may be noted that this is the most costly
ingredient suggested for rubber compounding. It occurs in two forms—the
protoxide, a dark green or bluish violet powder, and the teroxide,
a brown powder. The use of the protoxide was patented by Ninck.
For dental vulcanite it is doubtful if either form of the oxide
could be used, even if the price were so low as to bring it within
reach. Another formula calls for the mechanical admixture of gold
leaf.
GRAPHITE
See Plumbago.
GRAVEL
GYPSUM
See Calcium Sulphate.
INFUSORIAL
EARTH
It is known also as diatomaceous earth, Tripoli, fossil meal, mountain
flour and kieselguhr. This is obtained usually from deposits at
the bottom of inland waters, and consists of the minute siliceous
remains of infusoria or microscopic animals. The largest deposits,
in the form of a fine white or pinkish powder, are found in California,
Nova Scotia, and in Germany. This earth is a wonderful non-conductor
of heat, and, in connection with asbestos, is used in the manufacture
of boiler coverings. It is used also in small proportions in various
rubber compounds, where it increases both strength and resiliency,
though if used in excess it makes a very hard compound. The best
grades are wholly free from vegetable matter, are nearly pure silica,
and perfectly indifferent to corrosive substances. Under the name
of diatomaceous silica it is used in a formula for elastic valve
packing. This packing is described as practically indestructible
in steam or water, oils, acids, etc. Specific gravity, 1.66 to 1.95.
IRON
PYRITES
A natural sulphuret of iron, about 5.20 specific gravity, commonly
of a bright, brass-yellow color; a very plentiful mineral often
mistaken for gold. It is used in the manufacture of sulphuric acid,
while sulphur is also obtained from it by sublimation. It was used
by Wame, Fanshaw, and others, in the manufacture of packings to
resist a high degree of heat. The sulphur in iron pyrites has also
been used in vulcanization. Warne, in one of his heat-resisting
packings, patented the use of iron pyrites, and, in the compound
that he gives as an example, leaves out the whole or a portion of
the sulphur usually employed.
KAOLIN
aka: kaolin powder, cornwall clay, china clay
- From Kaolinite Al2O3.2SiO2.2H2O
Kaolin is a natural white clay whose chief ingredient is the mineral
kaolinite which has the specific gravity 2.20. Kaolin is highly
refractory and is one of the principal materials employed in the
manufacture of porcelain for insulating purposes. It is used in
some rubber compounds, and has been used as an inert ingredient
in many documented compositions. Kaolin was also tested as an inert
ingredient in the Edison cement tests that I covered
here,
and was documented in the Menlo
Park Notebook No. 143 (which covered the time periods from December
2 1882 and March of 1883). It was also used in another Edison
/ Bergmann asphalt composition which I documented here. (Also
see spanish white, bougival
white)
Kaolin is chemically classed under aluminum silicates, which is
basically a compound of alumina and silica which is a natural occurrence
in nature (not man made). Kaolin becomes almost like a plastic when
mixed with water. Pure kaolin has the chemical composition of Al2Si'O7.2H2O
and contains 39.4 per cent. Of alumina or 20.9 per cent. Of aluminum;
if water is removed, the residue will contain 45.9 per cent. Of
alumina or 24.3 per cent. Of aluminum. Common clay contains from
50 to 70 per cent. Of silica and 15 to 35 per cent. Of alumina,
and are not normally able to classify into a definite formula composition
as kaolin is.
KERMES
A brownish-red form of sulphide of antimony, artificially prepared
by boiling in carbonate of soda. If left to itself the solution
will partly deposit a very fine powder of kermes, while the clear
solution may be further treated with a weak acid to obtain the remainder.
Kermes will not vulcanize rubber without the addition of sulphur.
Its specific gravity is about 4.5. Its composition is 28 per cent,
sulphur and 72 per cent, antimony. It is rarely used in rubber compounding.
KIESELGUHR
See Infusorial Earth.
LEAD
ACETATE OR SUGAR OF LEAD
A white poisonous powder soluble in water and alcohol. In its crystalline
form it contains about 7 per cent, of water of crystallization,
which is easily driven off at a temperature of, say, 80 degrees
to 100 degrees'F. Its specific gravity is: crystallized, 2.3; water-free,
2.5. Its use in semi-hard composition was patented by both Goodyear
and Payen. India rubber dissolved in oil, to which has been added
acetate of lead, is used to fill the pores of certain leathers so
that the "filling" shall not come through. It is also
used in certain varnishes in connection with guttapercha.
LEAD
CARBONATE
See White Lead.
LEAD
OXIDE
See Minium and Litharge.
LEAD
OXYCHLORIDE
There are several oxychlorides of lead. Their specific gravity may
be taken at 7.20. The substance once known as Turner's yellow and
another known as Carsel yellow were both of this composition. More
recently a white compound has been prepared, which, from its covering
power, has been used largely as a paint. Tarpaulin compounds consisting
of india rubber, coal tar, and pitch are treated with oxychloride
of lead for surface drying, in lieu of vulcanization.
LEAD
PEROXIDE
The highest oxide of lead—a dark brown powder with a specific gravity
of about 9.00. It is easily decomposed, and from this characteristic
it has a strong oxidizing action. Exposed to sunlight or to heat,
it yields oxygen and passes into the lower oxide known as red lead.
Its oxidizing properties make it a questionable ingredient in compounding
rubber, although certain formulas call for its presence.
LEAD
SULPHATE
A white powder of the specific gravity of 6.2, insoluble in water,
but readily soluble in caustic alkalies. In Cooley's formula for
artificial leather, which has gutta-percha for a base, it is used
in connection with dextrine, magnesia, and cotton dust.
LIME
The oxide of the metal calcium. It is commonly known in two states,
viz.: quicklime, which is the pure oxide, and slaked lime, which
is the hydrated oxide mixed with some carbonate. Quicklime is a
white solid substance of specific gravity 3.2. It, is not stable,
taking up water and carbonic acid from the air and breaking down
into a fine white powder, usually called air-slaked lime. Its power
of absorbing water has caused it to be favorably used in drying
operations, while the insoluble compounds it forms with various
oils have led to its being considered as a drier, although this
action is not properly to be called one of drying. Lime, air-slaked
(specific gravity 2.40), is used in rubber work, where there may
be a little moisture in a compound, which it readily neutralizes.
It is also used in soft cements in connection with tallow and india
rubber, but only where the rubber has been melted and the cement
is of the nondrying variety. In compositions like that of Sorel's,
lime is introduced to effect a combination between resin acids found
in the resin and resin oil. Excess of lime in india rubber is injurious,
because it renders the compound too dry, thus inducing oxidation.
When used in small quantities, aside from its effect upon moisture,
it combines with free sulphur and modifies its continued action
upon the rubber. It must be remembered, however, that lime diminishes
the resiliency of india rubber, while it increases the hardness
of both hard and soft rubber. It may be used in small quantities
in insulated wire, and in a measure assists the insulating capacity
of the rubber. Rubber also cures quicker when compounded with lime.
LITHARGE
One of the oxides of the lead, known as the monoxide. When pure
its specific gravity is 9.36. Commercial litharge often contains
carbonic acid gas and water taken up from the air. These may be
removed by strong heating, It has a peculiar property, the nature
of which is yet a debated question, by virtue of which it renders
oil more easily oxidized, or, as it is commonly called, rendered
dry. There is no reason to suppose that this action is available
with caoutchouc. The best litharge is made from pig lead, which
is placed in a reverberatory furnace and exposed to a current of
air, which burns it to an oxide. It has been noted in rubber factories
that certain men seem sensitive to the effects of litharge, often
developing symptoms of lead poisoning. Persons who show any symptoms
should pay scrupulous attention to personal cleanliness. It is said
that such persons have been cured
by taking them out of the mixing room entirely, and putting them
to work on vulcanizers, particularly where they open and handle
the goods from the finished heat, the theory being that the sulphur
fumes neutralize the effects of the lead. Possibly there is a grain
of wisdom in this, for the old-fashioned treatment for lead poisoning
was sulphur baths and the drinking of water acidulated with sulphuric
acid or the acid sulphate of magnesia. Litharge is not only a valuable
filler for rubber, but has the faculty of hastening vulcanization
in a marked degree. In other words, it is an accelerator. All dry
heat goods depend upon it, and in mold work and general mechanical
goods it is used whenever possible. Of course, it is generally available
for dark or black effects only.
LITHARGRITE
A substitute for litharge, made of a mixture of pulverized and calcined
magnesia and oxide of lead.
LITHOPONE
See Colors.
MAGNESIA
A calcined white dry powder which, with water, forms a hard, compact
mass like marble. Its specific gravity is 3.65. It is earthy in
its nature, having no taste, but producing a sense of dryness in
the mouth, owing to its absorption of moisture. It is frequently
called calcined magnesia from the method of preparation by burning
magnesia alba. Its use in rubber is to increase its toughness and
resiliency, which it does to a marked degree when used in moderation.
Magnesia is also used in the production of compounds like balenite,
its use in hard rubber compounds being to increase resiliency as
well as hardness. A very small quantity of it is also used in compounds
for insulated wire, where it is said to increase the insulating
qualities of rubber. Carbonate of magnesia occurs native in the
mineral magnesite and, in connection with carbonate of lime, as
dolomite. There
exist two kinds of calcined magnesia: the heavy and the light calcined.
Heavy calcined magnesia is produced by calcining heavy carbonate
of magnesia, which carbonate is won by precipitation of hot magnesia
solutions by hot solutions of soda. The light calcined magnesia
is produced by calcining the light carbonate of magnesia, and this
light carbonate is the precipitation product of magnesia solution
together with soda solutions,
both carefully cooled. The difference between kinds of calcined
magnesia concerns only the structure, so that light calcined magnesia
in a dry state seems to have a very big volume, but if the included
air is expelled, the big volume cannot have the expected effect,
if light calcined magnesia is knealed together with india rubber
on the mixing rollers. The vulcanization of india rubber can easily
be accelerated by addition of calcined magnesia. Such an addition
is often necessary with soft rubbers in open steam-cured compounds.
Rubbers with a high amount of resins, such as Guayule, Cameroons,
Assam, Borneo, etc., usually give better results if compounded with
appropriate additions of calcined magnesia.
MANGANESE
PEROXIDE
Another name 'for black oxide of manganese, which is a black powder
having a specific gravity of 4.8. It is not readily acted on in
ordinary ways, being unchanged by heat short of bright red. It is
insoluble in the ordinary hydrocarbon solvents. Solvent naphtha
was treated with peroxide of manganese by Humphry to free it from
water.
OXIDES
OF MANGANESE
Oxides of manganese have a destructive effect on rubber, and blacks
that contain this, as they sometimes do, are to be avoided. Manganese
is used in connection with pitch, turpentine, and gutta-percha for
making Brandt's cement.
MARBLE
FLOUR
This is the finely ground chips of white marble, composed almost
wholly of carbonate of lime. It is a heavy inert powder used in
rubber compounding as a substitute for barytes. It has also been
used to some extent in hard rubber, and in the manufacture of hones.
Specific gravity 2.65 to 2.75.
MASSICOT
A monoxide of lead (lighter yellow than litharge). Specific gravity
7.90. A higher degree of oxidation turns this into a product called
minium or red lead. It is often used in rubber compounds, acting
practically like litharge.
MICA
is the name given to a group of complex silicates containing aluminum
and potassium, generally with magnesium, but rarely with lime. Their
specific gravity ranges from 2.8 to 3.2, while their color varies
greatly. Ground mica is simply one or other of these micas reduced
to powder. It is used in rubber compounding chiefly for insulating
purposes. It is handled as a cement, compounded with rubber, and
cut with benzine, or may be mixed dry on the grinder. It is also
used in fireproof coverings in connection with rubber, and it is
said that for a semi-hard result that is to come in contact with
hot water, rubber and mica form the best compound. Mica in a state
of a very fine powder is also known as "cat's gold" or
"cat's silver."
MINERAL
WOOL
Produced by sending blasts of steam through molten slag, which reduces
the fluid metal to a fiber similar to the fused glass that is spun
into glass silk. Natural mineral wool, such as is found in the Hawaiian
Islands, is very brittle, but the artificial has considerable toughness.
It is also known as slag wool, or silicate cotton. It appears in
light fleecy masses, and at a distance looks like fine cotton batting.
It is very cheap, but is easily affected by weak acids, and should
be kept away from a moist atmosphere. It has not been largely used
in rubber work as yet, but Lascelles-Scott strongly advises its
use, giving as reasons its cheapness and its physical fitness. The
sulfide's present in it also assist in vulcanization.
MINIUM
See Red Lead.
MOUNTAIN
FLOUR
See Infusorial Earth.
ORANGE
MINERAL
A red lead made from carbonate of lead, while red lead is made from
litharge. As a general rule, it contains some lead carbonate. It
differs from red lead in color, in that it is more orange red, and
more brilliant. The reason for this difference is that it is less
crystalline, its particles being much finer than those of red lead.
The pigment is also more bulky and much smoother. It is used in
finer grades of dark rubber, to assist the cure and impart resiliency.
Its specific gravity is 6.95.
OSSEIN
A light powder made from specially treated bone. Said not to be
affected by acids. Is not affected by heat and is not hygroscopic.
Preparation patented in England by J. F. Hunter.
PAGODITE
A mineral resembling steatite or soapstone. Its name comes from
its having been used in the East as a material for carving miniature
temples or pagodas from, as it is soft enough
to be cut with a knife. Its specific gravity is the same as that
of soapstone (about 2.70), and its color greenish white. See Agalmatolite.
PARIS
WHITE
This has exactly the same composition as whiting, but is a much
harder and more compact form of English chalk, and therefore has
greater density. Spanish white is a coarser variety of the same
material. Its uses are practically the same as those of whiting.
Specific gravity 2.70. See Whiting.
PERMANENT
WHITE
See Blanc Fixe.
PETRIFITE
A white powder composed of two inexpensive but secret substances.
When mixed with water it solidifies quickly, and is an excellent
binding substance. Mixed with marble dust, it is sometimes melted
and cast upon glass or other smooth surfaces, and makes an excellent
table-top in place of the zinc tables used in many rubber factories.
As it is perfectly impervious to ordinary solvents, neither cement
nor india rubber sticks to it. It is manufactured in England.
PHOSPHORUS
A non-metallic element or metalloid, although in its combining relation
it is more closely connected with arsenic and antimony than with
any members of the sulphur group. It is found ordinarily in two
states—the ordinary phosphorus and the red variety. Ordinarily phosphorus
is an almost colorless or faintly yellow substance, somewhat resembling
wax, and giving off a disagreeable odor. It fuses at 111.5 degrees
F. into a colorless fluid. Heated in the air to about 140 degrees
F., it catches fire and burns with a bright white flame. It dissolves
freely in benzol, bisulphide of carbon, and in many oils. Red phosphorus
is an amorphous powder of a deep red color, with no odor, and may
be heated to nearly 500 degrees F. without fusing. Its specific
gravity is 2.10. It does not take fire when rubbed, undergoes no
change on exposure to the air at ordinary temperatures, and is far
less inflammable than ordinary phosphorus. It is insoluble in solvents
of the ordinary phosphorus, and is not poisonous. Mulholland made
an insulated wire compound from shellac and india rubber in solution,
combined with one to two per cent, of phosphorus, which he cured
with chloride of sulphur. As cold-cure gums are of little value
as insulators his invention is of doubtful value. He also made a
preparation of india rubber, resin and tallow, and shoddy, to be
applied in a fluid state where gas came in contact with rubber,
adding phosphorus after his solution was finished, to prevent decomposition
of the rubber. Duvivier also treated guttapercha with sulphide of
phosphorus, claiming that he got an elastic result, but allowing
that his compound was damaged by acid vapors, to neutralize which
action he mixed carbonate of soda with it. An anti-fouling preparation
of English origin was also made of gutta-percha, turpentine, and
a little phosphorus.
PIPE
CLAY
A peculiar kind of clay containing neither iron, sand, nor carbonate
of lime. It is beautifully white, retaining its whiteness when burnt.
Its specific gravity is 2 to 2.5. It was used by Mayall in combination
with gutta-percha, india rubber, zinc, shellac, and resin for insulating
tape, and by Austin G. Day to absorb gases during vulcanization.
PLASTER
OF PARIS
This is prepared by calcining gypsum or sulphate of lime. Its properties
of hardening when made into a paste with water are well known. It
is used sometimes instead of lime in compounding and also for making
trial molds for rubber work. It was used in old-fashioned dry heat
compounds to prevent blistering. Specific gravity 3.2. See Anhydrite.
PLUMBAGINE
A dark-colored pigment manufactured in England and sold to rubber
manufacturers for the production of valves. By its use the rubber
is vulcanized and goods made which are said to resist successfully
the action of cheap lubricants. One pound of plumbagine is used
to two pounds of rubber.
PLUMBAGO
This sometimes is called black lead, though having no relation to
lead; it is also called graphite. Its specific gravity is 2.1 to
2.2. Its color is black and shiny. It consists chiefly of carbon,
but contains more or less alumina, silica, lime, iron, etc., varying
from 1 to 47 per cent., but not chemically combined. Black lead
is a perfect conductor of electricity. It is more incombustible
than most ingredients used in rubber compounding, and is capable
of withstanding great heat. It is used in the rubber industry, chiefly
in the manufacture of what are known as graphite or plumbago packings.
It is a wholly inert substance, safe to use in connection with any
compounds, and is not affected by heat or acids, alkalies, or corrosive
substances. It is useful also in certain polishing compositions
made with india rubber as a base. Almost all German asbestos cements
contain a proportion of finely powdered graphite.
PORTLAND
CEMENT
was first obtained by burning the mud found at the mouths of several
large rivers in Europe with a proportion of clay and lime. Its composition
is somewhat complex, containing: lime 55 to 63 per cent., silicic
acid 23 to 26 per cent., alumina 5 to 9 per cent., And oxide of
iron 2 to 6 per cent., together with magnesia, potash, soda, sulphate
of lime, clay, or sand in various small proportions, according to
the mode of manufacture. Its specific gravity is 3.00-3.10. Its
value as a cement depends upon the interaction of the lime and the
silicic acid. In compounding it would have no chemical effects upon
rubber, but might of itself become much hardened and thus cause
mechanical injury to goods in which it has been introduced. As it
occurs commercially, it is a gritty powder of a gray-brown or yellow-brown
color. Its only use as far as known in rubber is where it is mixed
with tar oil and waste rubber to joint pipes containing fluids.
POWDERED
COAL
Coal consists chiefly of carbon, and is universally regarded as
being of vegetable origin. Various coals differ widely in their
composition and characters, running from the softest kinds of earths
to compact and solid bodies like parrot coal, which is so compact
and solid that it has been made into boxes, inkstands, and other
articles which resemble jet. The average specimen of coal analysis
is: carbon 82.6, hydrogen 5.6, oxygen 11.8. Some curious compounds
of india rubber and coal have been formed. One, for instance, was
a mixture in which two pounds of waste india rubber in a cheap solvent
was mixed with nearly a ton of powdered coal (specific gravity 1.25-1.75),
which contained some clay and peat, the use being for an artificial
fuel; another use was in the production of hard rubber.
PUMICE
A light, porous, ashy stone, specific gravity 2.202.50, the product
of volcanic action, its structure being that of a mass of porous
glass. Its composition is a mixture of silicates of aluminum, magnesia,
calcium, iron, potassium, and sodium, varying with the particular
lava whence it had its origin. Its action on india rubber will be
quite inappreciable, chemically speaking, but its mechanical action
will be that of a sharp cutting powder. Ground fine, it is used
in the manufacture of erasive rubber, and is also used compounded
with the rubber in the manufacture of hones. Recent patents call
for its use in certain semi-hard compounds, its presence being said
greatly to increase their toughness. Mixed with lard oil to a thick
paste, this has been used for polishing india rubber It is particularly
valuable for use in the dry-heat cure of such articles as water-bags
and bottles. The goods filled, bedded and covered with fine pumice
powder are evenly cured without discoloration or change of color.
In this respect pumice is superior to talc for the purpose, and
the goods are more easily washed clean.
PUZZOLANA
A porous lava found near Naples, used chiefly, when mixed with ordinary
lime, in forming hydraulic cement. Compounded with marine glue,
it is used as a varnish for preserving metallic articles from corrosion.
RED CHALK
Artificially deposited chalk colored by any suitable pigment—usually
one of the red oxides of iron. See Chalk.
RED
LEAD
An oxide of the metal, which is also known as minium. Prepared from
pure massicot or from white lead. Its specific gravity is 8.6 to
9.1. A scarlet crystalline granular powder, of rather strong coloring
powers. As a colorant in rubber work it would be unavailable, since
the sulphur necessary to vulcanize would render it more or less
black, owing to the formation of sulphide of lead. It is sometimes
used, however, in place of litharge. It is also used in "hot"
cements of gutta-percha and for varnishes such as those made of
india rubber, linseed oil, etc., for covering the backs of mirrors.
See Minium, Massicot, and Orange Mineral.
ROTTEN
STONE
Usually considered to be the residuum of naturally decomposed impure
limestone, and varying in composition with its sources. Specific
gravity 1.98. That from Derbyshire, England, shows much alumina;
other sorts have more silica. The name is sometimes incorrectly
given to "Tripoli," which is a species of infusorial earth.
It can have no particular action on rubber, as it is very inert,
but it is used in certain packings, and was also used by Warne in
insulated wire compounds.
SAND
Sand
was documented as being used by Edison, his Companies and his employees
in many different compositions and experiments. Here in
a letter from Edison to Charles Batchelor
(December 28th 1882) "finely powdered sand" is used in
a new composition being tested.
SELENIUM
A non-metallic element or metalloid of a darkbrown color, analagous
to sulphur. Specific gravity 4.80. It has no smell and is a non-conductor
of electricity. It occurs rarely in nature, being found chiefly
as a selenide in combination with lead, silver, copper, or iron.
It is the basis of an unused process for vulcanizing india rubber.
SILEX
Pure silica. See Flint.
SILICA
The oxide of the metal silicon, familiar in the forms of flint,
quartz, etc. Its specific gravity is 2.6. It is without action on
india rubber, except mechanically speaking. It is used in Chapman's
vulcanite enameling solution, made of india rubber, sulphur and
silica. See Flint.
SILICATE
COTTON
See Mineral Wool.
SILT
SLAG WOOL
See Mineral Wool.
SLAKED
LIME
See Lime.
SLATE
A soft, laminated, argillaceous material, chiefly aluminous in composition,
and allied to the clays. Finely ground, it makes a good semi-hard
valve of a blue-gray shade. It has been also used in general rubber
compounding. Specific gravity 2.70.
SOAPSTONE
A silicate of magnesia, combined with more or less alumina and water.
It is really a massive form of talc. In color it is white, reddish,
or yellow, is soft and greasy to the touch, is easily cut, but is
hard to break. Its specific gravity is 2.26. It is used often in
the place of French talc, for keeping rubber surfaces from sticking
together during vulcanization, and also for burying dark colored
goods and holding them in shape while they are being cured. Used
as an adulterant for rubber, it makes an excellent semi-hard compound
for valves. It is also used as a basis compound in the manufacture
of insulated wire. See Talc.
STARCH
A vegetable substance allied closely to cellulose. It occurs in
regular lumps composed of granules which have a definite character,
according to the variety of the plant from which they were derived.
When dry its specific gravity is 1.53. Commercial starch contains
usually about 18 per cent, of water and, if kept in a damp place,
will absorb 33 per cent, of water. It was much used formerly on
solarized work. Torrefied starch is obtained by roasting the common
form, and is used in artificial leather compounds.
STONE
SUBLIMED
LEAD
A white lead known as sublimed lead is used very largely in rubber
manufacture. It is a fine white amorphous powder and imparts a decided
toughness to rubber compounds. It acts both as a filler and chemically.
Its peculiar velvety fineness makes it mix intimately with the rubber,
and gives a very fine finish, showing no shiny crystals on the surface.
The oxide of lead in the sublimed lead will also bind free sulphur
in the rubber. The amorphous state of the sublimed lead makes the
action of the lead oxide in this much more effective than the action
of litharge, and the result is a very smooth, lively, jet-black
rubber. Specific gravity 6.20.
SUGAR OF LEAD
See Lead Acetate.
TALC
OR FRENCH TALC
is a mineral allied to mica. It is composed entirely of silica and
magnesia, in the proportions of 67 to 73 of silica, 30 to 35 of
magnesia, and 2 to 6 of water. Specific gravity 2.70. Its colors
are silvery white, greenish white, and green. Talc slate is more
like steatite and is used for similar purposes. French talc is used
very largely in rubber factories in all lines of work for preventing
surfaces from sticking together, during either manipulation or vulcanization.
It is also used commonly for dusting molds to prevent the gum from
sticking to the metal and extensively to bury white goods and keep
them in shape during vulcanization. It is used sometimes in compounding,
but any great amount of it produces a stony effect. It makes, however,
an excellent semi-hard packing. It is used further in compounds
for soft polishing, with india rubber as a binding material.
TALITE
A white earthy material used in general rubber compounding. It is
allied to diatomaceous earth, presumably, TIN and has the same usage.
Its analysis shows: Moisture 5.59, silica 83.9, sesquioxide of iron
1.2, alumina 2.8, oxide of manganese trace, potash trace, combined
water and organic matter (by ignition) 6.47, loss and undetermined
0.04—total 100.
TIN OXIDE
The form most frequently used in the arts is the dioxide. This is
a white water-free powder, of the specific gravity of 6.7, insoluble
in acids and such solvents as naphtha, petroleum, etc. It is infusible,
except at a very high temperature, tasteless and inodorous. French
oxide of tin is a carefully prepared and purified form of the dioxide.
It is rarely used in rubber work, although Newton recommends it
for a basic ingredient in rubber type. The other oxides of tin are
at present merely of chemical interest.
TRIPOLI
See Infusorial Earth and Rotten Stone.
TYRE-LITH
A trade designation for colloidal barium sulphate. See Blanc Fixe.
Wheat Flour is used in making matrices for rubber stamp work, and
sometimes as a compounding material in india rubber, though this
is not to be advised, as the flour is apt to sour. A standard low
grade of wheat flour known as "red dog" is particularly
suited to the purpose of dusting the skim coating of wool linings,
because, owing to its peculiar texture, it is easily removable by
a wash of thin cement in the making-up process and does not impair
the adhesion to another rubber surface. A large and important use
for it has been in the dusting of black goods, such as rubber coats,
so as to keep them from sticking together, should they accidentally
touch during the dry heat of vulcanization. Wheat flour is preferable
to almost anything else, for the reason that it washes off after
vulcanization, without leaving any trace in color or stain. It is
used on the goods known as "dull finished."
WHITE
LEAD
This is a mixture of hydrated oxide and carbonate of lead and is
a heavy white powder. It is unstable in color, however, as sulphur
compounds, especially in the gaseous forms, easily attack it and
blacken it by reason of the formation of sulphide of lead. Its specific
gravity is 6.46. Sometimes it is adulterated with lead sulphate,
chalk, carbonate, or sulphate of baryta, or pipe clay. The simplest
test for the purity of white lead is to heat it in a thin glass
vessel with some very dilute pure nitric acid; if pure it will dissolve
completely. If chalk be present it also will pass into the solution,
in which it may be detected by the addition of caustic potash, throwing
it down as a white cloud. The best white lead is made by the old-fashioned
Dutch process, which consists of packing the metallic lead, cast
in the form of buckles to present a large surface for corrosion,
in covered earthen pots, in the bottom of which is placed acetic
acid. The pots, thus prepared, are stacked and buried in a mass
of spent tan bark to conserve the heat caused by the reaction of
the volatile acid on the metal. The original "triple compound,"
patented by Goodyear, consisted of india rubber, sulphur and white
lead.
WHITING
OR CHALK
Whiting Or Chalk, as it is often called, is carbonate of lime. It
is a white earthy material of the specific gravity of 2.7 to 2.9.
It is made from English chalk, which is crushed, floated, and run
through a filtering process, and dried in cakes made in varying
degrees of fineness by a system of dry grinding and bolting. Where
whiting is kiln-dried hastily, or under extreme heat, it is apt
to become calcined, which gives it a hard, gritty feeling. Air-dried
whiting is considered the best. Whiting is in reality a purified
form of carbonate of calcium, of a very soft or flocculent quality.
The finest grades are known as "gilders'" and "extra
gilders'." It is used more generally in rubber compounding
than any other material, except sulphur. Used moderately, it increases
the resiliency of rubber, but adds to the hardness. It does not,
however, produce the stony effect that many ingredients give. The
molds used in rubber-stamp making are composed of whiting, wheat
flour, glue, and carbolic acid. Whiting is liable to absorb considerable
quantities of water from the air. It is customary in many mills,
therefore, to keep it in large bins that not only are covered but
have steam pipes in the lower portions to drive out any moisture
from the material.
WITHERITE
See Carbonate of Barium.
ZINC
OXIDE
See under active ingredients
ZINC
SULPHATE OR WHITE VITRIOL
The crystals contain about 44 per cent, water of crystallization.
Specific gravity 2.03.
ZINC
SULPHIDE
See Colors.
LIST
OF COMMON ACTIVE INGREDIENTS USED IN COMPOSITIONS
|
Molded
insulation's are either cold molded or hot molded depending on which
active ingredients or binding agents and methods are chosen.
If it is a chemical reaction that takes place with a mixture (without
heat), this would be called a cold molded composition. It can still
have hard, stony, vitreous materials, fibers, etc. Added to the mixture,
but the binding agent would be one of two classes. It would be either
a pitch, or resin that is dissolved using chemicals, or a direct chemical
reaction such as lime, silica and water mixed with magnesia. An example
of other chemical mixtures would be oxide of magnesia mixed with chloride
of magnesia or zinc oxide with zinc chloride. Hot molded compositions
are normally molded using pressure and heat at the same time. Normally
the binding
materials
used for hot molded compositions, are those that are hard when cold
and soft when heated. Most any of the raw insulating materials can
be mixed with the binder as an inert ingredient. Often times the materials
are mixed together by use of a grinder and then heated to fuse the
binders while being placed into a hot mold and compressed. The composition
is then allowed to cool and harden under pressure.
MAGNESIUM OXIDE +
MAGNESIUM CHLORIDE -
aka:
magnesia
cement
When magnesium
chloride is mixed with hydrated magnesium
oxide (burnt magnesia), magnesium chloride forms a hard material long
called sorel cement. Important to know about different types of binders,
is that some are hydraulic and some are non-hydraulic. When magnesium
chloride is mixed with hydrated magnesium
oxide it becomes a hydraulic cement.
It hardens because of chemical
reactions caused by the hydration process
(when the water is added). The hardening process can even take place
underwater. The chemical reaction that results when the dry or dehydrated
cement powder is mixed with water, produces hydrates that are not
water-soluble. Non-hydraulic cements like plaster for example, must
be kept dry in order to retain its strength and binding qualities.
If testing, the approximate chemical formula would be: Mg4Cl2(OH)6(H2O)8,
corresponding to a weight ratio of 2.5-3.5 parts MgO (magnesium
oxide) to one part MgCl2 (magnesium chloride).
ZINC
OXIDE + ZINC CHLORIDE
- aka:
sorel
cement
Zinc
chloride reacts with zinc oxide to form a hard and transparent cement,
which was first investigated in the 1855 by the well known frenchman
Stanislas Sorel (the inventor of "sorel cement"). This combination
of zinc oxide and zinc chloride is simply a variant
of the same cement, (only using zinc oxide with zinc chloride instead
of the magnesium compounds). When used in a composition,
it is combined with filler materials such as sand, crushed stone,
talc, etc... This compound has been know to be used in the past for
grindstones, tiles, artificial stone (cast stone), cast floors, artificial
ivory (billiard-balls). It can withstand 10,000 - 12,000 psi of compressive
force whereas standard portland cement can only withstand 2,000 psi.
Its
chief drawback is its poor water resistance, making it unsuitable
for many outdoor uses.
EARLY KNOWN & UNKNOWN COMPOSITION MATERIALS FOUND IN PATENTS
|
234,417
- COVERING FOR STEAM-PIPES
Filed Sep 17, 1880 - Jane Meiiriam, of Milwaukee Wisconsin
Asbestos paper
249,239 - ASBESTUS
ROOF PAINT OR COMPOSITION
Filed September 12th 1881 - Fredrick M. Hibbard of Goshen Indiana
- Assigned William B. Lehman same place
Consists of asbestus, fifteen
pounds; litharge, five pounds; gypsum, ten pounds; coal-tar, forty
gallons
(also see 329,740)
251,473
- INSULATING COMPOSITION OR COMPOUND FOR COATING ELECTRIC AND OTHER
WIRES OR CONDUCTORS
Filed Oct 21st 1881 - Frederick W. SchboeDer of New York, New York
Consists of glue, mastic, dextrine, asbestus,
chrome-alum, chloride of iron, and glycerine
259,271
- PREPARATION OF MATERIALS FOR USE IN ELECTRIC INSULATION
Filed Mar 14, 1882 - John Ambrose Fleming of University College, Nottingham
England
Consists of ground up wood or vegetable fibrous material like flour-bran,
straw, cotton, jute, hemp, paper mache - impregnated it with melted
paraffine-wax or mixtures of paraffin's, wax and resin which may be
fine sifted sawdust, or ordinary sawdust of finer division, or any
of the other materials above mentioned, in a finely-divided state.
The whole is stirred during the process of saturation, and becomes
attack, pasty mass, which is then placed in molds of the required
shape. In order to obtain a better imitation of ebonite,
or to impart to the material any required shade of color, I may add
to the material in the course of preparation a small quantity of lamp-black,
vegetable black, or other vegetable coloring-matter By the term "
paraffine-wax " as used in this my specification I mean any of
the substances known by the ordinary names of
"ozocerite"
or "solidified petroleum" or "mineral wax,"
or, more strictly, a substance, whose main constituents are hydrocarbons,
the composition of which is denoted by the formula CnH2n+a; and by
the term "resin" as used in this my specification I mean
any of the substances known as "resin" or "rosin"
various species of pines and firs - The materials prepared according
to my invention I propose to designate "insulite."
See the entry on this page Insulite where
he later also used asphalt in
the place of other materials
268,034
- MANUFACTURE OF INSULATING COMPOUNDS
Filed August 15th 1882 - Murdoch Mackay - London, England
Consists of mineral wax as paraffine-wax or ozocerite-wax, vegetable
tar (woodtar), shellac, and asbestus.
(also see 310,899)
288,935
- FIRE-PROOF COMPOUND AND SHEET
Filed Jun 28, 1883 - Nathaniel C. Fowler of Boston Massachusetts -
INDESTRUCTIBLE SAFE AND FIRE PROOF COMPANY
Consists of calcined plaster-of-paris, finely fiberilized asbestus,
lamp-black, and pumice-stone
300,464
- COMPOUND MATERIAL FOR THE MANUFACTURE OF SHEETS, BOARDS, BLOCKS,
ARTIFICIAL WOOD
Filed Mar 15, 1884 - Levi Haas of Chester Pennsylvania
A compound material composed of vegetable fiber, leather or shoddy
waste, crude asbestus, litharge,
and sulphur, pitch and whiting blended with thinned asphaltum,
305,123
- COMPOUND FOR AXLE-BEARINGS
Filed Sep 12, 1883 - Isaac P. Wendell of Philadelphia Pennsylvania
Consists of a compound composed of silicate of soda, asbestus,
and sulphur for the principal ingredients, to which may be added,
if desired, a quantity of black-lead and paraffine or other lubricating
oil
310,205
Fabric for covering heated surfaces. — H. W. Johns.
Consists of ropes or rolls of fibrous materials, woven with sheets
of paper, sheathing
Asbestos Paper
310,334
Asbestos paper.—S. Tingley.
A sheet of asbestos
paper
is covered on one or both sides with thin paper, coated with a salt,
which will form a glaze when heated to high temperatures.
310,594
- PROCESS OF MANUFACTURING ASPHALTIC POWDER
Filed September 22 1884 - Hermann Kettmann - German Empire
Asphaltic concretes are made by mixing asphalum
or bitumen with pulverized material, while the latter are
suspended in water.
310,899 - PLASTIC COMPOUND SUITABLE FOR MOLDING INTO VARIOUS USEFUL
ARTICLES
Filed June 11th 1884 - Murdoch Mackay - London, England
Consists of lac, gum sandarac or gumkauri, carbon or asphaltum, rosin,
ivory, black, and asbestos.
(Also see 268,034)
311,287
- PLASTIC-CEMENT MIXTURE FOR NON-CONDUCTING COVERINGS FOR BOILERS
Filed July 10th 1883 - D. Austin Brown of Boston Massachusetts
Plastic cement mixture consists of infusorial earthy lime and asbestos.
311,401
- PAINT
Filed March 27, 1884 - William H. Wilber
A priming paint composed of liquid asphaltum,
rosin, linseed oil, turpentine or naphtha and white lead.
313,823
- COMPOSITION FOR CURING PAVING BLOCKS OR BRICKS
Filed November 28, 1884 - Thomas A. Huguenin of Charleston South Carolina
Composition for curing paving blocks or bricks.—T. A. Huguenin.
Consists of coal tar, bitumen,
pine gum and alum.
314,182
- COMPOUND FOR REPAIRING STOVES
Filed June 12, 1884 - Ephbaim Ivett and Alexander Geoege of Clay Bank,
Ohio
Consists of a mixture of burned and ground fire clay, unburned and
ground fire clay, sifted wood ashes, sand, salt, black lead, asphaltum
and water.
315,471
- ROOF-PAINT COMPOSITION
Filed Feb 13, 1884 - Daniel Beobst, of Portland, Michigan
Mixture of coal tar, asphalt,
salt, alum, gypsum, Roman cement, sulphur, pine resin, slacked lime,
tallow, and copperas.
315,487
- COMPOSITION MASTIC FOR COVERING ROOFS, TELEGRAPH-WIRES, AND
THE LIKE
Filed Apr 15, 1884 - Andrew Deeeom of Paterson New Jersey
Consists of crude Trinidad asphaltum,
beeswax and oil.
315,610
- CHEMICAL FIRE-EXTINGUISHER
Filed Oct 24, 1884 - William Gee & Ellwod Hendrick of New York,
New York
A compound consisting essentially of asphaltum
and caoutchouc oil.
319,079
- COMPOSITION OF MATTER FOR THE PRESERVATION OF PAPER OR VEGETABLE
TUBING USED FOR THE INSULATION OF TELEGRAPH-WIRES
Filed
- March 9, 1885 - James W. Ellis (ASSIGNOR OF TWO-THIRDS TO JOSIAH
W. PAEKEE) both of Brooklyn, New York
Consists of asphaltum, resin,
petroleum, vulcanized rubber and
sulphur.
319,084
- PREPARATION AND PRODUCTION OF INSULATING MATERIALS
Filed Apr 8, 1885 - , John Ambeose FilmIng, London England
Consists of vegetable fibre impregnated with a mixture of melted bitumen,
the silicates of magnesia, lime, iron and alumina, and amber or other
resin.
319,125
- PROCESS OF WORKING AND USING ASPHALTUM
Filed Oct. 2, 1884 - Judson Rice and Andrew Steiger, and Isaac Lane
Thurber of San Jose & Santa Cruz California
Pure native asphaltum is softened
with hot water or steam and pressed under heated rolls.
320,921
- COMPOUND FOR INSULATING ELECTRIC WIRES
Filed February 27 1885 - Egbert S. Ferguson of Waukegan Illinois -
William Schumacher and William Tubman both of Chicago
Compound consists of pine pitch, rubber,
and asbestos, mixed with beeswax,
tallow or linseed oil
322,280
- FIREPROOFING COMPOUND
Filed March 23, 1885 - John T. Greenwood, Jr. of Beloit Wisconsin
Composition consisting of coal-tar, silicate of soda, asbestus,
plaster-of-paris, salt, red lead, litharge, asphaltum, and Venetian
red or other pigment or coloring-matter
322,802
- PROCESS OF MAKING THE COMPOUND TERMED " KERITE."
Filed Jun 29, 1885 - Austin G. Day, of New York, New York
The process consists in first mixing together cotton seed oil
and coal tar or bitumen, and afterward
adding linseed oil and sulphide of antimony or other sulphide, with
or without the addition of sulphur. (Also see this
entry on this page for Kerite
329,740
- PAINT FOR ROOFING
Filed April 2nd 1885 - Fredrick M. Hibbard of Goshen Indiana
Paint consists of coal tar, beeswax, resin, litharge, gypsum and asbestos
(also see 249,239)
330,171
- TREATING ASBESTUS TO FORM CRUCIBLES
Filed October 7th 1885 - Mark S. Thompson of New York, New York,
Asbestos is mixed with water to
form a plastic mass, which is placed in molds, and then exposed to
a high temperature.
330.196
- ASPHALTIC MASTIC
Filed Dec 28, 1883 - Amzi L. Babber - BARBER ASPHALT PAVING COMPANY
of Washington, D.C.
Consists of refined Trinidad asphaltum,
residium of petroleum, or heavy petroleum oil and pulverized limestone
Also the same name as a trade name listed here. Also
see Mastic
330.197
- ASPHALTIC CEMENT FOR PAVING., ROOFING, ETC.
Filed Jul 21, 1884 - Amzi L. Babber - BARBER ASPHALT PAVING COMPANY
of Washington, D.C.
Trinidad or similar hard asphalt,
combined with Trinidad, Mexican,
Vene. zuelan or other naturally soft or liquid asphalt,
sand and pulverized limestone
361,885
- MANUFACTURE OF TRUNKS FROM CHEMICALLY-TREATED
FIBER
Filed November 2, 1886 - Henry W. Morrow of Wilmington, Delaware
This patent is for the trunk invention of the fiber named and called
Celluvert. See the entry on this
page for celluvert patent below - read more about my celluvert research
here.
332,629
- TREATMENT OF PAPER AND OTHER FIBROUS MATERIAL
FOR JOURNAL BEARINGS, BELTING - Celluvert
Filed May, 25,1885 - Henry W. Morrow of Wilmington, Delaware
The Process of treating paper and other vegetable
fibrous substances uniting them in layers (with the chemicals below)
and pressing the layers of treated sheets to cement them together.
The ability to manufacture articles made of sheets of paper or similar
material treated with no nitric acid or one of its salts, in connection
with another solvent or other solvents of cellulose, and united in
layers. The sheets or slabs thus produced are useful for
various purposes—such, for instance, as journal-bearings, belting,
trunks, washers,, cop-tubes, skaterollers, etc.. They may also be
made into knife-handles, and various forms and shapes of non-conductors
of electricity. The sheets or slabs may be made either hard and hornlike
or pliable and leather-like, according to the use to which the "celluvert"
is to be put. The sheets or slabs may be softened or made pliable
by immersion in a bath of glycerine or saccharine matter, or both,
the said bath consisting of about two-thirds water and one-third
glycerine or saccharine matter, or glycerine and saccharine matter
combined. If desired, a compound sheet may be formed by cementing
a sheet of woven material between sheets of paper by the process described
above. Starch, gum, mucilage, dextrine, or any form of cellulose may
be advantageously added to the paper or fabric, either during the
manufacture of the same or before treatment in the manner above described,
or these substances may be dissolved in the nitric acid or its equivalent
transforming fluid before described previous to the immersion of the
paper or similar material therein. If desired, any mineral or earthy
substance starch, gum, dextrine, or any form of celhrlose may be sifted
in or between, the layers of paper or similar material as they are
being wound onto the roll. I am aware that nitric acid has been used
in the treatment of paper pulp, and also in the treatment of single
sheets of paper or fabric; but I claim as my invention the process
herein described of treating
paper and other vegetable fibrous substances, said
process consisting in subjecting them in sheet
form to the action of nitric acid or a salt
thereof and uniting two or more layers so
treated.
See other celluvert or Henry W. Morrow patents: 346,823
(Apr 8, 1886), 378,016
(Oct 24, 1887)
409,904 - PAINT COMPOUND
Filed April 25, 1889 - Nineveh R. Bonner and Ira L. Burlingame Pana
Illinois
Composition consisting of mortar - cement, yellow ocher, Venetian
red, rosin, sulphur, alum, burnt umber, lamp-black, asbestus,
asphaltum, liquid japan, and coal-tar
505,916
- INSULATING COMPOUND AND METHOD OF MANUFACTURING
Filed December 2, 1892 - Joseph Hoffman of Schenectady New York -
Assigned GENERAL ELECTRIC CO.
One hundred pounds of asbestus
fiber and fifty pounds of powdered asbestus,
six pounds of bees-wax and twelve pounds of asphaltum dissolved in
two and one half gallons of benzine, thirty pounds of shellac and
one half pounds of albumen and about ten pounds of drop-black
526,721
- COMPOSITION OF MATTER FOR ELECTRIC CONDUCTORS.
Filed May 16, 1894 - Duncan Macfaklan of Philadelphia Pennsylvania
Several combinations:
a) mineral wool, ten percent.; Black lead twenty percent.; Chloride
of aluminum, ten percent.; Kaolin, forty percent.; Water,twenty percent
b) Asbestos or mineral wool, twenty-five
percent.; Graphite, twenty-five percent.; Silver, twenty percent.;Junior
sugar,five percent.; Water, twenty-five percent.
c) Asbestos, thirty percent.;
Graphite, twenty percent.; (German silver, twenty percent.; Gum or
sugar, five percent.; Water, twenty-five percent.
d) Asbestos or mineral wool, twenty-five
percent; silicate of soda, twenty percent.; Water, twenty-five percent.;
Graphite, thirty percent.
e) Asbestos or mineral wool, forty
percent.; Water, twenty-five percent.; Graphite, twenty 60 percent;
rubber and gutta percha. Fifteen
per cent.
f) Asbestos, twenty-five percent.;
Whiter, tweiity-five percent.; Graphite, thirty percent.; cement..twenty
percent
528,744 - INSULATING COMPOUND
Filed March 26, 1894 - Oscae Stiles of Omaha Nebraska
Combination of six parts of alcohol, three parts of shellac, three
parts of asbestos, and one part
each of mica and alum
537,321
- INSULATING COMPOUND
Filed July 30, 1894 - Alexander C. Thompson of St. Louis Missouri
Consists of alcohol, one gallon; gum shellac, five pounds; pulverized
asbestos, six pounds; pulverized
French chalk, four pounds; balsam tolu gum, one pound; ground mica,
four pounds.
551,230 - COMPOSITION OF MATTER FOR INSULATING PURPOSES
Filed October 31, 1889 - Rufus N. Pratt of Hartford Connecticut
Composition consisting
of dense hard rubber,
laminated mica, and fibrous asbestos
combined as specified
623,982
- GASKET FOR STEAM-BOILERS AND COUPLING THEREFOR
Filed Jun 3, 1898 - Arthur W. Chesterton, of Boston, Massachusetts
A mixture consisting of rubber
and asbestos Also see Rubberbestos
718,378
- INSULATING-LINING AND PROCESS OF MAKING SAME
ASSIGNOR TO THE GENERAL ELECTRIC COMPANY,
Filed Oct 6, 1898 - George B. Painter, Schenectady New York
This
may be of any suitable fibrous or insulating material. I have used
both hard rubber and insulating
fiber made by any of the processes now well known in
the art with good effect.
750,873
- INSULATING SLEEVE AND METHOD OF MAKING SAME.
Filed Jun 6, 1902 - Norman Marshall, of Newton Massachusetts
Elastoid Fibre Company - Elastoid Fibre is
largely composed of asbestos
fiber and a special binder and in process of manufacture is treated
at a temperature of about 650 degrees Fahrenheit. "H. T. Elastoid."
Laboratories' tests show that this lining is reasonably uniform
in thickness and diameter; is chemically neutral; has good dielectric
strength; is absorptive of moisture to about the same degree as
ordinary fiber linings; and is practically non-combustible. Its
properties are but little changed by exposure to temperatures below
300 degrees Fahrenheit. This lining is judged to be suitable for
use in mogul sockets and receptacles, including those provided with
shades, reflectors, fixtures or other enclosures above them and
used with gas-filled incandescent lamps of above 100-watt capacity.
|