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KARL O. CHRISTE

 

Education:

            B.S., Technical University of Stuttgart, Germany, 1957

            M.S., Technical University of Stuttgart, Germany, 1960

            Ph. D., Technical University of Stuttgart, Germany, 1961

 

Professional Employment:

            2005-Present   Consultant, Science and Technology Applications, LLC

1994-Present   Research Professor, University of Southern California, and Adjunct Professor, University of Idaho, Moscow, ID

1994-2005      Senior Staff Advisor, Air Force Research Laboratory, Edwards AFB, CA

            1967-1994       Manager, Exploratory Chemistry, Rocketdyne, Canoga Park, CA

 

Professional Experience:

          Dr. Christe has 49 years of experience in the synthesis of novel high energy oxidizers and rocket propellants and has managed and scientifically directed many government funded research contracts. He has achieved the first syntheses of many spectacular compounds, such       as ClF3O, ClF3O2, halogen perchlorates, OIF4OF, OsF4O2, and ions, such as NF4+, ClF6+, ClF6-, ClO2F2-, ClO2F2+, ClF2O+, ClF4O-, NF3+, NF2O+, and NH2F2+.  He has developed solid propellant fluorine gas generators for chemical laser weapon systems and has discovered      the first purely chemical synthesis of elemental fluorine.  He has developed a synthesis for anhydrous tetramethylammonium fluoride and has pioneered the use of this compound as a source of “naked” fluoride ions, which has led to a renaissance of high coordination number chemistry. Among the novel compounds, which he prepared in this manner, are the XeF5- and IF52- anions, which are the first known examples of pentagonal planar species.

            He has a very broad background in general chemistry. For example , he has prepared the first stable oxonium, OH3+, and sulfonium, SH3+, salts, has discovered a new process for metal joining using hydrazine as a gaseous flux, has developed new methods for the introduction of fluorine into aromatic rings, and has pioneered graphite based ion exchange resins for the use with powerful oxidizers in anhydrous HF solutions. In addition, he has made major contributions to the chemistry of fluorocarbons, inorganic high polymers, chemical laser technology, and methane oxychlorination. More recently, he and his coworkers have achieved major breakthroughs in polynitrogen chemistry. They have discovered with the pentanitrogen cation, N5+ the first stable new polynitrogen species in more than 100 years. Subsequently, they demonstrated the existence of the cyclo-N5- anion, the inorganic analogue of the cyclopentadienide anion. They have also prepared and characterized the N3NOF+ and N7O+ cations. In addition, they have synthesized and characterized a large number of novel polyazido compounds and have successfully combined species such as N5+ and P(N3)6- or B(N3)4- into a single compound. Presently, they are working on high-oxygen and high-nitrogen carriers as green and higher performing replacements for the toxic and carcinogenic hydrazine monopropellants and the halogen containing and toxic solid propellant ingredient ammonium perchlorate.

 

Professional Societies and Awards:

            Dr. Christe is a member of the American Chemical Society and the German Chemical Society and has received numerous awards, including the Alfred Stock Preis of the German Chemical Society (2006), the ACS Award in Inorganic Chemistry (2003), the Prix Moissan (2000), the ACS Award for Creative Work in Fluorine Chemistry (1986), and the NASA’s Apollo Achievement Award (1969). He has been elected to the European Academy of Sciences (Liege) in 2009 and the European Academy of Sciences and Arts (Salzburg) in 2010.

 

Publications and Patents:

            Dr. Christe has 345 publications in refereed journals and 63 patents to his credit. In addition, he has worldwide lectured on the results of his research.

 

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                Publications of Karl Christe

  1. "Silico Phosphoric Acid and Its Derivatives," Z. Anorg. Allgem. Chem., 325, 26 (1963) with J. Goubeau, W. Teske and W. Wilborn.
  2. "Antimony Pentafluoride as a Fluorinating Agent," J. Chem. Soc., 5549, (1963) with A.E. Pavlath.
  3. "Note on Octafluoroanthraquinone," Chem. Ber., 96, 2537 (1963) with A. E. Pavlath.
  4. "Preparation of Hexafluorobenzene from 1,2 Difluoro-1,2, Dichloroethane," Chem. Ber., 97, 2092 (1964) with A.E. Pavlath.
  5. "Silicon Tetrafluoride, A New Fluorinating Agent," J. Org. Chem., 29, 3007 (1964) with A.E. Pavlath.
  6. "Silicontetrafluoride as a Fluorinating Agent, Part II," J. Chem. Soc., 827, (1965) with A. E. Pavlath.
  7. "Ionic Complexes Containing the Difluorochlorinium Cation, ClF2+," Z. Anorg. Allgem.  Chem., 335, 210 (1965) with A.E. Pavlath.
  8. "The Chemistry of Carbonyl Chloride Fluoride.  I.  The Ring Opening of Cyclic Ethers with Carbonyl Fluoride,"  J. Org. Chem., 30, 1639 (1965)  with A.E. Pavlath.
  9. "The Chemistry of Carbonyl Chloride Fluoride. II.  The Reaction Between Vicinal Diols and Carbonyl Chloride Fluoride,"  J. Org. Chem., 30, 1644 (1965) with A.E. Pavlath.
  10. "The Difluorochlorate (I) Anion, ClF2-," Inorg. Chem., 4, 905 (1965) with J.P. Guertin.
  11. "Aromatic Fluorine Compounds.  II. A Novel method for Introducing Fluorine into an Aromatic Ring,"  J. Org. Chem., 30, 3170 (1965).
  12. "Difluorochlorates (I) of Cesium, Rubidium, and Potassium," Inorg. Chem., 4, 1785 (1965) with J.P. Guertin.
  13. "Aromatic Fluorine Compounds.  III. The Introduction of a Fluorine Atom into Substituted Aromatic Rings,"  J. Org. Chem., 30, 4104 (1965) with  A. E. Pavlath.
  14. "Aromatic Fluorine Compounds.  IV. The Introduction of More than One Fluorine Atom into the Same Ring by a Novel Method,"   J. Org. Chem., 31, 559 (1966) with A.E. Pavlath.
  15. "Structure of the Tetrafluorochlorate (III) Anion, ClF4-," Inorg. Chem., 5, 473 (1966) with J.P. Guertin.
  16. "The Tetrafluoronitronium (V) Cation, NF4+,"  Inorg. Nucl. Chem. Letters, 2, 83 (1966) with J.P. Guertin and A.E. Pavlath.
  17. "Complex Fluoro Cations.  II.  Tetrafluoronitrogen (V) Cation NF4+Synthesis and Properties of NF4+AsF6-," Inorg. Chem., 5, 1921  (1966) with J.P. Guertin and A.E. Pavlath.            
  18. "The Difluorochlorinium (III) Cation, ClF2+.  Vibrational Spectra and Force Constants," Inorg. Chem., 6, 313 (1967) with W. Sawodny.
  19. "Complex Fluoro Cations.   III. Tetrafluoronitrogen (V) Cations, NF4+.  Vibrational and 19F NMR Spectra of NF4+AsF6-," Inorg. Chem., 6, 533 (1967) with J.P. Guertin, A. E. Pavlath and W. Sawodny.
  20. "The Difluorochlorate (I) Anion, ClF2-.  Vibrational Spectra and Force Constants," Inorg. Chem., 6, 1159 (1967) with W. Sawodny and J.P. Guertin.
  21. "The Interaction of Phosgene with Lewis Acids," Inorg. Chem., 6, 1706 (1967).
  22. "The Hexafluoroiodine (VII)  Cation, IF6+,"  Inorg. Chem., 6,  1783 (1967) with W. Sawodny.
  23. "The Tetrafluorochlorate (III) Anion, ClF4-.  Raman Spectrum and Force Constants," Z. anorg. allgem. Chem., 357, 125 (1968) with W. Sawodny.
  24. "The Hexafluoroiodine (V) Anion, IF6-.  Vibrational Spectra," Inorg. Chem., 7, 626 (1968) with J.P. Guertin and W. Sawodny.
  25. "On the Vibrational Assignment of IF6+," Inorg. Chem., 7, 1685 (1968) with W. Sawodny.
  26. "Vibrational Spectra of Hexafluoroiodate Salts," Inorg. Chem., 7, 2174 (1968) with S.P. Beaton, D.W.A. Sharp, A.J. Perkins, I. Sheft, and H.H. Hyman.
  27. "The FCl2+ Cation," Inorg. Chem., 8, 212 (1969) with W. Sawodny.
  28. "On the Complex Formation of ClF5 with Lewis Acids and Bases," Inorg. Chem., 8, 391 (1969) with D. Pilipovich.
  29. "The Difluoronitronium Cation, NF2O+," Inorg. Chem., 8, 1253 (1969) with W. Maya.
  30. "Preparation of NF2Cl," Inorg. Chem., 8, 1539 (1969).
  31. "Comment on the Electrical Conductivity of BF3 in Mixed Halogen Fluorides," J. Phys. Chem., 73, 2791 (1969).
  32. "The Chloryl Cation ClO2+," Inorg. Chem., 8, 2489 (1969) with C.J. Schack, D. Pilipovich, and W. Sawodny.
  33. "Radical Cations in the Chlorine Fluoride-Antimony Pentafluoride Systems," J. Am. Chem. Soc., 91, 7777 (1969) with J. Muirhead.
  34. "Some Structural Aspects of IF6+AsF6- from NMR Data," J. Chem. Phys., 52, 1969 (1970) with J.F. Hon.
  35. "Electrical Conductivity of BrF3," J. Phys. Chem., 74, 2039 (1970).
  36. "Raman Spectrum and Force Constants of SF4," J. Chem. Phys., 52, 6320 (1970).
  37. "The Tetrafluorobromate (III) Anion, BrF4-," Inorg. Chem., 9, 1852 (1970) with C.J. Schack.
  38. "On the Structure of Complexes between BrF3 and Lewis Acids," Inorg. Chem., 9, 2296 (1970) with C.J. Schack.
  39. "Infrared Spectrum of ClOSO2F," Spectrochim. Acta, 26A, 2367 (1970) with C.J. Schack and E.C. Curtis.
  40. "On the Infrared Spectrum and Force Constants of the Tetrafluorochlorate (III) Anion ClF4-," Z. Anorg. Allgem. Chem., 374, 306 (1970) with W. Sawodny.           
  41. "The Raman Spectrum of IF6+AsF6in HF Solution,"  Inorg. Chem., 9, 2801 (1970).
  42. "Matrix-Isolation Study of the Low Pressure Pyrolysis and Ultraviolet Photolysis of Dimethyl Peroxides and of CF3OCl," J. Am. Chem. Soc., 93, 51 (1971) with D. Pilipovich.
  43. "Matrix-Isolation Study of ClF5," Spectrochim. Acta, 27A, 631 (1971).
  44. "The Vibrational Spectra of Dimethyl Peroxides," Spectrochim. Acta., 27A, 463 (1971).
  45. "Bromine Perchlorate," Inorg. Chem., 10, 1078 (1971) with C.J. Schack, D. Pilipovich, and R.D. Wilson.
  46. "The Vibrational Spectrum of the N2F+ Cation," J. Mol. Struct., 8, 245 (1971) with R.D. Wilson and W. Sawodny.
  47. "Matrix-Isolation Study of BrF3," Spectrochim. Acta, 27A, 931 (1971) with E.C. Curtis and D. Pilipovich.
  48. "Halogen Perchlorates, Vibrational Spectra," Inorg. Chem., 10, 1589 (1971) with C.J. Schack and E.C. Curtis.
  49. "Laser Raman Spectrum of the NF4+ Cation," Inorg. Chem., 10, 2813 (1971) with D. Pilipovich.
  50. "Vibrational Spectra and Force Constants of the Square Pyramidal Anions, SF5-, SeF5- and TeF5-" Inorg. Chem., 11, 1679 (1972) with E.C. Curtis, C.J. Schack and D. Pilipovich.
  51. "The Difluorochlorate (V) Anion, ClO2F2-," Inorg. Chem., 11, 35 (1972) with E.C. Curtis.
  52. "The Crystal Structure of [BrF4]+[Sb2F11]-,"  Inorg. Chem., 11, 608 (1972) with M.D. Lind.
  53. "On  Alkali Metal Fluoride-IF5 Adducts,"  Inorg. Chem., 11, 1215 (1972).
  54. "Selenium Pentafluoride Chloride, SeF5Cl.  Vibrational Spectrum," Inorg. Chem., 11, 583 (1972) with C.J. Schack and E.C. Curtis.
  55. "On the Reactions of Chlorine Fluorides with Hydroxyl Compounds," Inorg. Chem., 11, 1220 (1972).
  56. "Iodine Trisperchlorate and Cesium Tetraperchlorato Iodate (III)," Inorg. Chem., 11, 1682 (1972) with  C.J. Schack.
  57. "The Difluoroperchloryl Cation, ClO2F2+," Inorg. Nucl. Chem. Letters, 8, 453 (1972).
  58. "Chlorine Trifluoride Dioxide, ClF3O2,"  Inorg. Nucl. Chem. Letters, 8, 457 (1972).
  59. "The Hexafluorochlorine (VII) Cation, ClF6+," Inorg. Nucl. Chem. Letters, 8, 741 (1972).
  60. "Chlorine Trifluoride Oxide. I. Preparation and Properties,"  Inorg. Chem., 11, 2189 (1972) with D. Pilipovich,  C.B. Lindahl, C.J. Schack and R.D. Wilson.
  61. "Chlorine Trifluoride Oxide. III. Vibrational Spectrum, Force Constants and Thermodynamic Properties,"  Inorg. Chem., 11, 2196 (1972) with E.C. Curtis.
  62. "Chlorine Trifluoride Oxide. IV. Reaction Chemistry," Inorg. Chem., 11, 2201 (1972) with C.J. Schack, C.B. Lindahl and D. Pilipovich.
  63. "Chlorine Trifluoride Oxide.  V.  Complex Formation with Lewis Acids and Bases, Inorg. Chem., 11, 2205 (1972) with C.J. Schack and D. Pilipovich.
  64. "Chlorine Trifluoride Oxide. VI. The Tetrafluorooxychlorate (V) Anion, ClF4O-. Vibrational Spectra and Force Constants," Inorg. Chem., 11, 2209 (1972) with E.C. Curtis.
  65. "Chlorine Trifluoride Oxide.  VII. The ClF2O+ Cation.  Vibrational Spectrum and Force Constants," Inorg. Chem., 11, 2212 (1972) with E.C. Curtis and C.J. Schack.
  66. "Dimethyl Sulfate, Vibrational Spectra," Spectrochim. Acta28A, 1889 (1972) with E.C. Curtis.
  67. "New Technique for Metal Bonding and Cleaning," Welding Journal, 37, 569-S (1972) with R.D. Wilson and D. Pilipovich.
  68. "A 19F NMR Study of Chlorine Fluoride Cations," Inorg. Chem., 12, 84 (1973) with J.F. Hon and D. Pilipovich.
  69. "Vibrational Spectrum and Force Constants of the SF5O- Anion," Inorg. Chem., 12, 620 (1973) with C.J. Schack, E.C. Curtis, D. Pilipovich and W. Sawodny.
  70. "The ClF6+ Cation, Synthesis and Vibrational Spectrum," Inorg. Chem., 12, 1580 (1973).
  71. "Chlorine Trifluoride Dioxide, ClF3O2.  Synthesis and Properties,"Inorg. Chem., 12, 1356 (1973) with R.D. Wilson.
  72. "The Difluoroperchloryl Cation, ClO2F2+," Inorg. Chem., 12, 1358 (1973) with R.D. Wilson and E.C. Curtis.
  73. "On the Reaction of Cl2F+AsF6- with Xenon," Inorg. Nucl. Chem. Letters, 9, 845 (1973) with R.D. Wilson.
  74. "Vibrational Assignment of SF4," J. Mol. Spectrosc., 21, 158 (1974) with W. Sawodny and P. Pulay.
  75. "Halogenfluorides," International Union of Pure and Applied Chemistry XXIVth International  Congress of Pure and Applied Chem., 4, 115 (1974).
  76. "On a New Synthesis of NF4+ Salts and its Mechanistic Interpretation Involving a New and Exceptionally Powerful Oxidizing Species," Inorg. Chem., 12, 2478 (1973) with R.D. Wilson and A. Axworthy.
  77. "ClF3O2. Vibrational Spectrum, Force Constants, and Thermodynamic Properties," Inorg. Chem., 12, 2245 (1973) with E.C. Curtis.
  78. "Vibrational Spectra of Trifluoroacetates," Spectrochim. Acta, Part A, 29, 2017 (1973) with D. Naumann.
  79. "On Halogen Pentafluoride-Lewis Acid Adducts," Inorg. Chem., 12, 2879 (1973) with W. Sawodny.
  80. "Cesium Bis(perchlorato)bromate (I), Cs+[Br(OClO3)2]-," Inorg. Chem., 13, 1452 (1974) with C.J. Schack.
  81. "Reactions of the (CF3)2NO Radical with Strong Oxidizers," J. Fluor. Chem., 4, 423 (1974) with C.J. Schack and R.D. Wilson.
  82. "Trifluoromethyl Perchlorate, Preparation and Properties," Inorg. Nucl. Chem. Letters, 10, 449 (1974) with C.J. Schack.
  83. "Trifluoromethyl Perchlorate, Infrared and Raman Spectra," Inorg. Chem., 13, 2374 (1974) with C.J. Schack.
  84. "Reactions of Ozone with Covalent Hypohalites," Inorg. Chem., 13, 2378 (1974) with C.J. Schack.
  85. "Halogen Nitrates,"  Inorg. Chem., 13, 2811 (1974) with C.J. Schack and R.D. Wilson.
  86. "Halogen Perchlorates.  Reactions with Fluorocarbon Halides," Inorg. Chem., 14, 145 (1975) with C.J. Schack and D. Pilipovich.
  87. "ESR Study of O2+ Salts.  Influence of Crystal Field Effects and Relaxation," Inorg. Chem., 14, 152 (1975) with I.B. Goldberg and R.D. Wilson.
  88. "An Improved Synthesis of FClO2," Inorg. Nucl. Chem. Lett., 11, 161 (1975) with R.D. Wilson and C.J. Schack.
  89. "The NF3+ Radical Cation.  ESR Studies of Radiation Effects in NF4+ Salts," Inorg. Chem., 14, 1103 (1975) with S.P. Mishra, M.C.R. Symons, R.D. Wilson and R.I. Wagner.
  90. "The BrF6+ Cation.  Infrared Spectrum and Force Field," Inorg. Chem., 14, 694 (1975) with R.D. Wilson.
  91. "Vibrational Spectrum and Force Constants of the XeF5+ Cation," J. Inorg. Nucl. Chem., Supplement, 159 (1976) with E.C. Curtis and R.D. Wilson.
  92. "The CF3O- Anion.  Vibrational Spectrum of an Unusual CF3 Compound," Spectrochim. Acta, Part A, 31, 1035 (1975) with E.C. Curtis and C.J. Schack.
  93. "On the Existence of Several New ONF Compounds," Z. Anorg. Allg. Chem., 413, 177 (1975).
  94. "Novel Onium Salts.  Synthesis and Characterization of OH3+SbF6- and  OH3+AsF6-,"  Inorg. Chem., 14, 2224 (1975) with C.J. Schack and R.D. Wilson.
  95. "Novel Onium Salts.  Synthesis and Characterization of SH3+SbF6-," Inorg.Chem., 14, 2230 (1975).
  96. "Novel Onium Salts.  Synthesis and Characterization of the NH2F2+ Cation," Inorg. Chem., 14, 2821 (1975).
  97. "Chlorine Oxyfluorides," Advanc. Inorg. Chem. Radiochem., 18, 319-398, (1976) with C.J. Schack.
  98. "Titanium Perchlorate and Chromyl Perchlorate,"  J. Inorg. Nucl. Chem., Supplement, 207 (1976) with C .J. Schack and D. Pilipovich.
  99. "The Crystal Structure of (BrF2+)2GeF62-,"  J.C.S. Dalton, 175 (1976) with A.J. Edwards.
  100. "On the PtF6-XeOF4 Reaction System,"  J. Fluor. Chem., 7, 356 (1976) with R. D. Wilson.
  101. "The trans-H2PF4- Anion," Inorg. Chem., 15, 843 (1976) with C. J. Schack and E. C. Curtis.
  102. "Some Observations on the Reaction Chemistry of Dioxygenyl Salts and on the Blue and Purple Compounds Believed to be ClF3O2," J. Fluor. Chem., 7, 543 (1976) with R. D. Wilson and I. B. Goldberg.
  103. "Low-Temperature UV-Photolysis and its Application to the Synthesis of Novel and Known NF4+ Salts," Inorg. Chem., 15, 1275 (1976) with C. J. Schack and R.D. Wilson.
  104. "Dioxygenyl Pentafluorogermanate (IV), O2+GeF5-," Inorg. Chem., 15, 1271 (1976) with R. D. Wilson and I. B. Goldberg.
  105. "Vibrational Spectra of the Pseudo-Trigonal Bipyramidal Tetrafluorides, SF4 and ClF4+," Spectrochim. Acta, Part A, 32, 1141 (1976) with E. C. Curtis, C. J. Schack, S. J. Cyvin, and J. Brunvoll.
  106. "Improved Syntheses of NF4BF4 and NF4SbF6," J. Fluor. Chem., 8, 541 (1976) with C. J. Schack and R. D. Wilson.
  107. "Vibrational Spectrum and Normal Coordinate Analysis of SF5Br," Spectrochim. Acta, Part  A, 33, 69 (1977) with E. C. Curtis, C. J. Schack and A. Roland.
  108. "On the Synthesis and Characterization of NF4BiF6 and Some Properties of NF4SbF6," Inorg. Chem., 16, 937 (1977) with R. D. Wilson and C. J. Schack.
  109. "Vibrational Spectra of SF4O," Spectrochim. Acta, Part A, 33, 323 (1977) with C. J. Schack and E. C. Curtis.
  110. "Synthesis and Characterization of (NF4)2SnF6 and NF4SnF5," Inorg. Chem., 16, 849 (1977) with C. J. Schack and R. D. Wilson.
  111. "Synthesis and Characterization of (NF4)2TiF6 and of Higher NF4+ and Cs+ Polyperfluorotitanate (IV) Salts," Inorg. Chem., 16, 353 (1977) with C. J. Schack.
  112. "A Simple Method for the Purification of Fluorine," J. Fluor. Chem., 10, 169 (1977) with E. Jacob.
  113. "Synthesis and Characterization of (NF4)2NiF6," Inorg. Chem., 16, 2238 (1977).
  114. "On the Synthesis and Properties of Some Hexafluorobismuthate (V) Salts and Their Use   in the Metathetical Synthesis of NF4+ Salts,"  J. Fluor. Chem., 11, 71 (1978) with W. W. Wilson and C. J. Schack.
  115. "On the Synthesis of the N2F5+ Cation.  A Critical Comment on the Paper by Toy and Stringham," J. Fluor. Chem., 11, 183 (1978).
  116. "Electron Spin Resonance Evidence for the Formation of the NF3+ Radical Cation as an Intermediate in the Synthesis of NF4+ Salts by Low-Temperature Ultraviolet Photolysis,"  Inorg. Chem., 17, 759 (1978) with I. B. Goldberg.
  117. "Vibrational Spectra and Force Fields of the Tetrafluoroxohalate (V) Anions ClF4O-, BrF4O-, and IF4O-," Inorg. Chem., 17, 533 (1978) with R. D. Wilson, E. C. Curtis, W. Kuhlmann and W. Sawodny.
  118. "Bromine Trifluoride Oxide.  Vibrational Spectrum, Force Constants, and Thermodynamic Properties," Inorg. Chem., 17, 1533 (1978) with E. C. Curtis and R. Bougon.
  119. "Reactions of Electropositive Chlorine Compounds with Fluorocarbons," Israel J. Chem., 17, 20 (1978) with C. J. Schack.
  120. "Fluoroacyl Hypochlorites and Ester Derivatives," J. Fluor. Chem., 12, 325 (1978) with C. J. Schack.
  121. "On the Deformation Modes of the BiF6- Anion," J. Fluor. Chem., 12, 336 (1978) with W. W. Wilson, C. J. Schack and R. Bougon.
  122. "Improved Syntheses of Some Sulfur Fluoride and Oxyfluoride Peroxides," Inorg. Nucl. Chem. Letters, 14, 293 (1978) with C. J. Schack.
  123. "Bromyl Fluoride. Vibrational Spectra, Force Field, and Thermodynamic Properties," Inorg. Chem., 17, 2744 (1978) with E. C. Curtis and E. Jacob.
  124. "Chemistry and Structure of the N2F3+ Salts," Inorg. Chem., 17, 2749 (1978) with C. J. Schack.
  125. "ESR Spectra of the 14NF3+ and 15NF3+ Radical Cations," Inorg. Chem., 17, 3189 (1978) with I. B. Goldberg and H. R. Crowe.
  126. "On the Formation and Decomposition Mechanism of NF4+ Salts," Inorg. Chem., 18, 2572 (1979) with R. D. Wilson and I. B. Goldberg.
  127. "Novel Onium Salts. Synthesis and Characterization of the Peroxonium Cation, H2OOH+," Inorg. Chem., 18, 2578 (1979) with W. W. Wilson and E. C. Curtis.
  128. "Reactions of Fluorine Perchlorate with Fluorocarbons and the Polarity of the O-F Bond in Covalent Hypofluorites," Inorg. Chem., 18,  2619 (1979) with C. J. Schack.
  129. "Cis- and trans-Iodine (VII) Oxytetrafluoride Hypofluorite, OIF4OF," Inorg. Nucl. Chem. Letters, 15, 375 (1979) with R. D. Wilson.
  130. "Sulfur Tetrafluoride.  Assignment of Vibrational Spectra and Force Field," Spectrochim. Acta, Part A, 35A, 1347 (1979) with H. Willner and W. Sawodny.
  131. "Introduction of Functional Groups into Some Chlorofluorocarbon Ethers," J. Fluor. Chem., 14, 519 (1979) with C. J. Schack.
  132. "Synthesis and Properties of NF4+ClO4- and NF4+HF2-•nHF and Some Reaction Chemistry of NF4+ Salts," Inorg. Chem., 19, 1494 (1980) with W. W. Wilson and R. D. Wilson.
  133. “Halogen Fluorosulfate Reactions with Fluorocarbons," J. Fluor. Chem., 16, 63 (1980) with C. J. Schack.
  134. "Simplified Synthesis of NF4+SbF6-," J. Fluor. Chem., 15, 83 (1980) with W. W. Wilson.
  135. "The Force Field of SF4," Z. Naturforsch, 35B, 1137 (1980) with W. Sawodny, K. Birk and G. Fogarasi.
  136. "Vibrational Spectra of 15NF4AsF6 and General Valence Force Field of NF4+," Spectrochim. Acta, 36A, 921 (1980).
  137. "Synthesis and Properties of NF4+SO3F-," Inorg. Chem., 19, 3046 (1980) with R. D. Wilson and C. J. Schack.
  138. "Synthesis and Characterization of (NF4)2MnF6," Inorg. Chem., 19, 3254 (1980) with W. W. Wilson and R. D. Wilson.
  139. "Evidence for the Existence of Directional Repulsion Effects by Lone Valence Electron Pairs and p Bonds in Trigonal-Bipyramidal Molecules," Inorg. Chem., 20, 296 (1980) with H. Oberhammer.
  140. "Synthesis and Properties of NF4+UF5O-," J. Inorg. Nucl. Chem., 43, 1551 (1981) with W. W. Wilson and R. D. Wilson.
  141. "Determination of NF3 in NF4+ Containing Complex Fluoro Anion Salts," Anal. Chem., 53, 845 (1981) with R. Rushworth, C. J. Schack, and W. W. Wilson.
  142. "The General Valence Force Field of Perchloryl Fluoride," Spectrochim. Acta, 37A, 549 (1981) with E. C. Curtis, W. Sawodny, H. Haertner, and G. Fogarasi.
  143. "Syntheses and Properties of FOIF4O, ClOIF4O, HOIF4O, and Tetrafluoro-periodates," Inorg. Chem., 20, 2104 (1981) with R. D. Wilson and C. J. Schack.
  144. "Properties of Azidotrifluoromethane," Inorg. Chem., 20, 2566 (1981) with C. J. Schack.
  145. "Perfluoroammonium and Cesium Fluorotungstates," Inorg. Chem., 20, 4139 (1981) with W. W. Wilson.
  146. "Substitution and Addition Reactions of NF4BF4 with Aromatic Compounds," J. Fluor. Chem., 18, 363 (1981) with C. J. Schack.
  147. "Synthesis and Properties of (NF4)2SiF6 and Interaction of SiF4 with Anhydrous HF and CsHF2," J. Fluor. Chem., 19, 253 (1982) with W. W. Wilson.
  148. "Thermochemistry of NF4+ Salts," J. Fluor. Chem., 19, 263 (1982) with R. Bougon, T. Bui Huy, J. Burgess, and R. Peacock.
  149. "Gas Phase Structure of ClF3O," Inorg. Chem., 21, 273 (1982) with H. Oberhammer.
  150. "Iodine Fluorosulfate Reactions with Fluorocarbons," J. Fluor. Chem., 20, 283 (1982) with C.J. Schack.
  151. "Syntheses of NF4+ Salts Derived from the Lewis Acids AlF3 and BeF2," J. Fluor. Chem., 20, 751 (1982) with W. W. Wilson and C. J. Schack.
  152. "Perfluoro Ammonium Salts of Metal Heptafluoro Anions," Inorg. Chem., 21, 2091 (1982) with W. W. Wilson.
  153. "Perfluoro Ammonium and Alkali Metal Salts of the Heptafluoro Xenon (VI) and Octafluoro Xenon (VI) Anions," Inorg. Chem., 21, 4113 (1982) with W. W. Wilson.
  154. "New Syntheses of Pentafluorotellurium Hypochlorite," J. Fluor. Chem., 21, 393 (1982) with C. J. Schack.
  155. "Fluorine Perchlorate, Vibrational Spectra, Force Field and Thermodynamic Properties," Inorg. Chem., 21, 2938 (1982) with E. C. Curtis.
  156. "Synthesis and Characterization of TeF5OF," Inorg. Chem., 22, 18 (1983) with C. J. Schack and W. W. Wilson.
  157. "Reactions of Azidotrifluoromethane with Halogen-Containing Oxidizers," Inorg.Chem., 22, 22 (1983) with C. J. Schack.
  158. "Synthesis of N,N-Difluoro-O-Perfluoroalkylhydroxylamines, Part I.  Reaction of Perfluoroalkylhypofluorites with Difluoroamine," Inorg. Chem., 22, 810 (1983) with W. Maya, D. Pilipovich, M. G. Warner and R. D. Wilson.
  159. "Synthesis of N,N-Difluoro-O-Perfluoroalkylhydroxylamines, Part II.  The Lewis Acid Catalylzed Addition of NF3O to Olefins," Inorg. Chem., 22, 1355 (1983) with R. D. Wilson, W. Maya and D. Pilipovich.
  160. "Nitrogen-14 and  Nitrogen-15 NMR Spectroscopy of Fluoronitrogen Cations: p- and s-Fluoro Effects,"  Inorg. Chem., 22, 1849 (1983) with J. Mason.
  161. "On the Reality of Positive Fluorine," J. Fluor. Chem., 22, 519 (1983).
  162. "Thermochemistry of NF4+ Salts.  On the Enthalpy of Formation of NF4XeF7 and NF4SbF6-BrF3 System," J. Fluor. Chem., 23, 399 (1983) with W. W. Wilson, R. D. Wilson, R. Bougon and T. Bui Huy.
  163. "On the Synthesis of Coordinatively Saturated Complex Fluoro Cations.  Synthesis and Characterization of ClF6+AsF6- and ClF6+SbF6-," Inorg. Chem., 22, 3056 (1983) with W. W. Wilson.
  164. "Synthesis and Properties of ClF6BF4," Inorg. Chem., 22, 1950 (1983) with W. W. Wilson.
  165. "EPR Evidence on Molecular and Electronic Structure of the Nitrogen Trifluoride Radical Cation," J. Am. Chem. Soc., 105, 3799 (1983) with A. M. Maurice, R. L. Belford and I. B. Goldberg.
  166. "Far Infrared Laser Magnetic Resonance Detection of FO2," J. Phys. Chem., 87, 5068 (1983) with F. Temps, H. G. Wagner, P. B. Davies, and D. P. Stern.
  167. "Positive Fluorine. Reality or Misconception?,"  J. Fluorine Chem., 25, 269 (1984).
  168. "Synthesis of Bis-Pentafluorotelluriumoxide Fluorocarbons," J. Fluor. Chem., 26, 19 (1984) with C. J. Schack.
  169. "Coordinatively Saturated Fluoro Cations. Oxidative Fluorination Reactions with KrF+ Salts and PtF6," Inorg. Chem., 23, 2058 (1984) with W. W. Wilson and R. D. Wilson.
  170. "An Improved Synthesis of TeF5OF," Inorg. Chem., 23, 2922 (1984) with C. J. Schack.
  171. "Synthesis and Characterization of (ClF2O)2NiF6,"  Inorg. Chem., 23, 3261 (1984) with W. W. Wilson.
  172. "Some Interesting Observations in Chlorine Oxyfluoride Chemistry, J. Fluor. Chem., 26, 257 (1984).
  173. "Structure and Vibrational Spectra of Oxonium Hexafluoroarsenates(V) and - Antimonates(V),"  Inorg. Chem., 23, 3756 (1984) with P. Charpin, E. Soulie, R. Bougon, J. Fawcett and R. Russell.
  174. "Reactions of Pentafluorotellurium Hypohalites with Fluoroolefins," J. Fluor. Chem., 24, 467 (1984) with C. J. Schack.
  175. "Gas-Phase Structure of Azidotrifluoromethane.  An Electron Diffraction, Microwave Spectroscopy, and Normal-Coordinate Analysis," Inorg. Chem., 23, 4283 (1984) with D. Christen, H. Oberhammer and C. J. Schack.
  176. "Bis-Pentaflurotelluriumoxide Fluorocarbons," J. Fluor. Chem., 27, 53 (1984) with C. J. Schack.
  177. "Lewis Acid Induced Intramolecular Redox Reactions of Difluoramino Compounds," Inorg. Chem., 24, 303 (1985) with W. W. Wilson, C. J. Schack, and R. D. Wilson.
  178. "Extended Correlation Between O-F Bond Energies and 19F NMR Chemical Shifts in Fluoroxy Compounds," Inorg. Chem., 24, 2869 (1985) with E. Ghibaudi and A. J. Colussi.
  179. "Cyanation and Nitration of Toluene with Cyanamide and Nitramide Through Intermediate Cyano- and Nitrodiazonium Ions. Attempted Fluorination of Aromatics with Fluorodiazonium Ion," J. Org. Chem., 50, 1338 (1985) with G. A. Olah, K. Laali, M. Farnia, J. Shih, B. Singh, and C. J. Schack.
  180. "Synthesis and Characterization of NF4CrF6 and Reaction Chemistry of CrF5," Inorg.Chem., 24, 2286 (1985) with R. Bougon and W. W. Wilson.
  181. "Dioxygenyl Salts Containing Doubly Charged Mononuclear Counterions," J. Fluor. Chem., 30, 237 (1985) with R. Bougon and W. W. Wilson.
  182. "Synthesis and Characterization of NF4+BrF4 and NF4+BrF4O-," Inorg. Chem., 25, 1904 (1986) with W. W. WIlson.
  183. "Estimation of the N-F Bond Distance in NF4+ from its General Valence Force Field," Spectrochim Acta, Part A., 8, 939 (1986).
  184. "Synthesis and Characterization of CrF4O, KrF2•CrF4O and NO+CrF5O-,"  Inorg. Chem., 25, 2163 (1986) with W. W. Wilson and R. Bougon.
  185. "Chlorylfluoride," Inorg. Syntheses, 24, 3 (1986) with R. D. Wilson and C. J. Schack.
  186. "Tungsten Tetrafluoride Oxide," Inorg. Syntheses, 24, 37 (1986) with W. W. Wilson.
  187. "Tetrafluoroammonium Salts," Inorg. Syntheses, 24, 39 (1986) with W. W. Wilson, C. J. Schack and R. D. Wilson.
  188. "Cesium Hexafluoromanganate (IV)," Inorg. Syntheses, 24, 48 (1986) with W. W. Wilson.
  189. "Preparation and Characterization of Ni(SbF6)2," J. Fluor. Chem., 34, 287 (1986) with W. W. Wilson R. A. Bougon and P. Charpin.
  190. "Chemical Synthesis of Elemental Fluorine," Inorg. Chem., 25, 3721 (1986).
  191. "On the Existence of a CrF4O•SbF5 Adduct," J. Fluor. Chem.,  35, 531 (1987) with W. W. Wilson.
  192. "Self-Association in HOF and HNF2.  Which Atoms are Better Proton Acceptors, Fluorine, Oxygen, or Nitrogen?,"  J. Fluor. Chem., 35, 621 (1987).
  193. "New, One Step Syntheses of BrF3O and BrF4O- Salts and the Preparation and Characterization of RbBrF4O and NaBrF4O," Inorg. Chem., 26, 916 (1987) with W. W. Wilson.
  194. "On the Condensed Phases of Difluoramine and Its Alkali Metal Fluoride Adducts," Inorg. Chem., 26, 920 (1987) with R. D. Wilson.
  195. "Dinitrogen Pentoxide.  New Synthesis and Laser Raman Spectrum," Inorg. Chem., 26, 1631 (1987) with W. W. Wilson.
  196. "Bromine Nitrates," Inorg. Chem., 26, 1573 (1987) with W. W. Wilson.
  197. "Solid Propellant Based Pure Fluorine Gas Generators," Inorg. Chem., 26, 2554 (1987). with R. D. Wilson.
  198. "N-Nitro-N-(2,2,2-Trinitroethyl) Guanidine,"  J. Energetic Mat., 5, 83 (1987) with M. B. Frankel and J. F. Weber.
  199. "On the Existence of Pentacoordinated Nitrogen," Inorg. Chem., 27, 789 (1988) with W. W. Wilson, G. J. Schrobilgen, R. V. Chirakal, and G. A. Olah.
  200. "Convenient Synthesis of Xenon Oxide Tetrafluoride," Inorg. Chem., 27, 1296 (1988) with W. W. Wilson.
  201. "Synthesis of Pentafluoroseleniumoxide Fluorocarbons," J. Fluor. Chem., 39, 163 (1988) with C. J. Schack.
  202. "Preparation and Characterization of Ni(BiF6)2 and of the Ternary Adduct [Ni(CH3CN)6](BiF6)2, and [Ni(CH3CN)6](SbF6)2.  Crystal Structure of [Ni(CD3CN)6](SbF6)2,"  Inorg. Chem., 27, 1389 (1988) with R. Bougon, P. Charpin, J. Isabey, M. Lance, M. Nierlich, J. Vigner, and W. W. Wilson.
  203. "Crystal Structure of [NF4]+ Salts,"  Inorg. Chem., 27, 2714 (1988) with M.D. Lind, N. Thorup, J. Fawcett and R. Bau.
  204. "Synthesis and Properties of XeO2F+AsF6- and [FO2XeFXeO2F]+AsF6-,"  Inorg. Chem., 27, 2714 (1988) with W. W. Wilson.
  205. "Pentafluorotelluriumoxide Derivatives of Fluorocarbons," J. Fluor. Chem., 39, 153 (1988) with C. J. Schack.
  206. "One-Step Synthesis of NF4BiF6," J. Fluor. Chem.40, 59 (1988) with W. W. Wilson.
  207. "New Sytheses and Properties of XeO2F2, Cs+XeO2F3-, and NO2+[XeO2F3•nXeO2F2]-,"  Inorg. Chem., 27, 3763 (1988) with W. W. Wilson.
  208. "Formation of Chlorine-Fluorine and Nitrogen-Fluorine Bonds Using Carbonyl Difluoride as the Fluorinating Agent," Inorg. Chem., 27, 4771 (1988) with C. J. Schack.
  209. "Synthesis of SF5O- Substituted Fluorocarbons," J. Fluor. Chem., 45, 283 (1989) with C. J. Schack and R. D. Wilson.
  210. "Preparation of Halogen Oxyfluorides,"  Inorg. Reactions and Methods, Verlag Chemie., Vol. 3, 39 (1989).
  211. "Reactions of BrF5 with the Azide, Nitrite and Sulfate Anions," J. Fluor. Chem., 43, 125 (1989) with W. W. Wilson and C. J. Schack.
  212. "Reactions of Chlorine Fluorides and Oxyfluorides with the Nitrate Anion and Alkaki Metal Fluoride Catalyzed Decomposition of ClF5," Inorg. Chem., 28, 675 (1989) with W. W. Wilson and R. D. Wilson.
  213. "Fluorine-Oxygen Exchange Reactions in IF5, IF7 and IF5O" Inorg. Chem., 28, 904 (1989) with W. W. Wilson and R. D. Wilson.
  214. "Anion Exchange in NF4+ Salts Using Graphite Salts as an Oxidizer- and Acid-Resistant Anion Exchange Medium," Inorg. Chem., 28,  4175, (1989) with R. D. Wilson.
  215. "Steric Activity of the Central Atom Free Valence Electron Pairs in Free BrF6- and IF6- Ions,"  Inorg. Chem., 28, 3275 (1989) with W. W. Wilson.    
  216. "Tetramethylammonium Salts of ClF4-, BrF4- and BrF6-," Inorg. Chem., 28, 4172 (1989) with W. W. Wilson.
  217. "Tetramethylammonium Bifluoride, Crystal Structure and Vibrational Spectra," Canad. J. Chem., 67, 1898 (1989) with W. W. Wilson, J. Feng, and R. Bau.
  218. "Reactions of TeF5OCl with Fluorocarbon Iodides and Synthesis of CF3OTeF5," J. Fluor. Chem., 47, 79 (1990) with C. J. Schack.
  219. "New Synthesis of IF5O" J. Fluor. Chem., 49, 167 (1990), with C. J. Schack.
  220. "Syntheses and Vibrational Spectra of Fluorochloroamines," J. Fluor. Chem., 48, 361 (1990), with J. V. Gilbert, R. A. Conklin, and R. D. Wilson.
  221. "Reaction of the Fluoride Anion with Acetonitile," J. Fluor. Chem., 47, 117 (1990) with W. W. Wilson.
  222. "Nuclear Magnetic Resonance Spectrum of the Fluoride Anion," J. Fluor. Chem., 46, 339 (1990) with W. W. Wilson.
  223. "Syntheses, Properties, and Structures of Anhydrous Tetramethylammonium Fluoride and its 1:1 Adduct with trans-3-Amino-2-Butene Nitrile," J. Am. Chem. Soc., 112, 7619 (1990) with W. W. Wilson, R. D. Wilson, R. Bau, and J. Feng.
  224. "The Hexafluorochlorate(V) Anion, ClF6-," Inorg. Chem., 39, 3506 (1990) with R. V. Chirakal, J. Sanders, and G. J. Schrobilgen.
  225. "The N2F+ Cation.  An Unusual Ion Containing the Shortest Presently Known Nitrogen-Nitrogen and Nitrogen-Fluorine Bonds," J. Am. Chem. Soc., 113, 3795 (1991) with R. D. Wilson, W. W.  Wilson, R. Bau, S. Sukumar, and D. A. Dixon.
  226. "The Pentafluoroxenate (IV) Anion, XeF5-; the First Example of a Pentagonal Planar AX5 Species," J. Am. Chem. Soc., 113, 3351 (1991) with E. C. Curtis, H. P. Mercier,  J. C. P. Sanders, G. J. Schrobilgen, and D. Dixon.
  227. "X-ray Crystal Structure and Raman Spectrum of Tribromine(1+) Hexafluoroarsenate(V), Br3+AsF6-, and Raman Spectrum of Pentabromine(1+) Hexafluoroarsenate(V), Br5+AsF6-,"  Z. anorg. allg. Chem. 593, 46 (1991) with R. Bau, and D. Zhao.
  228. "High-coordination Number Fluoro- and Oxofluoro-anions; IF6O-, TeF6O2-, TeF7-, IF8-, and TeF82-," J. Chem. Soc. Chem. Commun., 837 (1991) with J. C. P. Sanders, G. J. Schrobilgen and W. W. Wilson.
  229. "Osmium Tetrafluoride Dioxide, OsF4O2; a New Osmium (VIII) Oxide Fluoride,"
    J. Chem. Soc. Chem. Commun., 1056 (1992) with R. Bougon.
  230. "New Synthesis, Crystal Structure, and Vibrational Spectra of Tetramethylammonium Azide and Reactions of the Fluoride Anion with HN3 and of the Azide Anion with HF," J. Am. Chem. Soc., 114, 3411 (1992) with W. W. Wilson, R. Bau and S. Bunte.
  231. "A Quantitative Scale for the Oxidizing Strength of Oxidative Fluorinators," J. Am. Chem. Soc., 114, 2978 (1992) with D. A. Dixon.
  232. "Nitrogen Pentafluoride:  Covalent NFversus Ionic NF4+F- and Studies on the Instability of the Latter," J. Am. Chem. Soc., 114, 9934 (1992) with W. W. Wilson.
  233. "Nitrosyl Hypofluorite: Local Density Functional Study of a Problem Case for Theoretical Methods," J. Phys. Chem., 96, 1018 (1992) with D. A. Dixon.
  234. "Controlled Replacement of Fluoride by Oxygen in Fluorides and Oxyfluorides," Chapter contributed to a book on "Synthetic Fluorine Chemistry," G. A. Olah, R. D. Chambers and G. K. S. Prakash, Edit. John Wiley & Sons, Inc. (1992) with W. W. Wilson and C. J. Schack.
  235. "The Pentabromine (1+) Cation, Br5+. Local Density Functional Calculations and Vibrational Spectra," Z. Anorg. Allg. Chem., 612, 1 (1992)  with D. A.Dixon and R. Minkwitz.
  236. "On the Problem of Heptacoordination: Vibrational Spectra, Structure, and Fluxionality of Iodine Heptafluoride" J. Am. Chem. Soc., 115, 1520 (1993) with E. C. Curtis and D. A. Dixon.
  237. "The Tetrafluorosulfate (1-) and Tetrafluorooxosulfate (1-) Radical Anions, SF4- and SF4O-," J. Am. Chem.Soc., 115, 1129 (1993) with J. T.Wang, B. Walther, F. Williams, I. B. Goldberg, D. A. Dixon, and C. J. Schack.
  238. "The Aminodiazonium Cation, H2N3+," J. Am. Chem. Soc., 115, 1836 (1993) with W. W. Wilson, D. A. Dixon, S. I. Khan, R. Bau, T. Metzenthin, and R. Lu.
  239. "The IOF6- Anion: The First Example of a Pentagonal Bipyramidal AX5YZ Species,"
    J. Am. Chem. Soc., 115, 2696 (1993) with D. A.Dixon, A. R. Mahjoub, H. P. A. Mercier, J. C. P. Sanders, K. Seppelt, G. J. Schrobilgen, and W. W. Wilson.
  240. "Heptacoordination:  On the Pentagonal Bipyramidal TeF7- and XeF7+ Ions," J. Am. Chem. Soc., 115,
  241. "The TeOF62- Anion:  The First Example of a Divalent, Pentagonal Bipyramidal AX5YZ Species and the Vibrational Spectra of the TeOF5- Anion," Inorg. Chem., 32, 4089 (1993) with D. A. Dixon, J. C. P. Sanders, G. J. Schrobilgen, and W. W. Wilson.
  242. "On the Structure of IOF5," J. Am. Chem. Soc, 115, 9655 (1993) with E. C. Curtis and D. A. Dixon.
  243. "Osmium Tetrafluoride Dioxide, cis-OsO2F4," J. Am. Chem. Soc., 115, 11279 (1993) with D. A. Dixon, H. G. Mack, H. Oberhammer, A. Pagelot, J. C. P. Sanders, and G. J. Schrobilgen.
  244. "The Tetrafluorophosphite, PF4-, Anion,” J. Am. Chem. Soc., 116, 2850 (1994) with D. A. Dixon, H. P.  A. Mercier, J. C. P. Sanders, G. J. Schrobilgen, and W. W. Wilson.
  245. “Heptacoordinated Main-Group Fluorides and Oxyfluorides,” Chapter 5 in “Inorganic Fluorine Chemistry Toward the 21st Century” ACS Symposium Series 555 (1994), with E. C. Curtis, D. A. Dixon, H. P. A. Mercier, J. C. P. Sanders, G. J. Schrobilgen, and W. W. Wilson.
  246. “Electrophilic Fluorination of Methane with “F+” Equivalent N2F+ and NF4+ Salts,” J. Am. Chem. Soc., 116, 5671 (1994) with G. A. Olah, N. Hartz, G. Rasul, Q. Wang, G. K. S. Prakash, and J. Casanova.
  247. “Hydrolysis and Methanolysis of PF4- and Nuclear Magnetic Resonance and Vibrational Spectra of the POF2- and HPO2F- Anions,” Inorg. Chem., 33, 4911 (1994) with D. A. Dixon, J. C. P. Sanders, G. J. Schrobilgen, and W. W. Wilson.
  248. “On the Instability of Salts Containing the Trifluoride Anion,” J. Fluor. Chem., 71, 149 (1994).
  249. “Vibrational Spectra and Mutual Ligand Interactions in the Hydrogen Substituted Main Group Hexafluorides HPF5- and HSF5,” J. Am. Chem. Soc., 116, 7123 (1994) with D. A. Dixon, and W. W. Wilson.
  250. “Theoretical Prediction of the Structures and Stabilities of Azidamines,” J. Phys. Chem., 99, 187 (1995) with H. H. Michels, J. A. Montgomery, Jr., and D. A. Dixon.
  251. “On the Structure of the [XeOF5]- Anion and of Heptacoordinated Complex Fluorides Containing One or Two Highly Repulsive Ligands or Sterically Active Free Valence Electron Pairs,” Inorg. Chem. 34, 1868 (1995) with D. A. Dixon, J. C. P. Sanders, G. J. Schrobilgen, S. S. Tsai, and W. W. Wilson.
  252. “An Excursion into Phosphorus-Fluoride Chemistry, N(CH3)4PF4, [POF2]- and M+HPF5-,” J. Fluor. Chem., 71, 205 (1995) with W. W. Wilson, H. P. A. Mercier, J. C. P. Sanders, G. J. Schrobilgen, and D. A. Dixon.
  253. “Oxidative Chemical Oxygenation of NF3 and Novel Synthesis of NF3O,” J. Am. Chem. Soc., 117, 6136 (1995).
  254. “The Dinitramide Anion, N(NO2)2-,” Inorg. Chem., 35, 5068 (1996), with W. W. Wilson, M. A. Petrie, H. H. Michels, J. C. Bottaro and R. Gilardi.
  255. “The [PO2F2·2AsF5]- Anion, an Example of a Stable Oxygen-bridged, 1:2 Donor-acceptor Polynuclear Anion,”  Eur. J. Solid State and Inorg. Chem., 33, 865 (1996), with R. Gnann, R. I. Wagner and W. W. Wilson.
  256. “Naked Fluoride Ion Sources: Synthesis, Characterization and Coupling Reaction of 1-Methyl Hexamethylenetetramine Fluoride,” J. Am. Chem. Soc., 119, 112 (1996), with R. Z. Gnann, R. I. Wagner, R. Bau, G. A. Olah and W. W. Wilson.
  257. “Tetrafluorophosphate Anion,” J. Am. Chem. Soc., 119, 3918 (1996), with D. A. Dixon, G. J. Schrobilgen and W. W. Wilson.
  258. “Disorder and Polymorphism in Tetramethylammonium Metaperiodate,” Inorg. Chem., 36, 2564 (1997) with R. I. Wagner, R. Bau, R. Z. Gnann and P. F. Jones.
  259. “Preparation, NMR, Raman, and DFT/IGLO-MP2 Study on Mono- and Diprotonated Thiourea and Theoretical Investigation of Triprotonated Thiourea,” J. Am. Chem. Soc., 119, 4345 (1997) with G. A. Olah, A. Burrichter, G. Rasul and G. K. S. Prakash.
  260. 17O and 13C NMR/ab Initio / IGLO/GIAO-MP2 Study of Oxonium and Carboxonium Ions (Dications) and Comparison with Experimental Data,” J. Am. Chem. Soc., 119, 8035 (1997) with G. A. Olah, A. Burrichter, G. Rasul, R. Gnann and G. K. S. Prakash.
  261. “Direct Syntheses of Tetramethylammonium Salts of Complex Fluoroanions,” J. Fluor. Chem., 83, 191 (1997) with R. Z. Gnann and R. I. Wagner.
  262. “Novel High-Energy Density Materials.  Synthesis and Characterization of Triazidocarbenium Dinitramide, -Perchlorate, and -Tetrafluoroborate,” J. Am. Chem. Soc., 119, 8802 (1997) with M. A. Petrie, J. A. Sheehy, J. A. Boatz, G. Rasul, G. K. S. Prakash and G. A. Olah.
  263. “Trimethylperoxonium Ion, CH3OO(CH3)2+,” J. Am. Chem. Soc., 119, 9572 (1997) with G. A. Olah, G. Rasul, A. Burrichter, M. Hachoumy, G. K. S. Prakash and R. I. Wagner.
  264. “Theoretical Study of Bicyclic Nitrogen Tetroxide Cation, NO4+,” J. Phys. Chem.A, 102, 1837 (1998) with A. A. Korkin, M. Nooijen and R. J. Bartlett.
  265. Preparation and Vibrational Spectra of N(CH3)4+IF2- and Electronic Structure Calculations of IF2-, BrF2-, ClF2-, XeF2 and KrF2,” J. Fluor. Chem., 88, 185 (1998) with W. W. Wilson, G. W. Drake, M. A. Petrie and J. A. Boatz.
  266. “Dinitramide Anion as a Reagent for the Controlled Replacement of Fluorine by Oxygen in Halogen Fluorides,” J. Fluor. Chem., 89, 97 (1998) with W. W. Wilson.
  267. “Pentagonal Planar AX5 Species:  Synthesis and Characterization of the Iodine (III) Pentafluoride Dianion, IF52-J. Am. Chem. Soc., 120, 4711 (1998) with W. W. Wilson, G. W. Drake, D. A. Dixon, J. A. Boatz and R. Z. Gnann.
  268. “Seven-Coordinated Pnicogens. Synthesis and Characterization of the SbF72- and BiF72- Dianions and a Theoretical Study of the AsF72- Dianion,” J. Am. Chem. Soc., 120, 8392 (1998) with G. W. Drake, D. A. Dixon and J. A. Boatz.
  269. “A convenient Synthesis of Carbonyl Chloride Fluoride,” J. Fluor. Chem., 94, 107 (1999) with B. Hoge.
  270. “Heptacoordination. Synthesis and Characterization of the IOF52- Dianion, an XOF5E Compound,” J. Am. Chem. Soc., 121, 3382 (1999) with W. W. Wilson, D. A. Dixon, and J. A. Boatz.
  271. “On the Existence of the Halocarbonyl and Trifluoromethyl Cations in the Condensed Phase,” Inorg. Chem., 38, 3132 (1999) with B. Hoge,  J. A. Boatz, G. K. S. Prakash, G. A. Olah, and J. A. Sheehy.
  272. “Experimental and Theoretical Characterization of the Oxygen-Coordination Donor-Acceptor Adducts of COCl2, COClF, and COF2 with AsF5 and SbF5,” Inorg. Chem., 38, 3143 (1999) with B. Hoge, J. A. Boatz, and J. Hegge.
  273. “Crystal Structure of Hexamethylguanidinium Hexafluorosilicate Hexahydrate,” J. Fluor. Chem., 98, 121 (1999) with X. Zhang, R. Bau, and J. A. Sheehy.
  274. “N5+: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material,” Angew. Chem. Int. Ed. 38, 2004 (1999) with W. W. Wilson, J. A. Sheehy, and J. A. Boatz.
  275. “Chemical Methods for the Generation of Fluorine,” Chapter 2.1 in Methods of Organic Chemistry (Houben-Weyl), Volume E 10a, Organo-Fluorine Compounds, Georg Thieme Verlag Stuttgart-New York, 1999.
  276. “Relative Abilities of Fluorine and Chlorine to Stabilize Carbenium Ions. Crystal Structures of Two Fluoro-Substituted Carbocations and of As2F11-,” J. Am. Chem. Soc., 122, 481 (2000) with X. Zhang, R. Bau, J. Hegge, G. A. Olah, G. K. Surya Prakash, and J. A. Sheehy.
  277. “On a Quantitative Scale for Lewis Acidity and Recent Progress in Polynitrogen Chemistry,” J. Fluor. Chem. 101, 151 (2000) with D. A. Dixon, D. McLemore, W. W. Wilson, J. A. Sheehy, and J. A. Boatz.
  278. “Never Say No to a Challenge,” contributed chapter to “Fluorine Chemistry at the Millenium: “Fascinated by Fluorine,” R. E. Banks, editor, Elsevier Science, Amsterdam, August 2000.
  279. “Crystal Structure of F2NO+AsF6- and Method for Extracting Meaningful Geometries from Oxygen/Fluorine Disordered Crystal Structures,” Inorg. Chem., 40, 416 (2001) with A. Vij and X. Zhang.
  280. “Structure of the SO2F- Anion, a Problem Case,” Inorg. Chem., 40, 1303 (2001) with E. Lork, R. Mews, D. Viets, P. Watson, T. Borrmann, A. Vij, and J. Boatz.
  281. “Novel Synthesis of ClF6+ and BrF6+ Salts,” Inorg. Chem., 40, 2415 (2001) with T. Schroer.
  282. “Crystal Structure of ClF4+SbF6-, Normal Coordinate Analyses of ClF4+, BrF4+, IF4+, SF4, SeF4, and TeF4, and Simple Method for Calculating the Effects of Fluorine Bridging on the Structure and Vibrational Spectra of Ions in a Strongly Interacting Ionic Solid,” J. Am. Chem. Soc., 123, 6338 (2001), with X. Zhang, J. Sheehy, and R. Bau.
  283. “In Pursuit of the PO2+ Cation. The Reaction of KPO2F2 and SbF5 leads to an Eight-membered Antimony-Oxygen-Phosphorus-bridged Ring,” Z. Anorg. Allg. Chem., 627, 631 (2001) with S. Schneider, A. Vij, J. A. Sheehy, F. S.  Tham, and T. Schroer.
  284. “On the stability of NF4+NO3- and a new synthesis of fluorine nitrate,” J. Fluor. Chem., 110, 87 (2001) with B. Hoge.
  285. “Synthesis and Characterization of the First Examples of Perfluoroalkyl-Sub-stituted Trialkyloxonium Salts, [(CH3)2OCF3]+[Sb2F11]- and [(CH3)2OCF(CF3)2]+  [Sb2F11]-,” Inorg. Chem., 40, 4404 (2001) with R. Minkwitz, S. Reinemann, R. Seelbinder, D. Konikowski, H. Hartl, I. Bruedgam, J. Hegge, B. Hoge, and J. A. Sheehy.
  286. “A Renaissance in Noble Gas Chemistry,” Angew. Chem. Int. Ed. 40, 1419 (2001).
  287. “Polynitrogen Chemistry. Synthesis, Characterization, and Crystal Structure of Surprisingly Stable Fluoroantimonate Salts of N5+,” J. Am. Chem. Soc., 123, 6308 (2001) with A. Vij, W. W. Wilson, V. Vij, F. S. Tham, and J. A. Sheehy.
  288. “An Improved Method for Product Separation in Metathetical Reactions and its Demonstration for the Synthesis of Anhydrous Cesium Salts,” Z. Anorg. Allg. Chem., 628, 1717 (2002) with R. Haiges.
  289. “Improved Synthesis of CsN3,” Z. Anorg. Allg. Chem., 628, 909 (2002) with  M. Gerken, S. Schneider, T. Schroer, and R. Haiges.
  290. “The 19F NMR Shifts are not a Measure for the Nakedness of the Fluoride Anion,” J. Fluor. Chem., 116, 49 (2002), with M. Gerken, J. A. Boatz, A. Kornath, R. Haiges, S. Schneider, and T. Schroer.
  291. “Triphenylmethyldifluoramine: A Stable Reagent for the Synthesis of gem-Bis(difluoramines),” J. Chem. Soc. Chem. Comm., 1712 (2002) with G. K. Surya Prakash, M. Etzkorn, G. A. Olah, S. Schneider, and A. Vij.
  292. “The Crystal Structures of ClF3O, BrF3O, and BrF4O-,” Z. Anorg. Allg. Chem., 628, 1991 (2002) with A. Ellern, J. A. Boatz, T. Drews, and K. Seppelt.
  293. “Synthesis and Characterization of the SO2N3-, (SO2)2N3-, and SO3N3- Anions,” Inorg. Chem., 41, 4275 (2002) with J. A. Boatz, M. Gerken, R. Haiges, S. Schneider, T. Schroer, F. S. Tham, A. Vij, V. Vij, R. I. Wagner, and W. W. Wilson.
  294. “Singlet Delta Oxygen Production from a Gas-Solid Reaction,” Angew. Chem. Int. Ed., 41, 3252 (2002) with A. Alfano.
  295. “Experimental Detection of the Pentaazacyclopentadienide (Pentazolate) Anion, cyclo-N5-,” Angew. Chem. Int. Ed., 41, 3051 (2002) with A. Vij, J. G. Pavlovich, W. Wilson, and V. Vij.
  296. “Structures of the BrF4+ and IF4+ Cations,” Inorg. Chem., 41, 6397 (2002) with A. Vij, F. S. Tham, V. Vij, and W. Wilson.
  297. “Tritylsulfinylamine: A New Member in the Family of Sulfinylamines,” Solid State Sciences, 4, 1529 (2002) with M. Gerken, R. Haiges, S. Schneider, T. Schroer, F. S. Tham, and A. Vij.
  298. “A Gas-Solid Singlet Delta Oxygen Generator for the Chemical Oxygen-Iodine Laser,” Technology Horizons, 3, 34 (2002) with A. Alfano and R. Corley.
  299. “The (SO2)2N3- Anion,” Inorg. Chem., 42, 419 (2003) with M. Gerken, R. Haiges, S. Schneider, T. Schroer, I.Tsyba, and R. Bau.
  300. “Polynitrogen Chemistry: Preparation and Characterization of (N5)2SnF6, N5SnF5, and N5B(CF3)4,” Chemistry – A European Journal, 9, 2840 (2003) with W. W. Wilson, A. Vij, V. Vij, and E. Bernhardt.
  301. “Synthesis and Characterization of the trans-IO2F52- Anion,” Inorg. Chem., 42, 5282 (2003) with J. A. Boatz, D. A. Dixon, B. A. Fir, M. Gerken, R. Z. Gnann, H. P. A. Mercier, and G. J. Schrobilgen.
  302. “On the Existence of FN5, a Theoretical and Experimental Study,” J. Phys. Chem. A, 107, 6638 (2003) with H. M. Netzloff, M. S. Gordon, W. W. Wilson, A. Vij, V. Vij, and J. A. Boatz.
  303. “Quantitative Measure for the Nakedness of Fluoride Ion Sources,” J. Am. Chem. Soc., 125, 9457 (2003) with H. D. B. Jenkins.
  304. “Polyazide Chemistry: Preparation and Characterization of Te(N3)4 and [P(C6H5)4]2[Te(N3)6] and Evidence for [N(CH3)4][Te(N3)5],” Angew. Chem. Int. Ed., 42, 5847 (2003), with R. Haiges, J. A. Boatz, A. Vij, M. Gerken, S. Schneider, and T. Schroer.
  305. “Enthalpies of Formation of Gas Phase N3, N3-, N5+, and N5- from Ab Initio Molecular Orbital Theory, Stability Predictions for N5+N3- and N5+N5-, and Experimental Evidence for the Instability of N5+N3-,” J. Am. Chem. Soc.,126, 834 (2004), with D. A. Dixon, D. Feller, W. W. Wilson, A. Vij, V. Vij, H. D. B. Jenkins, R. M. Olson, and M. S. Gordon.
  306. “First Structural Characterization of Binary As(III) and Sb(III) Azides,” Chemistry – A European Journal, 10, 508 (2004), with R. Haiges, A. Vij, J. A. Boatz, S. Schneider, T. Schroer, and M. Gerken.
  307. “X-ray Crystal Structures of [XF6][Sb2F11] (X = Cl, Br, I); 35,37Cl, 79,81Br and 127I NMR Studies and Electron Structure Calculations of the XF6+ Cations,” Inorg. Chem., 43, 6905 (2004), with J. F. Lehmann, G. J. Schrobilgen, A. Kornath, and R. Suontamo.
  308. “Preparation and Characterization of the First Binary Group 4 Azides, Ti(N3)4, [P(C6H5)4][Ti(N3)5] and [P(C6H5)4]2[Ti(N3)6] and on Linear Ti-N-NN Coordination,” Angew. Chem. Int. Ed., 43, 3148 (2004), with R. Haiges, J. A. Boatz, S. Schneider, T. Schroer, and M.  Yousufuddin.
  309. “New High Energy Density Materials. Synthesis and Characterization of N5+P(N3)6-, N5+B(N3)4-, N5+HF2-nHF, N5+BF4-, N5+PF6-, and N5+SO3F-,” Angew. Chem. Int. Ed., 43, 4919 (2004), with R. Haiges, S. Schneider, and T. Schroer.
  310. “The NH3Cl+ Cation,” Angew. Chem. Int. Ed., 43, 5213 (2004), with S. Schneider, R. Haiges, T. Schroer, and J. Boatz.
  311. “Polyazide Chemistry. Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6],” Angew. Chem. Int. Ed., 43, 6676 (2004), with R. Haiges, J. A. Boatz, A. Vij, V. Vij, M. Gerken, S. Schneider, T. Schroer, and M. Yousufuddin.
  312. “Polyazide Chemistry: Preparation and Characterization of the First Binary Group 6 Azides, Mo(N3)6, W(N3)6, Mo(N3)7-, and W(N3)7- and of the [NW(N3)4]- and [NMo(N3)4]- Anions,” Angew. Chem. Int. Ed., 44, 1860 (2005), with R. Haiges, J. A. Boatz, R. Bau, S. Schneider, T. Schroer, and M. Yousufuddin.
  313. “The race for the first generation of the pentazolate anion in solution is far from over,” J. Chem. Soc., Chem. Commun., 1607 (2005), with T. Schroer, R. Haiges, and S. Schneider.
  314. “The Heats of Formation of Xenon Fluorides,” J. Am. Chem. Soc., 127, 8627 (2005), with D. A. Dixon, W. A. de Jong, K. A. Petersen,  and G. J. Schrobilgen.
  315. “The Syntheses and Structures of Ph4EN3 (E = P, As, Sb), an Excellent Example for the Transition from Ionic to Covalent Azides within the Same Main Group,” Z. Anorg. Allg. Chem., 631, 2691 (2005) with R. Haiges, T. Schroer, and M. Yousufuddin.
  316. “Experimental Evidence for Linear Metal-Azide Bonds. The Binary Group 5 Azides Nb(N3)5, Ta(N3)5, [Nb(N3)6]- and [Ta(N3)6]-, and 1:1 Adducts of Nb(N3)5 and Ta(N3)5 with CH3CN,” Angew. Chem. Int. Ed., 45, 4830 (2006), with R. Haiges, J. A. Boatz, T. Schroer, and M. Yousufuddin.
  317. “Photochemistry of Interhalogen Compounds,” Argent. J. Chem., 93, 1 (2005), with R. D. Wilson and A. E. Axworthy.
  318. “New Signal Processing Method for the Faster Observation of Natural Abundance 15N NMR Spectra and its Application to N5+,” Inorg. Chem., 45, 437 (2006), with S. D. Kunikeev, H. S. Taylor, T. Schroer, R. Haiges, and CJ Bigler Jones.
  319. “Experimental Evidence for Linear Metal-Azide Bonds. The Binary Group 5 Azides Nb(N3)5, Ta(N3)5, [Nb(N3)6]- and [Ta(N3)6]-, and 1:1 Adducts of Nb(N3)5 and Ta(N3)5 with CH3CN,” Angew. Chem. Int. Ed., 45, 4830 (2006), with R. Haiges, J. A. Boatz, T. Schroer, and M.Yousufuddin.
  320. “Preparation, Characterization, and Crystal Structures of the SO3NHF- and SO3NF2- Anions,” Angew. Chem. Int. Ed., 45, 5179 (2006), with R. Haiges, R. Wagner, J. A. Boatz, M.Yousufuddin, M. Etzkorn, G. K. Surya Prakash, R. D. Chapman, M. F. Welker, and C. B. Kreutzberger.
  321. “Are the NF4+ Cations in NF4BF4 Really Nontetrahedral?,” Inorg. Chem., 45, 7981 (2006), with R. Haiges, M. Gerken, A. Iuga, and R. Bau.
  322. “Following in the Footsteps of Henri Moissan,” L’Actualite Chimique, 301, 34 (2006).
  323. “Oxygen Balanced Energetic Ionic Liquid,” Angew. Chem. Int. Ed., 45, 4830 (2006), with C. J. Bigler Jones, R. Haiges, and T. Schroer.
  324. “Polyazide Chemistry: Synthesis and Properties of [Nb(N3)7]2- and [Ta(N3)7]2-,” Angew. Chem. Int. Ed., 46, 2869 (2007), with R. Haiges, J. A. Boatz, and M. Yousufuddin.
  325. “Synthesis and Characterization of Silyldichloramines, their Reactions with F- Ions, Stability of N2Cl2 and NCl2-, and Formation of NCl3,” Inorg. Chem., 46, 93 (2007), with S. Schneider, M. Gerken, R. Haiges, T. Schroer, J. A. Boatz, D. A. Dixon, and D. J.  Grant.
  326. “Recent Advances in the Chemistry of N5+, N5-, and High Oxygen Compounds,” Propellants, Explosives, Pyrotechnics, 32, 194 (2007).
  327. “Synthesis and Characterization of z-N3NFO+ and e-N3NFO+,” Angew. Chem. Int. Ed., 46, 3023 (2007), with W. Wilson, R. Haiges, and J. A. Boatz.
  328. “Convenient Access to Trifluoromethanol,” Angew. Chem. Int. Ed., 46, 6155 (2007), with J. Hegge, B. Hoge and R. Haiges.
  329. “Heats of Formation of Krypton Fluorides and Stability Predictions for KrF4 and KrF6 from High Level Electronic Structure Calculations,” Inorg. Chem., 46, 10016 (2007), with D. A. Dixon, T.-H. Wang, D. J. Grant, K. A. Peterson, and G. J. Schrobilgen.
  330. “The Binary Selenium(IV) Azides Se(N3)4, [Se(N3)5]-, and [Se(N3)6]2-,” Angew. Chem. Int. Ed., 46, 8686 (2007), with T. M. Klapoetke, B. Krumm, M. Scherr, and R. Haiges.
  331. “Energetics and Mechanism of the Decomposition of Trifluoromethanol,” J. Phys. Chem. A, 112, 1298 (2008), with M. T. Nguyen, M. H. Matus, V. T. Ngan, R. Haiges, and D. A. Dixon.
  332. “Bond Dissociation Energies in Second Row Compounds,” J. Phys. Chem. A, 112, 3145 (2008), with D. J. Grant, M. H. Matus, J. R. Switzer, D. A. Dixon, and J. S. Francisco.
  333. “Thermochemical Parameters of CHFO and CF2O,” J. Phys. Chem. A, 112, 4973 (2008), with M. H. Matus, M. T. Nguyen, and D. A. Dixon.
  334. “The Structure and Heats of Formation of Iodine Fluorides and the Respective Closed Shell Ions from CCSD(T) Electronic Structure Calculations and Reliable Prediction of the Sterical Activity of the Free Valence Electron Pair in ClF6-, BrF6- and IF6-,” Inorg. Chem., 47, 5485 (2008), with D. A. Dixon, D. J. Grant, and K. A. Peterson.
  335. “Neil Bartlett (1932-2008), Founder of Noble-Gas Chemistry,” Nature, Vol. 455, 11 September, 2008.
  336. “Lewis Acidities and Hydride, Fluoride, and X- Affinities of the BH3-nXn Compounds for (X = F, Cl, Br, I, NH2, OH, and SH) from Coupled Cluster Theory,” Inorg. Chem., 48, 8811 (2009), with D. J. Grant, D. A. Dixon, D. Camaioni, and R. G. Potter.
  337. “On the XeF+/H2O System: Synthesis and Characterization of the Xenon(II) Oxide Fluoride Cation, FXeOXeFXeF+,” J. Am. Chem. Soc.,131, 13474 (2009) with M. Gerken, M. D. Moran, H. P. A. Mercier, B. E. Pointner, G. J. Schrobilgen, B. Hoge, and J. A. Boatz.
  338. “Synthesis and Properties of N7O+,” Inorg. Chem., 49, 1245 (2010), with R. Haiges, W. W. Wilson, and J. A. Boatz.
  339. “Heats of Formation of XeF3+, XeF3-, XeF5+, XeF7+, XeF7-, and XeF8 from High Level Electronic Structure Calculations, Inorg. Chem., 49, 261 (2010), with D. J. Grant, T-H. Wang, and D. A. Dixon.
  340. “Electron Affinities, Fluoride Affinities, and Heats of Formation of the Third Row Transition Metal Hexafluorides: MF6 (M = W, Re, Os, Ir, Pt, Au),” Inorg. Chem., 49, 1056 (2010), with R. Craciun, D. Picone, R. T. Long, S. Li, D. A. Dixon, and K. A. Peterson.
  341. “Sulfuryl and Thionyl Halide-Based Ultralow Temperature Primary Batteries, ”J. Electrochem. Soc., 157, 571 (2010), with W. C. West, A. Shevade, J. Soler, J. Kulleck, M. C. Smart, B. V. Ratnakumar, M. Moran, R. Haiges, and G. K. S. Prakash.
  342. “The Syntheses and the Structure of the First Vanadium(IV) and Vanadium(V) Binary Azides, V(N3)4, [V(N3)6]2- and [V(N3)6]-,” Angew. Chem. Int. Ed., 49, 8008 (2010), with R. Haiges and J. A. Boatz.
  343. “Electron Affinities, Fluoride Affinities, and Heats of Formation of the Second Row Transition Metal Hexafluorides: MF6 (M = Mo, Tc, Ru, Rh, Pd, Ag),” J. Phys. Chem. A, 114, 7571 (2010), with R. Craciun, R. T. Long, and D. A. Dixon.
  344. “Dinitrogen Difluoride Chemistry. Improved Synrtheses of cis- and trans-N2F2, Synthesis and Characterization of N2F+Sn2F9-, Ordered Crystal Structure of N2F+SbF2F11-, High-Level Electronic Structure Calculations of cis-N2F2, trans-N2F2, F2N=N, and N2F+, and Mechanism of the trans-cis Isomerization of N2F2,” Inorg. Chem., 49, 6823 (2010), with D. A. Dixon, D. J. Grant, R. Haiges, F. S. Tham, A. Vij, V. Vij, T.-H. Wang, and W. W. Wilson.
  345. “Selenium(IV) Fluoride and Oxofluoride Anions,” J. Fluor. Chem., 131, 791 (2010), with D. A. Dixon, R. Haiges, M. Hopfinger, V. E. Jackson, T. M. Klapoetke, B. Krumm, and M. Scherr.

 

 

 

                Patents of Karl Christe

  1. "Decomposition of Aromatic Fluoroformates and Fluorothioformates to Aromatic Fluorides,"  U.S. 3, 283, 018 (1 November 1966) with A.E. Pavlath.
  2. "Process for Preparing Arylfluoroformates and Arylfluorothioformates," U.S. 3,287,388 (1966) with A.E. Pavlath.
  3. "Fluorination with SiF4,"  U.S. 3, 287, 426 (1966) with A.E. Pavlath.
  4. "Fluoroformal and Fluorothioformal Compound and Production Thereof," U.S.  3, 328, 453 (1966) with A.E. Pavlath.
  5. "Method for the Preparation of Alkyl Vicinal-polyfluoroformates," U.S. 3,362,980 (1968).
  6. "Process for Preparing 1,3-Dichlorobutane,"  U.S. 3,406,212 (1968).
  7. "Preparation of Chlorine Substituted Alkyl Fluoroformates," U.S. 3, 418, 356 (1968).
  8. "Heterolytic Fission of Elementary Fluorine in Preparation of an Adduct of Fluorinated Lewis Bases with Lewis Acids," U.S. 3, 503, 719 (1970) with J.P. Guertin and A.E. Pavlath.
  9. "Certain Alkali Metal and Nitrosyl Difluorochlorates and Their Preparation," U.S. 3, 552, 936 (1971) with J.P. Guertin and A.E. Pavlath.
  10. "Methods of Using Fluxes in Joining Metal Surfaces," U.S. 3, 707, 762 (1975) with J.H. Bochinski, F.C. Gunderloy, Jr., D. Pilipovich and R.D. Wilson.
  11. "Process for Preparing Stable Chlorine Trifluoride Dioxide," U.S. 3, 873, 676 (1975).
  12. "Iodine Perchlorates," U.S. 3, 873, 677 (1975) with C.J. Schack.
  13. "High Energy Oxidizers and Method of Synthesizing Same," U.S. 3, 879, 526 (1975).
  14. "Iodine Perchlorates," U.S. 3, 922, 336 (1975) with C.J. Schack.
  15. "Stable Unsubstituted Sulfonium Salts," U.S. 3, 987, 152 (1976).
  16. "Stable Chlorine Trifluoride Dioxide," U.S. 4, 038, 374 (1977).
  17. "Production of OH3+ Salts," U.S. 4, 101, 640 (1978).
  18. "Photolysis Method for Producing NF4PF6," U.S. 4, 102, 984 (1978) with C.J. Schack.
  19. "Method for Producing NF4BF4," U.S. 4, 107, 275 (1978) with C.J. Sckack and R.D. Wilson.
  20. "(NF4)2NiF6 High Energy Solid Propellant Oxidizer and Method of Producing the Same,"  U.S. 4, 108, 965 (1978).
  21. "Self-Clinkering NF4+ Compositions for NF3-F2 Gas Generators and Method of Producing Same," U.S. 4, 152, 406 (1979) with C.J. Schack and R.D. Wilson.
  22. "Self-Clinkering Burning Rate Modifier for Solid Propellant NF3-F2 Gas Generators for Chemical HF-DF Lasers," U.S. 4, 163, 773 (1979) with C.J. Schack.
  23. "N2F3SbF6 and Its Preparation," U.S. 4, 163, 774 (1979) with C.J. Schack.
  24. "Displacement Reaction for Producing NF4PF6," U.S. 4, 172, 881 (1979) with C.J. Schack.
  25. "Self-Clinkering NF4+ Compositions for NF3-F2 Gas Generators and Method of Producing Same," U.S. 4, 172, 884 (1979) with C.J. Schack and R.D. Wilson.
  26. "High Detonation Pressure Explosives," U.S. 4, 207, 124 (1980).
  27. "Synthesis of Fluorocarbon Esters," U.S. 4, 216, 338 (1980) with C.J. Schack.
  28. "Method for Synthesizing Fluorocarbon Halides," U.S. 4, 222, 968 (1980) with C.J. Schack.
  29. "Iodine (VII) Oxytetrafluorohypofluorite and A Process for Preparing the Same," U.S.  4, 339, 330 (1982) with W.W. Wilson.
  30. "Peroxonium Salts," U.S. 4, 339, 423 (1982) with W.W. Wilson.
  31. "Stable NF4+ Salt of High Fluorine Content," U.S. 4, 374, 112 (1983) with W.W. Wilson.
  32. "NF4+WF7- and NF4+UF7- and Methods of Preparation," U.S. 4, 421, 727 (1983) with W.W. Wilson.
  33. "Method for Introducing Fluorine into an Aromatic Ring," U.S. 4, 423, 260 (1983) with C.J. Schack.
  34. "Perfluoroammonium Salt of Heptafluoroxenon Anion," U.S. 4, 428, 913 (1984) with W.W. Wilson.
  35. "Perfluoroammonium Salts of Fluoroxenon Anions," U.S. 4, 447, 407 (1984) with W.W. Wilson.
  36. "NF3-F2 Gas Generator Compositions," U.S. 4, 410, 377 (1983) with W.W. Wilson.
  37. "Synthesis of Pentafluorotellurium Hypofluorite," U.S. 4, 462, 975 (1984) with C.J. Schack and W.W. Wilson.
  38. "Method for Introducing Fluorine into an Aromatic Ring," U.S. 4, 476, 377 (1984) with C.J. Schack.
  39. "Pentafluorotelluriumoxide Fluorocarbons," U.S. 4, 508, 662 (1985) with C.J. Schack.
  40. "Multi-(OTeF5)-Substitued Fluorocarbons," U.S. 4, 578, 225 (1986) with C.J. Schack.
  41. "Process for Preparing Pentafluorotellurium Hypofluorite," U.S. 4, 594, 232 (1986) with C.J. Schack.
  42. "Synthesis of RfOTeF5," U.S. 4, 675, 088 (1987) with C.J. Schack.
  43. "Process for the Production of Advanced NF4+ Salts," U.S. 4, 683, 129 (1987).
  44. "Method for the Selective Separation of Gases," U.S. 4, 695, 296 (1987).
  45. "Pure Fluorine Gas Generator," U.S. 4, 711, 680 (1987).
  46. “Radiation Augmented Energy Storage System,” U.S. 4, 903, 479 (1990).
  47. “Method of Preparing Tetramethylammonium Azide,” U.S. 5, 369, 212 (1994) with W. W. Wilson.
  48. “Pentanitrogen(1+) Cation and Salt Containing the Same,” U. S. 6,224,696 (2001) with W. W. Wilson.
  49. “Process for the Chemical Generation of Singlet Delta Oxygen,” U.S 6,623,718 (2002) with A. Alfano.
  50. “Energetic Ionic Liquids,” U. S. Patent 7,771,549 (2010), with G. Drake.
  51. - 63.  Foreign Patents:
    French 1, 411, 243 (1965);  Belgian 651, 529 (1965);  Canadian 633, 990 (1966);  British 1, 076, 566 (1967);  Mexican 80, 279 (1967);  Australian 280, 046 (1968);  Italian 969, 002 (1974);  British 1, 361, 106 (1974); German 2,250,853 (1975); French; 72.36704 (1976);  Japan 893, 691 (1978); Taiwan 56, 294 (1992).

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